Search results for "strength"

showing 10 items of 2415 documents

PLA-based functionally graded laminates for tunable controlled release of carvacrol obtained by combining electrospinning with solvent casting

2020

Abstract A novel approach was designed to fabricate high-added value manufacts, starting from cost-effective materials and combining well-known processing techniques. Bi- and three-layered, functionally graded laminates were achieved by direct electrospinning onto dense substrates. The architecture of each multilayer comprises a dense layer formed by solvent casting, which is constituted by polylactic acid (PLA) and carvacrol, and one or two electrospun fibrous skin layers, consisting of PLA only. Processing-structure-properties relationships of such materials were investigated. As regards mechanical behavior, the amount of fibrous PLA layers determined an increase of stiffness from 20 to 3…

Materials sciencePolymers and PlasticsGeneral Chemical Engineering02 engineering and technology010402 general chemistry01 natural sciencesBiochemistrychemistry.chemical_compoundPolylactic acidUltimate tensile strengthMaterials ChemistryEnvironmental ChemistryComposite materialControlled drug release Electrospinning onto film Functionally graded Multilayer Peppas model Solvent castingGeneral Chemistry021001 nanoscience & nanotechnologyControlled releaseCastingElectrospinning0104 chemical sciencesSolventSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryElongation0210 nano-technologyLayer (electronics)Reactive and Functional Polymers
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Effects of anodizing surface treatment on the mechanical strength of aluminum alloy 5083 to fibre reinforced composites adhesive joints

2021

Abstract In this study, the anodizing process based on the use of tartaric sulfuric acid solution (TSA) was carried out on metal substrate to evaluate for the first time its effect on the adhesion strength and corrosion resistance of aluminium alloy (i.e., AA5083) to fibre (i.e., basalt or glass) reinforced composite adhesive joints for nautical applications. Furthermore, some TSA anodized samples were soaked in a NaOH solution to investigate the influence of this post-immersion step on the joint performances. With the aim to improve the fibre-matrix adhesion in the composite substrate thus further increasing the overall mechanical response of the joint, glass and basalt fibres were treated…

Materials sciencePolymers and PlasticsGeneral Chemical EngineeringAlloychemistry.chemical_element02 engineering and technologyengineering.materialCorrosionBiomaterials03 medical and health scienceschemistry.chemical_compound0302 clinical medicineAluminiumUltimate tensile strengthAluminium alloyComposite materialAnodizingtechnology industry and agriculture030206 dentistryEpoxy021001 nanoscience & nanotechnologySilaneSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialiSettore ING-IND/23 - Chimica Fisica Applicatachemistryvisual_artAdhesive joint Anodizing Basalt Corrosion resistance Silane coupling agent Surface treatmentvisual_art.visual_art_mediumengineering0210 nano-technologyInternational Journal of Adhesion and Adhesives
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Self assembled hydrophobic nanoclusters of poly(methyl methacrylate) embedded into polyvinyl alcohol based hydrophilic matrix: Preparation and water …

2009

Hydrophilic matrices containing nanosized clusters of hydrophilic moieties have demonstrated potential applications in biomedical field. A novel hydrogel containing nanosized domains (20–35 nm) of hydrophobic moieties of poly(methyl methacrylate) (PMMA) was prepared by grafting crosslinked poly(acrylic acid-co-methyl methacrylate) chains onto polyvinyl alcohol (PVA) backbone using an efficient redox system. The graft copolymerization process was investigated to observe the influence of gel components on the kinetic parameters of grafting such as rate of grafting (Rg), grafting yield (Gy) and grafting efficiency (Ge). The prepared graft nanohydrogel was evaluated for its water sorption poten…

Materials sciencePolymers and PlasticsGeneral ChemistryMethacrylateGraftingPolyvinyl alcoholPoly(methyl methacrylate)Surfaces Coatings and FilmsNanoclusterschemistry.chemical_compoundchemistryIonic strengthvisual_artPolymer chemistryMaterials Chemistryvisual_art.visual_art_mediumCopolymerMethyl methacrylateJournal of Applied Polymer Science
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Stress-Strain State in the Zone of Load Transfer in a Composite Specimen under Uniaxial Tension

2004

The stress-strain state in the zone of load transfer in a uniaxially stretched specimen made of a unidirectional epoxy carbon-fiber-reinforced plastic (CFRP) is investigated. A parametric analysis of the influence of geometric and mechanical characteristics of the specimen on its stress-strain state is performed by means of finite-element modeling. The parameters allowing us to significantly reduce the dangerous concentration of transverse and tangential stresses are revealed. The mechanical tensile characteristics of a high-strength pultruded unidirectional CFRP are determined experimentally, and the size effect of its strength is estimated.

Materials sciencePolymers and PlasticsGeneral MathematicsComposite numberStress–strain curveEpoxyCondensed Matter PhysicsFinite element methodBiomaterialsTransverse planeMechanics of MaterialsPultrusionvisual_artUltimate tensile strengthSolid mechanicsCeramics and Compositesvisual_art.visual_art_mediumComposite materialMechanics of Composite Materials
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Static and dynamic elasticity of some thermotropic liquid-crystalline copolyesters

1997

Two series of thermotropic liquid crystalline copolyesters were studied in static and dynamic tensile deformation. Static loading generally does not lead to any peculiar phenomena: the stress-strain diagrams are linear or convex, except one copolyester fibre, the stress-strain diagram of which is concave at high temperatures. On the contrary, in dynamic loading the elasticity modulus increased during deformation for all the samples investigated. So it can be assumed that formation of a more rigid and stable structure takes place due to the dynamic deformation.

Materials sciencePolymers and PlasticsGeneral MathematicsCondensed Matter PhysicsCopolyesterThermotropic crystalBiomaterialsSynthetic fiberMechanics of MaterialsDynamic loadingSolid mechanicsUltimate tensile strengthCeramics and CompositesComposite materialDeformation (engineering)Elastic modulusMechanics of Composite Materials
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Physicomechanical properties of composites from recycled polyethylene and linen yarn production wastes

1999

The possibilities of utilizing wastes of linen thread production (chaffs, spinning and roving losses) in recycled polyolefin composites have been investigated. The wastes were mixed with recycled polyethylenes (produced from domestic and industrial film production wastes). The physicomechanical properties (tensile strength, bending and tensile moduli, and water resistance) and the fluidity (melt flow-behavior index) for systems with a different filler content are estimated. Almost all the composite materials obtained have satisfactory fluidity (melt flow-behavior index is not lower than 0.07–0.15 dg/min). For all types of the composites, a slight increase in tensile strength and a considera…

Materials sciencePolymers and PlasticsGeneral MathematicsPolyethyleneCondensed Matter PhysicsIndustrial wastePolyolefinBiomaterialschemistry.chemical_compoundFlexural strengthchemistryMechanics of MaterialsUltimate tensile strengthCeramics and CompositesComposite materialSpinningNatural fiberMelt flow indexMechanics of Composite Materials
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Tunable release of Chlorhexidine from Polycaprolactone-based filaments containing graphene nanoplatelets

2019

Abstract Graphene nanoplatelets (GNP) as fillers and Chlorhexidine (CHX), as an antibacterial agent, were incorporated in a polycaprolactone (PCL) matrix and processed into filaments by melt spinning. The influence of both drawing and formulation on the processability, spinnability, mechanical properties and release behaviour of these materials were deeply investigated by performing rheological, morphological analysis, tensile tests, and by measuring the cumulative release of CHX in PBS at 37 °C. Furthermore, Korsmeyer–Peppas model was adopted to study the kinetics release mechanism. The results showed that adding GNP did not alter the processability and spinnability of the systems. Further…

Materials sciencePolymers and PlasticsGeneral Physics and Astronomy02 engineering and technology010402 general chemistry01 natural scienceslaw.inventionchemistry.chemical_compoundRheologylawUltimate tensile strengthMaterials ChemistryControlled releaseComposite materialAntibacterial agentNanocompositeNanocompositeGrapheneOrganic Chemistry021001 nanoscience & nanotechnologyControlled release0104 chemical sciencesMelt spinningSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryPCLPolycaprolactoneMelt spinningGraphene0210 nano-technologyMechanical propertie
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Progressive cracking mastercurves of the transverse ply in a laminate

2009

In this study, progressive cracking of a transverse layer in a cross-ply composite laminate subjected to tensile loading is considered. Using the results of a probabilistic cracking model, approximate relations for crack density as a function of stress are derived for initiation-controlled and propagation-controlled cracking. It is shown that the crack density evolution in the transverse ply can be represented by a mastercurve in suitably normalized coordinates. The mastercurve approach is applied to progressive cracking in glass/epoxy laminates. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers

Materials sciencePolymers and PlasticsGlass fiberComposite numberFracture mechanicsGeneral ChemistryEpoxyStress (mechanics)CrackingTransverse planevisual_artUltimate tensile strengthMaterials ChemistryCeramics and Compositesvisual_art.visual_art_mediumComposite materialPolymer Composites
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Processing, structure, property relationships and release kinetics of electrospun PLA/Carvacrol membranes

2018

Abstract In this work, polylactic acid (PLA) membranes at two different carvacrol (CRV) nominal concentration (i.e. 14 wt% and 28 wt%) were prepared via electrospinning technology. The membranes were characterized by scanning electron microscopy, ATR-FTIR and calorimetric measurements as well as tensile tests. Moreover, the release kinetics of CRV in phosphate buffered solution at 37 °C was monitored through UV–Vis measurements and the data were fitted with a power law model. Results indicated that the successful incorporation of CRV in the polymer matrix damaged the fibers morphology but increased all the mechanical parameters investigated (i.e. elastic modulus, tensile strength and elonga…

Materials sciencePolymers and PlasticsKineticsGeneral Physics and Astronomy02 engineering and technology010402 general chemistry01 natural sciencesEssential oilchemistry.chemical_compoundPhysics and Astronomy (all)Polylactic acidUltimate tensile strengthMaterials ChemistryControlled releaseElastic moduluschemistry.chemical_classificationPolymers and PlasticElectrospinningOrganic ChemistryPolymer021001 nanoscience & nanotechnologyControlled releaseElectrospinning0104 chemical sciencesMembraneSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryChemical engineering0210 nano-technology
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Structure–property relationship and controlled drug release from multiphasic electrospun carvacrol-embedded polylactic acid/polyethylene glycol and p…

2018

Electrospinning technologies gained considerable interest over the last decade. In this study, it is proposed a systematic study of polylactic acid/polyethylene glycol (PLA/PEG) and polylactic acid/polyethylene oxide (PLA/PEO) electrospun blends at different concentrations. The effect of blend composition and PEG molecular weight on the morphological and mechanical properties of the mats was evaluated. Furthermore, the kinetic release of carvacrol as model drug in phosphate buffer saline at 37℃ was studied and the data were then fitted using an exponential model. The scanning electron microscopy revealed that the morphology of the mats was strongly dependent on the relative ratio PLA:PEG, …

Materials sciencePolymers and PlasticsMaterials Science (miscellaneous)medical textilesfabricationmacromolecular substances02 engineering and technologyPolyethylene glycolIndustrial and Manufacturing Engineeringmaterialschemistry.chemical_compound020401 chemical engineeringPolylactic acidPEG ratioChemical Engineering (miscellaneous)Carvacrol0204 chemical engineeringnonwovendiffusiontechnology industry and agriculturestructure propertiesSettore ING-IND/34 - Bioingegneria IndustrialePolyethylene oxide021001 nanoscience & nanotechnologyElectrospinningChemistrySettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryChemical engineeringNanofiberDrug releaseprocessingstrength0210 nano-technologyJournal of Industrial Textiles
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