Search results for "strontium"

showing 10 items of 195 documents

Hackmanite—The Natural Glow-in-the-Dark Material

2020

“Glow-in-the-dark” materials are known to practically everyone who has ever traveled by airplane or cruise ship, since they are commonly used for self-lit emergency exit signs. The green afterglow, persistent luminescence (PeL), is obtained from divalent europium doped to a synthetic strontium aluminate, but there are also some natural minerals capable of afterglow. One such mineral is hackmanite, the afterglow of which has never been thoroughly investigated, even if its synthetic versions can compete with some of the best commercially available synthetic PeL materials. Here we combine experimental and computational data to show that the white PeL of natural hackmanite is generated and cont…

Materials scienceGeneral Chemical Engineeringchemistry.chemical_element02 engineering and technologyNatural mineral010402 general chemistry01 natural sciencesNatural (archaeology)Synthetic materialsSODALITEchemistry.chemical_compoundPersistent luminescenceMaterials ChemistryTUGTUPITESPECTRACOLORluminesenssiIRONStrontium aluminate[CHIM.MATE]Chemical Sciences/Material chemistryOPTICAL-PROPERTIESGeneral ChemistryRESONANCE021001 nanoscience & nanotechnology0104 chemical sciencesAfterglow[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryCENTERSPhysics and AstronomychemistryChemical physicsLUMINESCENCE0210 nano-technologyEuropiumLuminescenceChemistry of Materials
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Comparative study of polar perovskite surfaces

2004

A novel model of the ‘‘zig–zag’’ (1 1 0) polar surface termination of ABO3 perovskites is suggested and analyzed. Classical shell model calculations for BaTiO3, SrTiO3 and LaMnO3 show that such the (1 · 2) (1 1 0) surface reconstruction has the lowest energy, comparable to that for the (1 0 0) surfaces. The calculated surface energy reaches the saturation only when 6–8 atomic near-surface planes are allowed to relax. Surface relaxation leads to the formation of considerable dipole moment perpendicular to the surface. The predicted surface polarization of thin perovskite films, even in the cubic phase, could affect their dielectric properties. � 2004 Elsevier B.V. All rights reserved.

Materials scienceMineralogySurfaces and InterfacesDielectricSurface finishCondensed Matter PhysicsMolecular physicsSurface energySurfaces Coatings and FilmsDipolechemistry.chemical_compoundchemistryMaterials ChemistryStrontium titanateSurface reconstructionPerovskite (structure)Surface statesSurface Science
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Effect of surface impurities on downconversion luminescence of Pr3+, Yb3+ activated SrF2 nanoparticles

2020

Abstract Pr3+,Yb3+ activated SrF2 nanoparticles synthesized by low-temperature hydrothermal method were studied. The composition and size of nanoparticles were intentionally changed by controlling synthesis conditions. After structural and morphological characterization, the spectroscopic properties of the nanoparticles were analyzed in the visible and near infrared spectra ranges. The results show correlation between the gradual change of the amount of carboxylate and hydroxyl moieties on the nanoparticle surface, varied by the size nanoparticles and the quenching of the luminescence. The size-related amount of surface quenchers is strongly connected to the decrease of the downconversion e…

Materials scienceNanoparticle02 engineering and technology010402 general chemistryPhotochemistryDownconversion01 natural sciencesHydrothermal circulationInorganic Chemistrychemistry.chemical_compoundImpurityNear infrared spectraCarboxylateElectrical and Electronic EngineeringPhysical and Theoretical ChemistrySpectroscopyQuenching (fluorescence)Organic ChemistryStrontium fluoride021001 nanoscience & nanotechnologyAtomic and Molecular Physics and OpticsStrontium fluoride0104 chemical sciencesElectronic Optical and Magnetic MaterialschemistryNanoparticles0210 nano-technologyLuminescence
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Domain wall transformations and hopping in La0.7Sr0.3MnO3nanostructures imaged with high resolution x-ray magnetic microscopy

2014

We investigate the effect of electric current pulse injection on domain walls in La(0.7)Sr(0.3)MnO(3) (LSMO) half-ring nanostructures by high resolution x-ray magnetic microscopy at room temperature. Due to the easily accessible Curie temperature of LSMO, we can employ reasonable current densities to induce the Joule heating necessary to observe effects such as hopping of the domain walls between different pinning sites and nucleation/annihilation events. Such effects are the dominant features close to the Curie temperature, while spin torque is found to play a small role close to room temperature. We are also able to observe thermally activated domain wall transformations and we find that,…

Materials scienceNanostructure530 PhysicsNucleation01 natural sciencesCondensed Matter::Materials ScienceLanthanum0103 physical sciencesMicroscopyddc:530General Materials Science010306 general physicsSpin (physics)010302 applied physicsMicroscopyCondensed matter physicsMagnetic PhenomenaX-RaysElectric ConductivityTemperatureOxides530 PhysikCondensed Matter PhysicsNanostructuresVortexDomain wall (magnetism)Manganese CompoundsStrontiumCurie temperatureCondensed Matter::Strongly Correlated ElectronsJoule heatingJournal of Physics: Condensed Matter
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The search for defects in undoped SrAl2O4 material

2019

This research project was supported financially by ERDF Project No: Nr.1.1.1.1/16/A/182 .

Materials sciencePersistent luminescenceCharge Carrier trappingPhosphor02 engineering and technology010402 general chemistry01 natural sciencesInorganic ChemistryPersistent luminescence:NATURAL SCIENCES:Physics [Research Subject Categories]Emission spectrumIrradiationElectrical and Electronic EngineeringPhysical and Theoretical ChemistrySpectroscopyCondensed matter physicsDopantOrganic ChemistryDoping021001 nanoscience & nanotechnologyAtomic and Molecular Physics and Optics0104 chemical sciencesElectronic Optical and Magnetic MaterialsAfterglowUndoped strontium aluminate0210 nano-technologyLuminescenceOptical Materials
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Ab initio study of the SrTiO3, BaTiO3 and PbTiO3 (001) surfaces

2004

The results of first-principles calculations of the two possible terminations of (0 0 1) surfaces of SrTiO 3 (STO), BaTiO3 (BTO) and PbTiO3 (PTO) perovskites are presented. Surface atomic structures and their electronic configurations have been calculated using ab initio density functional theory (DFT) combined with hybrid (B3PW) exchange-correlation technique. Our results are compared with previous quantum mechanical calculations and available experimental data. Surface relaxations and the electronic states near valence band gap are discussed in details for all three perovskites. © 2004 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

Materials scienceProcess Chemistry and TechnologyRelaxation (NMR)Ab initioElectronic structureMolecular physicsTitanateSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundchemistryComputational chemistryAb initio quantum chemistry methodsMaterials ChemistryCeramics and CompositesStrontium titanateDensity functional theoryElectron configurationCeramics International
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Novel method of phosphorescent strontium aluminate coating preparation on aluminum

2018

This work was supported by the ERDF , European-Union Project No. 1.1.1.1/16/A/182 .

Materials sciencechemistry.chemical_element02 engineering and technologyengineering.material010402 general chemistry7. Clean energy01 natural scienceschemistry.chemical_compoundCoatingAluminium:NATURAL SCIENCES:Physics [Research Subject Categories]lcsh:TA401-492General Materials SciencePersistent luminophoreStrontium aluminateStrontiumLong afterglowMechanical EngineeringStrontium aluminatePlasma electrolytic oxidation021001 nanoscience & nanotechnology0104 chemical sciencesElectrolytic oxidationChemical engineeringchemistryMechanics of Materialsengineeringlcsh:Materials of engineering and construction. Mechanics of materialsPhosphorescent coating0210 nano-technologyPhosphorescenceLuminescencePowder diffractionMaterials & Design
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Nuclear moments of strongly deformed strontium isotopes

1990

Nuclear spins, moments and mean square charge radii of78–100Sr have been obtained by fast ion-beam collinear laserspectroscopy. The experiments performed at ISOLDE have been extended to include99Sr, measured by a non-optical detection scheme with a two-step optical pumping sequence. The results for the strongly deformed isotopes are discussed in the frame of the particle-plus-deformed core model.

Mean squareNuclear and High Energy PhysicsStrontiumSpinsIsotopeChemistrychemistry.chemical_elementCharge (physics)Condensed Matter PhysicsAtomic and Molecular Physics and OpticsIsotopes of strontiumOptical pumpingCharge radiusPhysical and Theoretical ChemistryAtomic physicsNuclear ExperimentHyperfine Interactions
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Prediction of alkaline earth elements in bone remains by near infrared spectroscopy.

2016

An innovative methodological approach has been developed for the prediction of the mineral element composition of bone remains. It is based on the use of Fourier Transform Near Infrared (FT-NIR) diffuse reflectance measurements. The method permits a fast, cheap and green analytical way, to understand post-mortem degradation of bones caused by the environment conditions on different skeletal parts and to select the best preserved bone samples. Samples, from the Late Roman Necropolis of Virgen de la Misericordia street and En Gil street located in Valencia (Spain), were employed to test the proposed approach being determined calcium, magnesium and strontium in bone remains and sediments. Coef…

Mean squared errorMineralogychemistry.chemical_element02 engineering and technologyResidual01 natural sciencesBone and BonesAnalytical Chemistrysymbols.namesakeMetals Alkaline EarthSpectroscopy Fourier Transform InfraredHumansMagnesiumBone mineralStrontiumSpectroscopy Near-InfraredChemistryFossils010401 analytical chemistryNear-infrared spectroscopyReproducibility of Results021001 nanoscience & nanotechnology0104 chemical sciencesDiagenesisFourier transformSpainStrontiumsymbolsCalciumDiffuse reflection0210 nano-technologyTalanta
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Hybrid DFT calculations of the atomic and electronic structure for ABO3 perovskite (001) surfaces

2005

Abstract We present the results of first-principles calculations on two possible terminations of the (0 0 1) surfaces of SrTiO3, BaTiO3, and PbTiO3 perovskite crystals. Atomic structure and the electronic configurations were calculated for different 2D slabs, both stoichiometric and non-stoichiometric, using hybrid (B3PW) exchange-correlation technique and re-optimized basis sets of atomic (Gaussian) orbitals. Results are compared with previous calculations and available experimental data. The electronic density distribution near the surface and covalency effects are discussed in details for all three perovskites. Both SrTiO3 and BaTiO3 (0 0 1) surfaces demonstrate reduction of the optical …

MineralogySurfaces and InterfacesElectronic structureCondensed Matter PhysicsMolecular physicsSurfaces Coatings and FilmsBrillouin zonechemistry.chemical_compoundAtomic orbitalchemistryMaterials ChemistryStrontium titanateElectron configurationSurface reconstructionElectronic densityPerovskite (structure)Surface Science
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