Search results for "structural"
showing 10 items of 5047 documents
Numerical analysis of masonry structures via interface models
2001
The present paper is devoted to the theoretical formulation and numerical implementation of an interface model suitable to simulate the behavior of mortar joints in masonry structures. The interface laws are formulated in the framework of elasto-plasticity for non-standard materials in order to simulate the softening response which occurs along the decohesion process in presence of shear and tension tractions. A variable material dilatancy parameter is introduced together with a further geometrical dilatancy related to the roughness of contact surfaces after joint fracture. An asperity model is adopted with the aim to describe the evolution of the contact surface shape during the loss of co…
Damage and plasticity at the interfaces in composite materials and structures
2009
Abstract The structural behavior at the interface between two surfaces of ductile, brittle or quasi-brittle materials is studied by a new analytical elastoplastic damaging model. The model is developed in the framework of a thermodynamically consistent theory. The Helmholtz free energy is written to predict the materials’ hardening or softening. An isotropic damage is considered and the possible effects of dilatancy are taken into account including non-associative flow rules. The interface laws are presented both in a rate and a discrete incremental form. The analytical formulation is then implemented into a finite element code and two structural members are studied to validate the model. T…
Testing the USLE-M family of models at the Sparacia experimental site in south Italy
2017
The modified Universal Soil Loss Equation (USLE-M) was empirically deduced by a statistical analysis of the original data set of soil loss measurements used to derive the Universal Soil Loss Equation (USLE). The USLE-M, including the effect of runoffin the event rainfall-runofferosivity factor, is characterized by a better capacity to predict event soil loss. At first, in this paper, using the soil erosion representative variables of USLE-M and the reference condition adopted in the USLE, the dimensional analysis and the self-similarity theory are applied to theoretically deduce a multiplicative equation similar to the USLE-M. Then using the database of the Sparacia experimental site, the a…
New Theoretical Solution of Stage-Discharge Relationship for Slit Weirs
2018
In this paper, the flow-process of a slit weir was analyzed on the basis of a theorem of dimensional analysis and incomplete selfsimilarity theory. The theoretically deduced stage-discharge formula then was calibrated using experimental data obtained for a ratio between the weir and the channel width, ranging from 0.05 to 0.25. The deduced stage-discharge relationship allowed measuring discharge values characterized by errors that, for 98% of the measured values, were less than or equal to 5%. The performance of the proposed theoreticalstage-discharge formula also was improved by introducing the Reynolds number (for 98.5% of the measured values the error was less than or equal to 5%, and th…
Analytical prediction of ultimate moment and curvature of RC rectangular sections in compression
2013
This paper presents closed form expressions linking the ultimate bearing capacity to the ultimate curvature of rectangular RC sections subjected to axial load and bending moment acting in one of the two symmetry planes of the section. With respect to possible simplified formulations the following effects are also considered: confinement of the concrete, hardening of the longitudinal reinforcement, and presence of reinforcing bars distributed orthogonally to the neutral axis. The formulation is proposed in dimensional terms after a preliminary definition of the geometrical and mechanical parameters governing the structural response of the class of sections considered. The analytical expressi…
Dual-affinity avidin molecules
2005
A recently reported dual-chain avidin was modified further to contain two distinct, independent types of ligand-binding sites within a single polypeptide chain. Chicken avidin is normally a tetrameric glycoprotein that binds water-soluble d-biotin with extreme affinity (Kd ≈ 10−15M). Avidin is utilized in various applications and techniques in the life sciences and in the nanosciences. In a recent study, we described a novel avidin monomer-fusion chimera that joins two circularly permuted monomers into a single polypeptide chain. Two of these dual-chain avidins were observed to associate spontaneously to form a dimer equivalent to the wt tetramer. In the present study, we successfully used …
Room temperature crystal structure of the fast switching M159T mutant of the fluorescent protein dronpa
2015
The fluorescent protein Dronpa undergoes reversible photoswitching reactions between the bright ‘on’ and dark ‘off’ states via photoisomerisation and proton transfer reactions. We report the room temperature crystal structure of the fast switching Met159Thr mutant of Dronpa at 2.0 A resolution in the bright on state. Structural differences with the wild type include shifted backbone positions of strand β8 containing Thr159 as well as an altered A-C dimer interface involving strands β7, β8, β10, and β11. The Met159Thr mutation increases the cavity volume for the p-hydroxybenzylidene-imidazolinone chromophore as a result of both the side chain difference and the backbone positional difference…
Approaching a “naked” boryl anion: amide metathesis as a route to calcium, strontium, and potassium boryl complexes
2020
Abstract Amide metathesis has been used to generate the first structurally characterized boryl complexes of calcium and strontium, {(Me3Si)2N}M{B(NDippCH)2}(thf)n (M=Ca, n=2; M=Sr, n=3), through the reactions of the corresponding bis(amides), M{N(SiMe3)2}2(thf)2, with (thf)2Li‐ {B(NDippCH)2}. Most notably, this approach can also be applied to the analogous potassium amide K{N(SiMe3)2}, leading to the formation of the solvent‐free borylpotassium dimer [K{B(NDippCH)2}]2, which is stable in the solid state at room temperature for extended periods (48 h). A dimeric structure has been determined crystallographically in which the K+ cations interact weakly with both the ipso‐carbons of the flanki…
3D reconstruction of the hemocyanin subunit dimer from the chiton Acanthochiton fascicularis.
2004
Procedures are presented for the purification of the subunit dimer from Acanthochiton fasicularis hemocyanin. Electron microscopy of negatively stained specimens revealed a uniform population of macromolecules possessing the characteristic "boat shape". A 3D reconstruction from this EM data generated a approximately 3 nm resolution model that correlates well with earlier data of the purported subunit dimer, extracted from the 3D reconstruction of the didecamer of Haliotis tuberculata hemocyanin type 1.
Study of Reactivity in the 1,3-Dipolar Cycloaddition Reactions Leading to New Triazolopyrrolopyrazine Ring Systems
2010
The influence of the structural symmetry of the 2-pi double-reactive-sites component in the 1,3-dipolar cycloaddition reactions, involving nitrilimines as dipoles, was investigated. the experimental data showed that the loss of the symmetry leads to the formation of the monocycloadduct in good yields.