Search results for "structural"
showing 10 items of 5047 documents
Influencing the Self‐Sorting Behavior of [2.2]Paracyclophane‐Based Ligands by Introducing Isostructural Binding Motifs
2020
Abstract Two isostructural ligands with either nitrile (Lnit) or isonitrile (Liso) moieties directly connected to a [2.2]paracyclophane backbone with pseudo‐meta substitution pattern have been synthesized. The ligand itself (Lnit) or its precursors (Liso) were resolved by HPLC on a chiral stationary phase and the absolute configuration of the isolated enantiomers was assigned by XRD analysis and/or by comparison of quantum‐chemical simulated and experimental electronic circular dichroism (ECD) spectra. Surprisingly, the resulting metallosupramolecular aggregates formed in solution upon coordination of [(dppp)Pd(OTf)2] differ in their composition: whereas Lnit forms dinuclear complexes, Liso…
Novel atrazine-binding biomimetics inspired to the D1 protein from the photosystem II of Chlamydomonas reinhardtii.
2020
Biomimetic design represents an emerging field for improving knowledge of natural molecules, as well as to project novel artificial tools with specific functions for biosensing. Effective strategies have been exploited to design artificial bioreceptors, taking inspiration from complex supramolecular assemblies. Among them, size-minimization strategy sounds promising to provide bioreceptors with tuned sensitivity, stability, and selectivity, through the ad hoc manipulation of chemical species at the molecular scale. Herein, a novel biomimetic peptide enabling herbicide binding was designed bioinspired to the D1 protein of the Photosystem II of the green alga Chlamydomonas reinhardtii. The D1…
HPLC study on the ‘history’ dependence of gramicidin A conformation in phospholipid model membranes
1989
AbstractA novel HPLC methodology for the study of gramicidin A reconstituted in model membranes has been tested in comparison with circular dichroism data. It is shown that this chromatographic technique not only corroborates most of the recent spectroscopic results but allows one to explain them in terms of mass fractions of different actual conformational species of GA in the phospholipid assemblies. In particular, the dependence of the inserted peptide configuration on the organic solvent and other parameters involved in the ‘history’ of the sample preparation and handling has been analyzed by HPLC in two phospholipid model systems: small unilamellar vesicles and micelles. Moreover, a sl…
The Behaviour of Mistuned Piezoelectric Shunt Systems and Its Estimation
2016
This paper addresses monoharmonic vibration attenuation using piezoelectric transducers shunted with electric impedances consisting of a resistance and an inductance in series. This type of vibration attenuation has several advantages but suffers from problems related to possible mistuning. In fact, when either the mechanical system to be controlled or the shunt electric impedance undergoes a change in their dynamical features, the attenuation performance decreases significantly. This paper describes the influence of biases in the electric impedance parameters on the attenuation provided by the shunt and proposes an approximated model for a rapid prediction of the vibration damping performa…
Identification of stiffness, dissipation and input parameters of multi degree of freedom civil systems under unmeasured base excitations
2009
A time domain dynamic identification technique based on a statistical moment approach has been formulated for civil systems under base random excitations in the linear state. This technique is based on the use of classically damped models characterized by a mass proportional damping. By applying the Itô stochastic calculus, special algebraic equations that depend on the statistical moments of the response can be obtained. These equations can be used for the dynamic identification of the mechanical parameters that define the structural model, in the case of unmeasured input as well, and the identification of the input itself. Furthermore, the above equations demonstrate the possibility of id…
An output-only stochastic parametric approach for the identification of linear and nonlinear structures under random base excitations: Advances and c…
2014
In this paper a time domain output-only Dynamic Identification approach for Civil Structures (DICS) first formulated some years ago is reviewed and presented in a more generalized form. The approach in question, suitable for multi- and single-degrees-of-freedom systems, is based on the statistical moments and on the correlation functions of the response to base random excitations. The solving equations are obtained by applying the Itô differential stochastic calculus to some functions of the response. In the previous version ([21] Cavaleri, 2006; [22] Benfratello et al., 2009), the DICS method was based on the use of two classes of models (Restricted Potential Models and Linear Mass Proport…
The durability of basalt fibres reinforced polymer (BFRP) panels for cladding
2015
The study focuses on two basalt composite laminate panels for cladding, produced by means of vacuum bagging technique. In particular, unidirectional and random basalt fabrics, with different areal weights, using epoxy resin as matrix, were used. According to the ISO 15686 methodology for the evaluation of durability, samples were subjected to cycles of artificial aging in climatic chamber and outdoor exposure, carrying out mechanical (i.e. quasi-static and dynamic) and calorimetric tests. The results show the effectiveness over time of produced basalt composite laminates and the initial increase of the mechanical performances after the first steps of accelerated aging.
Heuristic Solutions for a Class of Stochastic Uncapacitated p-Hub Median Problems
2019
In this work, we propose a heuristic procedure for a stochastic version of the uncapacitated r-allocation p-hub median problem with nonstop services. In particular, we assume that the number of hubs to which a terminal can be allocated is bounded from above by r. Additionally, we consider the possibility of shipping traffic directly between terminals (nonstop services). Uncertainty is associated with the traffic to be shipped between nodes and with the transportation costs. If we assume that such uncertainty can be captured by a finite set of scenarios, each of which with a probability known in advance, it is possible to develop a compact formulation for the deterministic equivalent proble…
The development of school well-being in secondary school: High academic buoyancy and supportive class- and school climate as buffers
2021
Abstract Students experience increasing pressure to perform well and worry about their academic performance before critical school transitions. These challenges may compromise students' school well-being. Drawing on the Model of Personality and Affect for Education (Matthews et al., 2005) as well as on the Conservation of Resources Theory (Hobfoll, 1989), we investigated the buffering role of high academic buoyancy and supportive class- and school climate against decreases in school well-being (i.e., school-related stress, anti-school attitude, and satisfaction with school) among Finnish lower secondary school students (N = 1024) from grades seven to nine. Controlling for gender, fluid inte…
THE TOPOLOGY OF BASIN BOUNDARIES IN A CLASS OF THREE-DIMENSIONAL DYNAMICAL SYSTEMS
1996
We will develop new methods to determine the topology of the basin boundary in a class of three-dimensional dynamical systems. One approach is to approximate the basin boundary by backward integration. Unfortunately, there are dynamical systems where it is hard to approximate the basin boundary by a numerical backward integration algorithm. We will introduce topological methods which will provide new information about the structure of the basin boundary. The topological invariants which we will use can be numerically computed.