Search results for "surface"

Structural Features of β-Cyclodextrin Solvation in the Deep Eutectic Solvent, Reline

2020

The inherently amphiphilic nature of native cyclodextrins (CDs) determines their peculiar molecular encapsulation features, enabling applications such as targeted drug nanodelivery, aroma protection, etc. On the contrary, it may also lead to poor solubility in water and other organic solvents and to potentially detrimental flocking in these media, thus posing limitations to more extensive usage. Here we use small angle X-ray scattering to show that deep eutectic solvent reline (1:2 choline chloride:urea) succeeds in dissolving large amounts of beta-CD (at least 800 mg/mL, compared with the solubility in water of 18 mg/mL), without aggregation phenomena occurring. At the microscopic level, m…

WATER MASSES EXCHANGE THROUGH THE STRAIT OF SICILY DURING THE LAST DEGLACIAL PERIOD AND THE HOLOCENE

2022

The main goal of this thesis is to explore the inter-basin connection between the eastern and the western Mediterranean (E- and W-Med, respectively) during the last deglacial and Holocene periods (last 15 kyr). The thesis is based on the study of a sediment core recovered at the west flank of Sicily channel (W-Sicily), strategically located under the current path of the surface Atlantic waters and directly below the present-day hydrographic boundary layer between the Eastern Mediterranean Sourced Water (EMSW) and the Western Mediterranean Deep Water (WMDW). This key location allow to explore past changes in both surface and deep water exchange between the E and the W-Med. In this thesis, a …

Reconfigurable nonlinear response of dielectric and semiconductor metasurfaces

2021

Abstract Optically resonant dielectric and semiconductor metasurfaces are an emerging and promising area of nanophotonics and light–matter interaction at the nanoscale. Recently, active tuning of the linear response and nonlinear effects of these components has received an increasing amount of interest. However, so far these research directions have remained separated with only few sporadic works that study their combination beginning to appear in the literature. The evolution of nonlinear metasurfaces based on dielectric and semiconductor materials toward reconfigurable and dynamic components could potentially answer the demand of integrated on-chip components that realize essential functi…

On Grinbergs' differential geometry and finite fields

2019

Emanuels Grinbergs, in his youth, during ten years, from 1933 until 1943, wrote three dissertations on one subject, namely, differential geometry [1, 2, 3]. We think that his work in this direction has been neglected for many years, and it is the last time to try to understand the significance of these works. Here, in this short article we touch only one aspect of this work, and compare and put together two approaches, one from thesis of Grinbergs [3], and another, of the author's, [5, 6], where we show close relation between both.

Antibody recognition of fluorinated MUC1 glycopeptide antigens.

2011

The syntheses of various fluorinated MUC1 glycopeptide antigens and their specific binding to serum antibodies from mice immunized with natural and fluorinated TF(6)-MUC1-TTox conjugate vaccines are presented.

Synthesis of a MUC1-glycopeptide-BSA conjugate vaccine bearing the 3'-deoxy-3'-fluoro-Thomsen-Friedenreich antigen.

2011

A novel MUC1-glycopeptide–BSA conjugate vaccine with a specifically fluorinated Thomsen–Friedenreich antigen side chain at Thr6 was prepared. Preliminary immunological experiments reveal specific binding of the tumor-associated glycopeptide antigen analog by anti-MUC1-mouse antibodies.

Ozone-Based Atomic Layer Deposition of Al2O3 from Dimethylaluminum Chloride and Its Impact on Silicon Surface Passivation

2017

Dimethylaluminum chloride (DMACl) as an aluminum source has shown promising potential to replace more expensive and commonly used trimethylaluminum in the semiconductor industry for atomic layer deposited (ALD) thin films. Here, the Al2O3 DMACl-process is modified by replacing the common ALD oxidant, water, by ozone that offers several benefits including shorter purge time, layer-by-layer growth, and improved film adhesion. It is shown that the introduction of the ozone instead of water increases carbon and chlorine content in the Al2O3, while long ozone pulses increase the amount of interfacial hydrogen at silicon surface. These are found to be beneficial effects regarding the surface pass…

Structure−Dynamics Coupling between Protein and External Matrix in Sucrose-Coated and in Trehalose-Coated MbCO:  An FTIR Study

2004

We performed FTIR measurements on carboxy-myoglobin (MbCO) embedded in a sucrose−water matrix to study the degrees of freedom coupling between protein and external matrix in such a system. The work was undertaken on the light of recent results by Giuffrida et al. (J. Phys. Chem. B 2003, 107, 13211−13217), who evidenced, in trehalose-coated MbCO, a structured water−sugar environment of the protein, tightly coupled to the heme pocket structure. Such information was obtained through a suitable analysis of the temperature dependence of the CO stretching and of the water association bands in samples of different content of residual water. We applied here the same analysis to sucrose-coated MbCO.…

Dynamics of Strongly Coupled Modes between Surface Plasmon Polaritons and Photoactive Molecules: The Effect of the Stokes Shift

2017

We have investigated the dynamics of strongly coupled modes of surface plasmon polaritons (SPPs) and fluorescent molecules by analyzing their scattered emission polarization. While the scattered emission of SPPs is purely transverse magnetic (TM) polarized, the strong coupling with molecules induces transverse electric (TE) polarized emission via the partial molecular nature of the formed SPP–molecule polariton mode. We observe that the TM/TE ratio of the polariton emission follows the contribution of the molecular excited states in this hybrid mode. By using several types of molecules, we observe that, in addition to the coupling strength, which determines the contribution of the molecular…

Dam displacements monitoring by using GNSS and remote sensing techniques

Il presente lavoro mira a valutare le potenzialità delle tecniche satellitari per il monitoraggio delle dighe. In particolare, l’attenzione è stata rivolta alle dighe di terra, poichè queste rappresentano la tipologia costruttiva più diffusa ed i modelli esistenti in letteratura sono in grado di descriverne gli spostamenti solo nell’ipotesi di conoscere accuratamente tutti parametri geotecnici e strutturali che caratterizzano la composizione della diga stessa. Negli ultimi anni, è stato ampiamente dimostrato che le tecniche satellitari da remoto sono in grado di individuare con elevata accuratezza, il comportamento di grandi strutture (incluse le dighe), valutandone spostamenti e deformazio…