Search results for "surface"
showing 10 items of 9345 documents
Characterizing Cavities in Model Inclusion Fullerenes: A Comparative Study
2001
Abstract: The fullerene-82 cavity is selected as a model system in order to test several methods for characterizing inclusion molecules. The methods are based on different technical foundations such as a square and triangular tessellation of the molecular surface, spherical tessellation of the molecular surface, numerical integration of the atomic volumes and surfaces, triangular tessellation of the molecular surface, and cubic lattice approach to the molecular volume. Accurate measures of the molecular volume and surface area have been performed with the pseudorandom Monte Carlo (MCVS) and uniform Monte Carlo (UMCVS) methods. These calculations serve as a reference for the rest of the meth…
Using fractal dimensions for characterizing intra-urban diversity : the example of Brussels
2003
International audience; The objective of this paper is to compare fractal-based parameters calculated by different fractal methods for urban built-up areas and to link the observed spatial variations to variables commonly used in urban geography, urban economics, or land-use planning. Computations are performed on Brussels, Belgium. Two fractal methods (correlation and dilation) are systematically applied for evaluating the fractal dimension of built-up surfaces; correlation is used to evaluate the fractal dimension of the borders (lines). Analyses show that while fractal dimension is ideal for distinguishing the morphology of Brussels, each estimation technique leads to slightly different …
The XMM Cluster Outskirts Project (X-COP): Thermodynamic properties of the Intracluster Medium out to $R_{200}$ in Abell 2319
2018
We present the joint analysis of the X-ray and SZ signals in A2319, the galaxy cluster with the highest signal-to-noise ratio in Planck maps and that has been surveyed within our XMM Cluster Outskirts Project (X-COP). We recover the thermodynamical profiles by the geometrical deprojection of the X-ray surface brightness, of the SZ comptonization parameter, and an accurate and robust spectroscopic measurements of the temperature. We resolve the clumpiness of the density to be below 20 per cent demonstrating that most of this clumpiness originates from the ongoing merger and can be associated to large-scale inhomogeneities. This analysis is done in azimuthally averaged radial bins and in eigh…
Unveiling the environment and faint features of the isolated galaxy CIG 96 with deep optical and HI observations
2018
Context. Asymmetries in atomic hydrogen (HI) in galaxies are often caused by the interaction with close companions, making isolated galaxies an ideal framework to study secular evolution. The AMIGA project has demonstrated that isolated galaxies show the lowest level of asymmetry in their HI integrated profiles compared to even field galaxies, yet some present significant asymmetries. CIG 96 (NGC 864) is a representative case reaching a 16% level. Aims. Our aim is to investigate the HI asymmetries of the spiral galaxy CIG 96 and what processes have triggered the star-forming regions observed in the XUV pseudo-ring. Methods. We performed deep optical observations at CAHA1.23m, CAHA2.2m and V…
The anthropogenic sealing of soils in urban areas
2009
The sealing of soils by impervious materials is, normally, detrimental to its ecological functions. Exchanges of energy, water and gases are restricted or hampered and an increasing pressure is being exerted on adjacent, non sealed areas. The negative effects span from loss of plant production and natural habitats to increased floods, pollution, and health risks and consequently higher social costs. Environmental Agencies produce periodical reports where the phenomenon of soil consumption by urban infrastructures is monitored with extremely sophisticated geographical tools but little specific research is available that describes the effects of soil sealing. This paper reviews some recent co…
Triggering a transient organo-gelation system in a chemically active solvent
2021
A transient organo-gelation system with spatiotemporal dynamic properties is described. Here, the solvent actively controls a complex set of equilibria that underpin the dynamic assembly event. The observed metastability is due to the in situ formation of a secondary solvent, acting as an antagonist against the primary solvent of the organogel. peerReviewed
Oligonucleotides-decorated-poly(N-vinyl pyrrolidone) nanogels for gene delivery
2013
Pulsed electron-beam irradiation of a semi-dilute poly(N-vinyl pyrrolidone) (PVP) aqueous solution in the presence of acrylic acid has led to a carboxyl functionalized nanogel system. Nanoparticles hydrodynamic size and surface charge density, in water and as a function of pH, were investigated by dynamic light scattering and laser doppler velocimetry, respectively. Nanogels (NGs) were proved not to be cytotoxic at the cellular level. Indeed, they rapidly bypass the cellular membrane to accumulate in specific cell portions of the cytoplasm, in the perinuclear area. The availability of pendant carboxyl groups on the crosslinked PVP NGs core prompted us to attempt their decoration with a sing…
The adsorption of water vapor on super absorbent product at low temperatures and low mass.
2006
The adsorption isotherms of water vapor on super absorbent product have the same form of type III isotherm at ambient temperature with the hysteresis phenomena. For temperatures lower than ambient, the isotherms become deformed because of the chains effect. The polymer is characterized by a multilayer adsorption, which occurs before a full-course is complete. During adsorption reactions, the polymer undergoes rearrangement polymeric network, which results from a cooperative diffusion of the water molecules and from a chain spacing followed by an expansion of the polymeric network. Three types of water molecules adsorbed on polymer were identified: strongly dependent water, adsorbed water, a…
Selective Recognition and Sensing of Succinate vs. Other Aliphatic Dicarboxylates by Thiourea-Functionalized Gold Nanoparticles
2016
Gold nanoparticles functionalized with thiourea moieties have been used as selective colorimetric sensors for the naked-eye detection of succinate versus other aliphatic dicarboxylates, all of them as their TBA salts. The detection process is based on the interparticle aggregation triggered by coordination of the end-carboxylates to the thiourea moieties of two different nanoparticles. This nanoparticle aggregation results in a batochromic shift of the plasmon resonance band and a visual color change from red to blue.
Physicochemical Surface Properties of Various Intraocular Lenses
2001
<i>Purpose:</i> It is of major interest to understand how intraocular lens (IOL) surfaces interact with aqueous humor or tissues after implantation. Important parameters to describe the physicochemical surface properties are the contact angle and critical surface tension. Therefore, we performed measurements of the contact angle and critical surface tension of several commercially available IOLs. <i>Setting:</i> Department of Ophthalmology, Johannes Gutenberg University, Mainz, University Eye Hospital, Tübingen, and Max Planck Institute for Polymer Research, Mainz, Germany. <i>Methods:</i> A total of 17 commercially available standard quality IOL types (6…