Search results for "surface"
showing 10 items of 9345 documents
Micelles in Mixtures of Sodium Dodecyl Sulfate and a Bolaform Surfactant
2006
Mixtures composed of water, sodium dodecyl sulfate (SDS), and a bolaform surfactant with two aza-crown ethers as polar headgroups (termed Bola C-16) were investigated by modulating the mole ratios between the components. The two surfactants have ionic and nonionic, but ionizable, headgroups, respectively. The ionization is due to the complexation of alkali ions by the aza-crown ether unit(s). Structural, thermodynamic, and transport properties of the above mixtures were investigated. Results from surface tension, translational self-diffusion, and small angle neutron scattering ( SANS) are reported and discussed. Interactions between the two surfactants to form mixed micelles result in a com…
"Mutta niille ei voi mitään, joilla on aivoissa vika" : mielisairauden kansanomaiset tulkinnat 1900-luvun alkuvuosikymmenten modernisoituvassa Suomes…
2015
Artikkelissa tarkastellaan mielisairauden kansanomaisia tulkintoja 1900-luvun ensimmäisinä vuosikymmeninä, jolloin mielisairaita ja muita marginaaliryhmiä koskeva yhteiskunnallinen keskustelu kävi vilkkaana. Mielisairaat alkoivat degeneraatioteorioiden myötä näyttäytyä modernisoituvan yhteiskunnan ei- toivottuina toisina, joiden henkinen ja fyysinen rappio uskottiin perinnölliseksi. Mielisairaaloiden lukumäärää lisättiin, mutta merkittävä osa mielisairaiksi katsotuista eli yhä laitosten ulkopuolella, esimerkiksi elätteellä maaseudun yksityisissä perheissä. Artikkelissa selvitetään, miten mielisairaisiin suhtaudutaan aikakauden maallikkokerronnassa ja millaisia käsityksiä esitetään mielisair…
On-Surface Reactions
2015
On-surface synthesis constitutes a rapidly growing field of research due to its promising application for creating stable molecular structures on surfaces. While self-assembled structures rely on reversible interactions, on-surface synthesis provides the potential for creating long-term stable structures with well-controlled properties, for example superior electron transport for future molecular electronic devices. On-surface synthesis holds the promise for preparing insoluble compounds that cannot be produced in solution. Another highly exciting aspect of on-surface synthesis is the chance to discover new reaction pathways due to the two-dimensional confinement of the reaction educts. In …
Case-specific performance of MM-PBSA, MM-GBSA, and SIE in virtual screening.
2015
In drug discovery the reliable prediction of binding free energies is of crucial importance. Methods that combine molecular mechanics force fields with continuum solvent models have become popular because of their high accuracy and relatively good computational efficiency. In this research we studied the performance of molecular mechanics generalized Born surface area (MM-GBSA), molecular mechanics Poisson-Boltzmann surface area (MM-PBSA), and solvated interaction energy (SIE) both in their virtual screening efficiency and their ability to predict experimentally determined binding affinities for five different protein targets. The protein-ligand complexes were derived with two different app…
Late Pleistocene vertebrate - bearing deposits at San Teodoro Cave (North-Eastern Sicily): Preliminary data on faunal diversification and chronology
2008
Abstract This paper deals with the chronology and the possible correlations among levels of different excavated areas in the Pleistocene vertebrate-bearing deposits at the large San Teodoro Cave (North-Eastern Sicily). Two trenches have been excavated along the eastern side of the cave, located at a distance from the entrance, respectively, of 8 m ( α trench) and 28 m ( β trench) and at different depths. Lithological features, biometrical data from small mammals and ecological data from molluscs point to similar environmental conditions for the α trench deposits and those located along the eastern wall of the cave in the eastern part of the β trench. The same evidence, and the taphonomic fe…
Multi-resolution anisotropy studies of ultrahigh-energy cosmic rays detected at the Pierre Auger Observatory
2017
We report a multi-resolution search for anisotropies in the arrival directions of cosmic rays detected at the Pierre Auger Observatory with local zenith angles up to $80^\circ$ and energies in excess of 4 EeV ($4 \times 10^{18}$ eV). This search is conducted by measuring the angular power spectrum and performing a needlet wavelet analysis in two independent energy ranges. Both analyses are complementary since the angular power spectrum achieves a better performance in identifying large-scale patterns while the needlet wavelet analysis, considering the parameters used in this work, presents a higher efficiency in detecting smaller-scale anisotropies, potentially providing directional informa…
Surface modification of gold nanoparticles and nanoclusters
2016
Gold nanoparticles are used in many beneficial technological applications in biochemistry, medicine and electronics. Among them, monolayer protected gold nanoclusters (MPCs) have received a significant attention in the scientific community due to their well-defined atomic structure, which is important for fundamental studies of nanoparticles properties and their functionalization. These particles, with a precise number of atoms, exhibit size-dependent optical, chemical and electronic properties. The thesis focuses on the structure, preparation, characterization, and properties of MPCs. For multifunctional applications, gold nanoparticles are an ideal class of compounds for surface functiona…
Modelos de vida femeninos en el medio rural. Un caso de estudio en la Sierra del Segura (Albacete)
2019
La sobreemigració femenina i la masculinització són processos encara latents en gran part de la ruralitat espanyola. No obstant això, existeixen dones que mantenen o traslladen la seua residència a aquestes àrees. Així doncs, aquesta investigació tracta de caracteritzar les principals circumstàncies i patrons de vida que assumeixen i configuren les dones rurals. A partir d’un estudi de cas, la Sierra del Segura (Albacete), i mitjançant tècniques qualitatives, s’exposen quatre grans models de vida femenins. Per una part, dos que impliquen una trajectòria de localització ancorada en el món rural i el manteniment de rols de gènere, si bé el component generacional habilita divergències importan…
Excitation Transfer Engineering in Ce-Doped Oxide Crystalline Scintillators by Codoping with Alkali-Earth Ions
2018
This work has been supported by the European Social Fund Measure No. 09.3.3-LMT-K-712 activity Improvement of Researchers Qualification by Implementing the World-Class R&D Projects, and by grant #14.W03.31.0004 of the Russian Federation Government. Authors are grateful to CERN Crystal Clear Collaboration and COST Action TD1401 "Fast Advanced Scintillator Timing (FAST)" for support of collaboration.
Rational Chemical Multifunctionalization of Graphene Interface Enhances Targeted Cancer Therapy
2020
The synthesis of a drug delivery platform based on graphene was achieved through a step‐by‐step strategy of selective amine deprotection and functionalization. The multifunctional graphene platform, functionalized with indocyanine green, folic acid, and doxorubicin showed an enhanced anticancer activity. The remarkable targeting capacity for cancer cells in combination with the synergistic effect of drug release and photothermal properties prove the great advantage of a combined chemo‐ and phototherapy based on graphene against cancer, opening the doors to future therapeutic applications of this type of material.