Search results for "surface"

showing 10 items of 9345 documents

Quantum Motion of Chemisorbed Hydrogen on Ni Surfaces

1983

Quantum mechanical energy levels and wave functions have been calculated for the motion of chemisorbed hydrogen atoms on Ni surfaces. The results show considerable quantum effects for the adatom in both the ground and the excited states. The description of the adparticles as being delocalized along the surface offers a novel interpretation of several phenomena, in particular the vibrational excitations. Peer reviewed

nickel surfacesMaterials scienceSolid-state physicsHydrogenwave functionsGeneral Physics and Astronomychemistry.chemical_element02 engineering and technology01 natural sciencesCondensed Matter::Materials ScienceDelocalized electron0103 physical sciencesPhysics::Atomic and Molecular Clustersenergy levels010306 general physicsWave functionQuantumMechanical energyPhysicshydrogen atoms021001 nanoscience & nanotechnologychemistryChemisorptionExcited stateAtomic physics0210 nano-technologyPhysical Review Letters
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Wpływ stanu napięcia mięśni dna miednicy na ocenę poziomu zaburzeń erekcji i nietrzymania moczu u osób po prostatektomii radykalnej. Doniesienie wstę…

2017

Celem pracy była ocena, jak napięcie mięśni dna miednicy (MDM) mierzonego za pomocą sEMG wpływa na ocenę obiektywną i subiektywną trzymania moczu oraz zaburzeń erekcji. W badaniach uczestniczyło 10 mężczyzn, będących po zabiegu prostatektomii. Nasilenie objawów nietrzymania moczu oceniano na podstawie kwestionariusza ICIQ-SF, aktywność seksualną kwestionariuszem IIEF-5. Nie wykazano istotnego statystycznie związku między napięciem MDM, ocenianego za pomocą sEMG, a obiektywnymi wyznacznikami nietrzymania moczu, jednakże zaobserwowano tendencję, że niższe napięcie MDM występuje częściej u chorych ze wszystkimi dolegliwościami w ocenie subiektywnej.

nietrzymanie moczuerectile dysfunctionzaburzenia erekcjielektromiografia powierzchniowaQoL-Brefpelvic floor muscles urinary incontinencesurface electromyographyprostatektomia radykalnamięśnie dna miednicyradical prostatectomyGerontologia Współczesna
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Comparison of oxidoreductive enzyme activities in three coal tar creosote-contaminated soils

2019

This study used laboratory experiments to compare the effects of coal tar creosote on the activity of oxidoreductive enzymes in sandy loam, loamy sand and sandy clay loam soils. Different amounts of coal tar creosote were added to soil samples as follows: 0 (control), 2, 10 or 50 g kg–1 dry matter. The activity of soil dehydrogenases (DHAs), o-diphenol oxidase (o-DPO), catalase (CAT), nitrate reductase (NR) and peroxidases (POX) was determined. Contamination of soil with coal tar creosote affected oxidoreductase activity. Oxidoreductive enzyme activity following soil contamination with coal tar creosote was in the following order: DHAs > CAT > NR > POX > o-DPO in…

nitrate reductaseSoil testvirusespolycyclic aromatic hydrocarbonsSoil Science010501 environmental sciencesEnvironmental Science (miscellaneous)Nitrate reductasecomplex mixtures01 natural scienceslaw.inventionresistance indexBioremediationlawotorhinolaryngologic diseasesmedicineCoal tar0105 earth and related environmental sciencesEarth-Surface ProcessesChemistrycatalasedehydrogenases04 agricultural and veterinary sciencesSoil contaminationCreosoteEnvironmental chemistryLoamSoil water040103 agronomy & agriculture0401 agriculture forestry and fisheriesperoxidasesmedicine.drugSoil Research
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Direct Visualization of Molecule Deprotonation on an Insulating Surface

2012

Elucidating molecular-scale details of basic reaction steps on surfaces is decisive for a fundamental understanding of molecular reactivity within many fields, including catalysis and on-surface synthesis. Here, the deprotonation of 2,5-dihydroxybenzoic acid (DHBA) deposited onto calcite (101;4) held at room temperature is followed in situ by noncontact atomic force microscopy. After deposition, the molecules form two coexisting phases, a transient striped phase and a stable dense phase. A detailed analysis of high-resolution noncontact atomic force microscopy images indicates the transient striped phase being a bulk-like phase, which requires hydrogen bonds between the carboxylic acid moie…

noncontact atomic force microscopyCarboxylic acidCatecholsGeneral Physics and AstronomyMicroscopy Atomic ForceKelvin probe force microscopy530Calcium Carbonatechemistry.chemical_compoundDeprotonationPhase (matter)Materials TestingHydroxybenzoatesMoleculeGeneral Materials ScienceReactivity (chemistry)CarboxylateParticle Sizechemistry.chemical_classificationKelvin probe force microscopeHydrogen bondinsulating surfaceGeneral EngineeringElectric ConductivityMolecular ImagingNanostructuresCrystallographychemistrydeprotonationProtons
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Antineoplastic dosing in overweight and obese cancer patients: an Associazione Italiana Oncologia Medica (AIOM)/Associazione Medici Diabetologi (AMD)…

2021

Most anticancer molecules are administered in body-size-based dosing schedules, bringing up unsolved issues regarding pharmacokinetic data in heavy patients. The worldwide spread of obesity has not been matched by improved methods and strategies for tailored drug dosage in this population. The weight or body surface area (BSA)-based approaches may fail to fully reflect the complexity of the anthropometric features besides obesity in cancer patients suffering from sarcopenia. Likewise, there is a lack of pharmacokinetic data on obese patients for the majority of chemotherapeutic agents as well as for new target drugs and immunotherapy. Therefore, although the available findings point to the …

obesityCancer Researchmedicine.medical_specialtypharmacokinetic parametersConsensusBSAcancer drug dosingPopulationchemotherapy doseAntineoplastic AgentsReviewOverweightNODosing schedulesNeoplasmsPhysiciansInternal medicineHumansMedicineDosingLS4_3educationBody surface areaeducation.field_of_studybusiness.industryCancerCytotoxic chemotherapymedicine.diseaseOncologyBSA; cancer drug dosing; chemotherapy dose; obesity; pharmacokinetic parametersPosition paperBSA; cancer drug dosing; chemotherapy dose; obesity; pharmacokinetic parameters; Consensus; Humans; Obesity; Antineoplastic Agents; Neoplasms; Physiciansmedicine.symptombusinessESMO Open
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Estudio de la eficacia de la plicatura del tendón cantal lateral con anclaje en Y en el síndrome del ojo seco evaporativo

2018

INTRODUCCIÓN El síndrome de ojo seco (SOS) es una patología muy prevalente que afecta a la calidad de vida de los pacientes. El manejo terapéutico del SOS es complejo y varía en función del subtipo de SOS que se esté tratando. No se ha demostrado hasta el momento ninguna técnica quirúrgica que cure aquellos SOS por malposición palpebral de causa intrínseca. HIPÓTESIS, MATERIAL Y MÉTODOS La hipótesis del estudio es que la plicatura del tendón cantal lateral con anclaje en Y es eficaz en el tratamiento del SOS evaporativo de causa intrínseca. Se ha realizado un estudio prospectivo de casos y controles en el que se han reclutado en el periodo de tiempo existente entre noviembre de 2016 y novie…

ocular surface disease indextendon cantal lateralOjo secoUNESCO::CIENCIAS MÉDICAS:CIENCIAS MÉDICAS [UNESCO]plicatura
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The effects of microwave radiation generated by mobile phones on the tear film

2021

Abstract Electromagnetic radiation (ER) emitted by mobile phones and other modern devices has potentially harmful effects on ocular tissue. Their effects on the eye surface and tear film are little known so far. The aim of this paper was to investigate the effects of ER emitted by the phone mobile on the tear film. For this study, we selected a total of 50 subjects, young, healthy, without chronic treatment, who are not contact lens wearers and who have no history of ophthalmic surgery. Schirmer I test, tear pH and tear ferning test (TFT) were performed on all subjects before (“-pre”) being exposed to ER emitted by the mobile phone and after (“-post”) exposure for 5 minutes, the pH and TFT …

ocular surfacebusiness.industryRelectromagnetic radiationdry eye diseaseeye diseases03 medical and health sciences0302 clinical medicine030220 oncology & carcinogenesis030221 ophthalmology & optometryMedicineOptoelectronicsMedicinesense organsbusinessMicrowavetear filmtRevista Romana de Medicina de Laborator
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Increasing Yield and Antioxidative Performance of Litchi Pericarp Procyanidins in Baked Food by Ultrasound-Assisted Extraction Coupled with Enzymatic…

2018

Extraction with organic solvents is a traditional method to isolate bioactive compounds, which is energy-wasting and time-consuming. Therefore, enzyme and ultrasound treatments were combined to assist the extraction of oligomeric procyanidins from litchi pericarp (LPOPC), as an innovative approach to replace conventional extraction methods. Under optimum conditions (enzyme concentration 0.12 mg/mL, ultrasonic power 300 W, ultrasonic time 80 min, and liquid/solid ratio 10 mL/g), the yield of LPOPC could be improved up to 13.5%. HPLC analysis indicated that the oligomeric procyanidins (OPC) content of LPOPC from proposed extraction was up to 89.6%, mainly including (&minus

oligomeric procyanidinsPharmaceutical Sciencelitchi pericarpChemical FractionationHigh-performance liquid chromatographyPeroxideAntioxidantsArticleAnalytical Chemistrylcsh:QD241-441Lipid peroxidationchemistry.chemical_compound0404 agricultural biotechnologylcsh:Organic chemistryLitchiDrug DiscoveryRSM (Response Surface Methodology)Physical and Theoretical ChemistryChromatography High Pressure LiquidAnalysis of VarianceChromatographyMolecular StructurePlant ExtractsOrganic ChemistryExtraction (chemistry)04 agricultural and veterinary sciences040401 food sciencebaked foodMonomerProanthocyanidinchemistryUltrasonic WavesChemistry (miscellaneous)Yield (chemistry)Molecular MedicineHPLCProcyanidin A1Molecules
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Optical Absorption of Excimer Laser‐Induced Dichlorine Monoxide in Silica Glass and Excitation of Singlet Oxygen Luminescence by Energy Transfer from…

2021

An optical absorption (OA) band of interstitial dichlorine monoxide molecules with peak at 4.7 eV and halfwidth 0.94 eV is identified in F2 laser - irradiated (photon energy=7.9 eV) synthetic silica glass bearing both interstitial O2 and Cl2 molecules. Alongside with intrinsic defects, this OA band can contribute to solarization of silica glasses produced from SiCl4. While the formation of ClClO is confirmed by its Raman signature, its structural isomer ClOCl may also contribute to this induced OA band. Thermal destruction of this band between 300C and 400C almost completely restores the pre-irradiation concentration of interstitial Cl2. An additional weak OA band at 3.5 eV is tentatively a…

optical absorptionMaterials scienceInfraredinterstitial chlorinemedicine.medical_treatmentFOS: Physical sciencesPhoton energyPhotochemistrysinglet oxygenchemistry.chemical_compoundsymbols.namesakesilica glassMaterials ChemistrymedicineElectrical and Electronic Engineering[PHYS]Physics [physics]Condensed Matter - Materials ScienceExcimer laserSinglet oxygenMaterials Science (cond-mat.mtrl-sci)Surfaces and InterfacesCondensed Matter PhysicsSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsDichlorine monoxidechemistryglass nanovoidssymbolschlorine oxidesluminescenceactivationAbsorption (chemistry)Raman spectroscopyLuminescence
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Photoluminescence time decay of surface oxygen deficient centers in un‐doped and Ge‐doped silica

2005

We report a study of the emission decay from the singlet excited state of two fold coordinated Si and Ge centers stabilized on the surface of silica and Ge-doped silica. The PL lifetimes are of the order of nanoseconds and increase on decreasing the temperature. The results suggest that, for the surface centers, the phonon assisted intersystem-crossing process linking the excited states affects the decay rates, is effective down to low temperatures and is distributed because of the inhomogeneity of the defects. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)

optical fiberSurface oxygenPhotoluminescenceradiation effectChemistryPhononDopingTime decayAnalytical chemistryNanosecondExcited stateradiation-induced attenuationSinglet stateAtomic physicsphysica status solidi (c)
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