Search results for "switch."
showing 10 items of 463 documents
Conformational and Tautomeric Control by Supramolecular Approach in Ureido-N-iso-propyl,N’-4-(3-pyridin-2-one)pyrimidine
2019
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Design and control of NxN microphotonics switch array based on non-adiabatic theory
2021
The development of linear programmable nanophotonics processors requires large number of couplers to route light through the photonic chip. This number scales nonlinearly with the number of inputs and outputs [1] , making the device increasingly complex to control, and bulky. Regarding the latter aspects, densely packed array of waveguides would be an elegant solution. In order to couple selectively the different –at first isolated- waveguides, we rely on the analogy between the equations governing the unidirectional propagation in optics and the time evolution in quantum physics [2] . Namely, as seen in fig. 1-a , if each waveguide can be considered as a photonic energy level, then a trans…
Supramolecular hierarchy among halogen and hydrogen bond donors in light-induced surface patterning
2015
Halogen bonding, a noncovalent interaction possessing several unique features compared to the more familiar hydrogen bonding, is emerging as a powerful tool in functional materials design. Herein, we unambiguously show that one of these characteristic features, namely high directionality, renders halogen bonding the interaction of choice when developing azobenzene-containing supramolecular polymers for light-induced surface patterning. The study is conducted by using an extensive library of azobenzene molecules that differ only in terms of the bond-donor unit. We introduce a new tetrafluorophenol-containing azobenzene photoswitch capable of forming strong hydrogen bonds, and show that an io…
Field- and irradiation-induced phenomena in memristive nanomaterials
2016
The breakthrough in electronics and information technology is anticipated by the development of emerging memory and logic devices, artificial neural networks and brain-inspired systems on the basis of memristive nano-materials represented, in a particular case, by a simple 'metal-insulator-metal' (MIM) thin-film structure. The present article is focused on the comparative analysis of MIM devices based on oxides with dominating ionic (ZrOx, HfOx) and covalent (SiOx, GeOx) bonding of various composition and geometry deposited by magnetron sputtering. The studied memristive devices demonstrate reproducible change in their resistance (resistive switching - RS) originated from the formation and …
Rugged Large Volume Injection for Sensitive Capillary LC-MS Environmental Monitoring
2017
A rugged and high throughput capillary column (cLC) LC-MS switching platform using large volume injection and on-line automatic filtration and filter back-flush (AFFL) solid phase extraction (SPE) for analysis of environmental water samples with minimal sample preparation is presented. Although narrow columns and on-line sample preparation are used in the platform, high ruggedness is achieved e.g. injection of 100 non-filtrated water samples would did not result in a pressure rise/clogging of the SPE/capillary columns (inner diameter 300 µm). In addition, satisfactory retention time stability and chromatographic resolution were also features of the system. The potential of the platform for …
Multiscale Model Selection for High-Frequency Financial Data of a Large Tick Stock by Means of the Jensen–Shannon Metric
2014
Modeling financial time series at different time scales is still an open challenge. The choice of a suitable indicator quantifying the distance between the model and the data is therefore of fundamental importance for selecting models. In this paper, we propose a multiscale model selection method based on the Jensen–Shannon distance in order to select the model that is able to better reproduce the distribution of price changes at different time scales. Specifically, we consider the problem of modeling the ultra high frequency dynamics of an asset with a large tick-to-price ratio. We study the price process at different time scales and compute the Jensen–Shannon distance between the original…
RNAs That Behave Like Prions
2020
The term “prion” was originally coined to describe the proteinaceous infectious agents involved in mammalian neurological disorders. More recently, a prion has been defined as a nonchromosomal, protein-based genetic element that is capable of converting the copies of its own benign variant into the prion form, with the new phenotypic effects that can be transmitted through the cytoplasm. Some prions are toxic to the cell, are able to aggregate and/or form amyloid structures, and may be infectious in the wild, but none of those traits are seen as an integral property of all prions. We propose that the definition of prion should be expanded, to include the inducible transmissible entities und…
Endpoint Admission Control with Delay Variation Measurements for QoS in IP Networks.
2002
In this paper we describe a novel Endpoint Admission Control scheme (EAC) for IP telephony. EAC mechanisms are driven by independent measurements taken by the edge nodes on a flow of packets injected in the network to probe the source to destination path. Our scheme is characterized by two fundamental features. First, it does not rely on any additional procedure in internal network routers other than the capability to apply different service priorities to probing and data packets. Second, the connection admission decision is based on the analysis of the probing flow delay variation statistics. Simulation results, which focus on a IP telephony scenario, show that, despite the lack of core ro…
PCP-DV: An End-to end Admission Control Mechanism for IP Telephony
2001
In this paper we describe a novel endpoint admission control mechanism for IP telephony:the PCP-DV which is characterized by two fundamental features. First, it does not rely on any additional procedure in internal network routers other than the capability to apply different service priority to probing and data packets. Second, the triggering mechanism for the connection admission decision is based on the analysis of the delay variation statistics over the probing flow. Numerical results for an IP telephony traffic scenario prove that 99th delay percentiles not greater than few ms per router are guaranteed even in overload conditions.
Depletion of polyubiquitin encoded by the UBI4 gene confers pleiotropic phenotype to Candida albicans cells.
2003
We have studied the roles of polyubiquitin in Candida albicans physiology. Heterologous expression of the C. albicans polyubiquitin (UBI4) gene in a ubi4 Saccharomyces cerevisiae strain suppressed the mutant phenotype (hypersensitivity to heat shock). A heterozygous strain UBI4/Deltaubi4::hisG, obtained following the ura-blaster procedure, was used to construct a conditional mutant using a pCaDis derivative plasmid. By serendipity we isolated the UBI4 conditional mutant as well as a UBI4 mutant containing a non-functional MET3 promoter. Depletion of polyubiquitin conferred pleiotropic effects to mutant cells: (i) a limited increased sensitivity to mild heat shock; (ii) increased formation o…