Search results for "synthesis"
showing 10 items of 2844 documents
A theoretical study on NHC-catalysed enantioselective cycloaddition of ketenes and 3-aroylcoumarins: mechanism and enantioselectivity.
2018
NHC-catalysed enantioselective cycloaddition of ketenes to 3-aroylcoumarins to yield dihydrocoumarin-fused dihydropyranones has been investigated using DFT methods at the B3LYP/6-31G* and MPWB1K/6-311G** computational levels. Two plausible mechanisms have been studied: the “ketene-first” mechanism A and the “coumarin-first” mechanism B. An analysis of the activation Gibbs free energies involved in the two competitive pathways makes it possible to rule out the pathway associated with the “coumarin-first” mechanism B. The first step of the “ketene-first” mechanism A is the formation of zwitterionic intermediate IN1-Zvia a nucleophilic attack of NHC 1 on ketene 2. A [4 + 2] cycloaddition throu…
Alcohol consumption and hormonal alterations related to muscle hypertrophy: a review
2014
Detrimental effects of acute and chronic alcohol (ethanol) consumption on human physiology are well documented in the literature. These adversely influence neural, metabolic, cardiovascular, and thermoregulatory functions. However, the side effects of ethanol consumption on hormonal fluctuations and subsequent related skeletal muscle alterations have received less attention and as such are not entirely understood. The focus of this review is to identify the side effects of ethanol consumption on the major hormones related to muscle metabolism and clarify how the hormonal profiles are altered by such consumption.
Metabolic Adaptation and Protein Complexes in Prokaryotes.
2012
Protein complexes are classified and have been charted in several large-scale screening studies in prokaryotes. These complexes are organized in a factory-like fashion to optimize protein production and metabolism. Central components are conserved between different prokaryotes; major complexes involve carbohydrate, amino acid, fatty acid and nucleotide metabolism. Metabolic adaptation changes protein complexes according to environmental conditions. Protein modification depends on specific modifying enzymes. Proteins such as trigger enzymes display condition-dependent adaptation to different functions by participating in several complexes. Several bacterial pathogens adapt rapidly to intrace…
Trafficking of the human transferrin receptor in plant cells: effects of tyrphostin A23 and brefeldin A.
2006
Plant cells possess much of the molecular machinery necessary for receptor-mediated endocytosis (RME), but this process still awaits detailed characterization. In order to identify a reliable and well-characterized marker to investigate RME in plant cells, we have expressed the human transferrin receptor (hTfR) in Arabidopsis protoplasts. We have found that hTfR is mainly found in endosomal (Ara7- and FM4-64-positive) compartments, but also at the plasma membrane, where it mediates binding and internalization of its natural ligand transferrin (Tfn). Cell surface expression of hTfR increases upon treatment with tyrphostin A23, which inhibits the interaction between the YTRF endocytosis signa…
Performances Comparison for a Rotating Shaft Suspended by 4-Axis Radial Active Magnetic Bearings via 𝜇 -Synthesis, Loop-Shaping Design, and Sub ( 𝐻…
2011
The control systems applied on active magnetic bearing are several. A perfect levitation is characterized by maintaining the operating point condition that is characterized by the center of stator coincident with the geometric center of shaft. The first controller implemented for this purpose is PID controller that is characterized by an algorithm that leads the amplifier to produce control current until the operating point condition is not reached, this is obtained by an integration operator. The effect of an integrator is essential but not necessary for a centered levitation for example in the robust control characterized by a dynamic model depended on plant of system so that it depends o…
Continuous hydrothermal synthesis of inorganic nanopowders in supercritical water: towards a better control of the process
2009
International audience; A hydrothermal synthesis process working in supercritical conditions (T > 374 °C, P > 22 MPa) and in a continuous mode has been developed for inorganic nanopowder synthesis. This paper presents a review of the past 5 years of research conducted on this process. Numerous materials (oxides: ZrO2, TiO2, Fe2O3..., ferrites: Fe2CoO4..., or BaZrO3) were obtained with specific features. Some technical issues have been solved, that are presented here. Heat transfer was studied, leading to a more efficient design of the reactor. Future developments have been examined through process engineering, in which our group is engaged, especially through CFD modelling.
Industrial Microreactor Process Development up to Production
2008
This chapter is about industrial applications of microprocess technology. Industry is not very active in publishing not only because of confidentiality reasons but also because of the absence of direct need for a corresponding profile. Thus, one cannot expect that the ongoing developments can be shown with a similar degree of completeness, clarity and detailedness, as this is possible for reviewing scientific contributions from academy with a wealth of peer-reviewed papers. Especially, the information of major interest of what has been transferred to production and how do the companies make profit with the new technology is usually kept secret. Thus, it has to be accepted that some informat…
Method for designing PI-type fuzzy controllers for induction motor drives
2001
The paper illustrates a new systematic method for designing PI-type fuzzy controllers for direct field-oriented controlled induction motor drives. First, linear and decoupled models expressing the dynamics of speed, rotor flux, direct and inquadrature stator currents are derived using a nonlinear static compensator and choosing convenient input variables. Then, to guide the dynamics of the above quantities, four conventional PI controllers are designed independently, choosing their bandwidths conveniently. Finally, the input and output scale factors of PI-type fuzzy controllers are derived from the conventional PI controller parameters. The whole drive controller also includes a rotor flux …
Stereo to Wave-Field Synthesis music up-mixing: An objective and subjective evaluation
2008
Sound source separation techniques are known to be very useful in many applications. High fidelity and audio oriented applications are a challenging issue in this topic, however, existing algorithms are far from performing with such a high quality. In this paper, a subjective and objective evaluation are carried out for several algorithms designed for dealing with stereo music mixtures. The performance of these algorithms applied to acoustic scene resynthesis in a Wave Field Synthesis system is discussed.
Hardware implementation of a robust adaptive filter: Two approaches based in High-Level Synthesis design tools
2009
Abstract Adaptive filters are used in a wide range of applications. Impulsive noise affects the proper operation of the filter and the adaptation process. This noise is one of the most damaging types of signal distortion, not always considered when implementing algorithms. Field Programmable Gate Array (FPGA) are widely used for applications where timing requirements are strict. Nowadays, two main design processes can be followed, namely, Hardware Description Language (HDL) and a High Level Synthesis (HLS) design tool for embedded system design. This paper describes the FPGA implementation of an adaptive filter robust to impulsive noise using two approaches based in HLS and the implementati…