Search results for "tecnologie"

Carbon nitride nanosheets for the selective photocatalytic oxidation of 5-hydroxymethyl-2-furfural to 2,5-furandicarboxyaldehyde in water suspension

2017

Carbon nitride nanosheets for the selective photocatalytic oxidation of 5-hydroxymethyl-2-furfural to 2,5-furandicarboxyaldehyde in water suspension

Carbon nitride-hydrogen peroxide adduct for selective photo-oxidation

Application of thermally exfoliated g-C3N4 for a green selective photocatalytic oxidation of 5-hydroxymethyl-2-furfural

2016

Graphitic carbon nitride assisted partial photocatalytic oxidation of 5-hydroxymethyl-2-furfural (HMF) in aqueous medium was investigated. Different carbon nitride precursors were considered, being melamine the one yielding the most efficient photocatalyst. The obtained 30% selectivity of HMF oxidation towards 2,5-furandicarboxaldehyde (FDC) is higher than those reported up to now. A further thermal exfoliation of the g-C3N4 samples showed under artificial light irradiation both an enhanced photocatalytic activity in conversion of HMF, and selectivity (ca. 42-45 %) towards FDC. The performance of the catalysts increased when the experiments were carried out under real outdoor illumination, …

Selective photocatalytic oxidation of 5-hydroxymethyl-2-furfural to 2,5-furandicarboxyaldehyde in aqueous suspension of g-C3N4

2017

Graphitic carbon nitride assisted partial photocatalytic oxidation of 5-hydroxymethyl-2-furfural (HMF) in aqueous medium was investigated. Different carbon nitride precursors were considered, being melamine the one yielding the most efficient photocatalyst. The obtained 30% selectivity of HMF oxidation to 2,5-furandicarboxaldehyde (FDC) is higher than those reported up to now. A further thermal exfoliation of the g-C3N4 samples showed under artificial light irradiation both an enhanced photocatalytic activity in conversion of HMF, and selectivity (ca. 42–45%) to FDC. The performance of the catalysts increased when the experiments were carried out under real outdoor illumination, reaching 50…

Selective photocatalytic oxidation of 5-hydroxymethyl-2-furfural in aqueous suspension of polymeric carbon nitride and its adduct with H2O2 in a sola…

2018

Abstract This work reports a study on the reactivity of polymeric carbon nitride (PCN) and PCN-H2O2 adduct samples for sunlight photocatalytic selective oxidation reactions. The characterization of these materials was reported in a previous paper where the reactivity towards the partial oxidation of 5-hydroxymethylfurfural (HMF) was studied by using two different laboratory scale photoreactors; one irradiated by UV lamps and the other one by natural sunlight. In the present study it has been confirmed the effectiveness of these C3N4 based materials for the selective partial oxidation of HMF to FDC (2,5-furandicarboxaldehyde) in aqueous medium in a pilot plant photoreactor irradiated by natu…

POMOLOGICAL TRAITS, SENSORY CHARACTERISTICS, AND ANTIOXIDANT ACTIVITY IN FRUITS OF NINE LOQUAT CULTIVARS GROWN IN SICILY

2015

Loquat cultivation in Italy currently aims at offering a wider choice of cultivars to growers. The present study determined commercial quality, characterized the antioxidant capacity, and quantified the major bioactive compounds of some local ('BRT 20', 'Claudia', 'Nespolone di Trabia', 'Sanfilippara') and international ('Algerie', 'El Buenet', 'Bueno', 'Golden Nugget' and 'Peluche') cultivars. Fruit was harvested at commercial ripening and chemical-physical determinations of weight, diameters, skin and flesh color, soluble solid content, tritable acidity, antioxidant activity and polyphenol content, and sensory analyses were carried out. Data showed a large variability among genotypes and …

Properties Augmentation of Cast Hypereutectic Al–Si Alloy Through Friction Stir Processing

2022

AbstractThe present endeavour is to augment mechanical attributes via friction stir processing (FSP) in hypereutectic aluminium–silicon castings by the means of microstructural modifications and defects reduction. Wherein, the study proceeds with mainly two approaches namely, alteration in tool revolution (TR) and the number of FSP passes. The prepared specimens were evaluated investigating volume fraction of porosities, microstructural characterizations and microhardness. Therefrom, the specimen with highest number of passes delivered most uniform properties resulting from the reduction in casting porosities and refined silicon particle uniform distribution throughout friction stir process…

Confronto tra attività catalitica e fotocatalitica dell’eteropoliacido di Keggin H3PW12O40 supportato su ossidi o su nanotubi di carbonio

2015

Catalytic and catalytic photo-assisted dehydration of 2-propanol to form propene in gas-solid regime at atmospheric pressure and 80°C was carried out by using a Keggin heteropolyacid H3PW12O40 (PW12) supported on different oxides. Binary materials have been prepared by impregnation of PW12 on different commercial and home prepared supports (TiO2, SiO2 or carbon nanotubes). The supported Keggin PW12 species played a key role both for the catalytic and the photo-assisted catalytic reactions, due to their strong acidity and ability to form strong oxidant species under UV irradiation, respectively. The contemporary presence of heat and UV light improved the activity of almost all POM supported …

Influenza di lieviti diversi sulla composizione e sul profilo sensoriale di vini Catarratto

2013

In-situ gelling xyloglucan formulations as 3D artificial niche for adipose stem cell spheroids.

2020

Abstract Three-dimensional spheroidal cell aggregates of adipose stem cells (SASCs) are a distinct upstream population of stem cells present in adipose tissue, with enhanced regeneration properties in vivo. The preservation of the 3D structure of the cells, from extraction to administration, can be a promising strategy to ensure optimal conditions for cell viability and maintenance of stemness potential. With this aim, an artificial niche was created by incorporating the spheroids into an injectable, in-situ gelling solution of partially degalactosylated xyloglucan (dXG) and an ad hoc formulated culture medium for the preservation of stem cell spheroid features. The evolution of the mechani…