Search results for "thesis"

showing 10 items of 4193 documents

Electrosynthesis 2.0 in 1,1,1,3,3,3-hexafluoroisopropanol/amine mixtures

2020

540 Chemistry and allied sciencesChemistry540 ChemieElectrochemistryOrganic chemistryAmine gas treatingElectrosynthesisCatalysis
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A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution

2018

We report herein the synthesis and chromo-fluorogenic behaviour of a new probe 1 containing a boron-dipirromethene (BODIPY) unit electronically connected with a dithia-dioxa-aza macrocycle. Acetonitrile and water-acetonitrile 95:5 v/v solutions of the probe showed an ICT band in the visible zone and are nearly non-emissive. When acetonitrile was used as solvent, addition of Hg(II) and trivalent metal cations induced an hypsochromic shift of the absorption band and moderate emission enhancements. A highly selective response was obtained when using competitive media such as wateracetonitrile 95:5 v/v. In this case only Hg(II) induced a hypsochromic shift of the absorption band and a marked em…

:Ciências Químicas [Ciências Naturais]BodipyHeterocyclesColorimetric sensor010402 general chemistryPhotochemistry01 natural sciencesCatalysisMetalchemistry.chemical_compoundSynthesisQUIMICA ORGANICABODIPYMaterials ChemistryFluorimetric sensorDetection in aqueous solutionAcetonitrileDual channel chemosensorCrown etherchemistry.chemical_classificationAqueous solutionScience & Technology010405 organic chemistryChemistryOptical chemosensorQUIMICA INORGANICAWaterGeneral ChemistryMercuryCiências Naturais::Ciências QuímicasFluorescence3. Good health0104 chemical sciencesAbsorption bandvisual_artHg (II)Coordinationvisual_art.visual_art_mediumHypsochromic shiftfluorescenceBODIPYCrown ether
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Karbociklisko amīnu- potenciālo NMDA receptora antagonistu sintēze un īpašību izpēte

2000

:NATURAL SCIENCES::Chemistry::Organic chemistry [Research Subject Categories]CikloheksānamīniOrganiskā ķīmijaKarbocikliskie amīniOrganiskā sintēzeOrganic synthesis
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CT angiography for the assessment of EVAR complications : a pictorial review

2022

Aortic aneurysm; Blood vessel prosthesis implantation; Endovascular procedures Aneurisma aórtico; Implantación de prótesis de vasos sanguíneos; Procedimientos endovasculares Aneurisma aòrtic; Implantació de pròtesis de vasos sanguinis; Procediments endovasculars Endovascular aneurysm repair (EVAR) is a minimally invasive treatment proposed as an alternative to open repair in patients with abdominal aortic aneurysms. EVAR consists in a stent-graft placement within the aorta in order to exclude the aneurysm from arterial circulation and reduce the risk of rupture. Knowledge of the various types of devices is mandatory because some stents/grafts are more frequently associated with complication…

:intervenciones quirúrgicas::procedimientos quirúrgicos cardiovasculares::procedimientos quirúrgicos vasculares::procedimientos endovasculares [TÉCNICAS Y EQUIPOS ANALÍTICOS DIAGNÓSTICOS Y TERAPÉUTICOS]:Cardiovascular Diseases::Vascular Diseases::Aneurysm::Aortic Aneurysm::Aortic Aneurysm Abdominal [DISEASES]Aortic aneurysmR895-920:diagnóstico::técnicas y procedimientos diagnósticos::diagnóstico por imagen::interpretación de imágenes asistida por ordenador::tomografía computarizada por rayos X::angiografía por tomografía computarizada [TÉCNICAS Y EQUIPOS ANALÍTICOS DIAGNÓSTICOS Y TERAPÉUTICOS]:Otros calificadores::Otros calificadores::/diagnóstico por imagen [Otros calificadores]:enfermedades cardiovasculares::enfermedades vasculares::aneurisma::aneurisma de la aorta::aneurisma de la aorta abdominal [ENFERMEDADES]Blood vessel prosthesis implantation:Surgical Procedures Operative::Cardiovascular Surgical Procedures::Vascular Surgical Procedures::Endovascular Procedures [ANALYTICAL DIAGNOSTIC AND THERAPEUTIC TECHNIQUES AND EQUIPMENT]Medical physics. Medical radiology. Nuclear medicineVasos sanguinis - CirurgiaEndovascular procedureEndovascular procedures:Diagnosis::Diagnostic Techniques and Procedures::Diagnostic Imaging::Image Interpretation Computer-Assisted::Tomography X-Ray Computed::Computed Tomography Angiography [ANALYTICAL DIAGNOSTIC AND THERAPEUTIC TECHNIQUES AND EQUIPMENT]cardiovascular systemRadiology Nuclear Medicine and imagingAbdominalStentsAngiografiacardiovascular diseasesComputed tomography angiography:Other subheadings::Other subheadings::/diagnostic imaging [Other subheadings]Educational ReviewAneurisma abdominal - Imatgeria
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Revised rates for the stellar triple-alpha process from measurement of C-12 nuclear resonances

2005

4 pages, 3 figures.-- PMID: 15650733 [PubMed].

ASTROPHYSICSchemistry.chemical_elementAstrophysics7. Clean energy01 natural sciencesTriple-alpha processNuclear physicsNucleosynthesis0103 physical sciencesELEMENTSPARTICLESBETA-DECAY010303 astronomy & astrophysicsHeliumPhysicsNUCLEOSYNTHESISMultidisciplinary010308 nuclear & particles physicsB-12Carbon-12Cell BiologyAlpha particleStarsSupernovachemistry13. Climate actionExcited stateSTARS
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Periscopes, chimneys, sandwich and VORTEC to facilitate abdominal and thoracoabdominal aortic aneurysm repair

2012

The VORTEC (VIABAHN open revascularization technique) and the chimney graft technique are tools with which to maintain or restore blood flow to the aortic branches and can be used intentionally or as a bailout procedure in open surgery or endovascular procedures. VORTEC is a stent graft-based vascular connection technique that achieves end-to-end anastomosis configuration; it is especially useful when the traditional suture technique proves (can be) cumbersome. It is also a speedy tool with virtually no blood flow interruption and no anastomotic bleeding, and patency rates compare favorably with sutured anastomosis. The chimney/periscope, as well as the sandwich graft technique (CHIMPES), i…

Abdominal aorta Thoracic aorta Aortic aneurysm Blood vessel prosthesis Endovascular procedures
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Machine learning of microbial interactions using abductive ILP and hypothesis frequency/compression estimation

2021

Interaction between species in microbial communities plays an important role in the functioning of all ecosystems, from cropland soils to human gut microbiota. Many statistical approaches have been proposed to infer these interactions from microbial abundance information. However, these statistical approaches have no general mechanisms for incorporating existing ecological knowledge in the inference process. We propose an Abductive/Inductive Logic Programming (A/ILP) framework to infer microbial interactions from microbial abundance data, by including logical descriptions of different types of interaction as background knowledge in the learning. This framework also includes a new mechanism …

Abductive/Inductive Logic Programming (A/ILP)[SDV] Life Sciences [q-bio]inferencehypothesis frequencymachine learning of ecological networksinteraction networkcomputer scienceestimation (HFE)
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Elucidation of the biosynthesis and degradation of allantofuranone by isotopic labelling and fermentation of modified precursors.

2010

Feeding experiments with the ascomycete Allantophomopsis lycopodina indicated that the potent fungistatic allantofuranone is biosynthesized from phenylalanine. Further experiments with synthetic precursors gave evidence that the naturally occurring polyporic acid serves as a key intermediate in the biosynthesis. In addition to the formation of allantofuranone, its abiotic and metabolic degradation were investigated.

Abiotic componentAntifungal AgentsOrganic ChemistryFungiPolyporic acidPhenylalanineBiologyBiochemistryIsotopic labelingchemistry.chemical_compoundBiosynthesischemistryBiochemistry4-ButyrolactoneLabellingIsotope LabelingFermentationMolecular MedicineDegradation (geology)FermentationMolecular BiologyChembiochem : a European journal of chemical biology
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Mannitol-producing tobacco exposed to varying levels of water, light, temperature and paraquat

2007

Transgenic mannitol-producing (+mtlD) and wild-type (-mtlD) tobacco plants were exposed to water deficit, varying light intensities, low temperatures, and paraquat applications to test whether mannitol was involved in protection against abiotic stresses. In the water deficit experiment, -mtlD and +mtlD plants were fully irrigated [100% evapotranspiration (ET)] or received 25% ET for 40 d. Water deficit reduced the relative water content (RWC) of both types of plant starting on day 22 and the total stem length (TSL) of -mtlD 25% ET plants after 11 d, whereas TSL of +mtlD 25% ET was reduced only after 34 d. After 30 days of water deficit, a higher percentage of mature foliage was retained by …

Abiotic componentDehydrogenaseHorticulturePhotosynthesisWater deficitchemistry.chemical_compoundHorticultureAgronomyParaquatchemistryEvapotranspirationGeneticsmedicineMannitolWater contentmedicine.drugThe Journal of Horticultural Science and Biotechnology
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Origin of Life, Theories Of

2017

Modern advances in biology, geology, chemistry, and astronomy have allowed us to elaborate models and hypotheses on the origin of life on Earth within the framework of the evolutionary theory. About four billion years ago, a rich inventory of organic compounds accumulated on the planet, as a product of volcanic, atmospheric, and cosmic chemistry. As chemical systems became increasingly more complex, a critical point was reached with the appearance of self-replicative polymers. This marks the possibility of optimizing abiotic systems by natural selection and historical contingency, which were added to the determinism of abiotic chemistry. A landmark of the origin of life was the articulation…

Abiotic componentProtocellRNA world hypothesisPaleontologyPrebiotic chemistryNatural selectionAbiogenesisDeterminismGeologyEvolutionary theoryAstrobiology
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