Search results for "thio­cyanate"

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Crystal structure of bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ2N2,N3]bis(thiocyanato-κS)copper(II)

2016

The structure of the title compound is similar to that of the related complexes [Co(C12H8N4S)2(N3)2] and [Ni(C12H8N4S)2(N3)2] in which the azide ion is substituted by the thio­cyanate group. The CuN4S2 octa­hedron is more distorted than the CoN6 and NiN6 octa­hedra.

crystal structureStereochemistrychemistry.chemical_elementThio-Crystal structure010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesChlorideResearch CommunicationsMetalchemistry.chemical_compoundmedicine25-bis(pyridin-2-yl)-134-thiadiazoleGeneral Materials Sciencecopper complexCoordination geometrythio­cyanate ligandCrystallographyHydrogen bondGeneral Chemistrythiocyanate ligandCondensed Matter PhysicsCopper0104 chemical sciencesCrystallographychemistryQD901-999visual_artvisual_art.visual_art_mediumDiazole25-bis­(pyridin-2-yl)-134-thia­diazolemedicine.drugActa Crystallographica Section E Crystallographic Communications
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Crystal structure, spectroscopic characterization and Hirshfeld surface analysis of trans-di­aqua­[2,5-bis­(pyridin-4-yl)-1,3,4-oxa­diazole]di­thio­c…

2019

The NiII atom in the mononuclear title complex has an almost regular octa­hedral N4O2 coordination geometry. In the crystal, the complex mol­ecules are linked in a three-dimensional network through strong O—H⋯N hydrogen bonds.

crystal structurespectroscopyThio-chemistry.chemical_elementcoordination complexCrystal structure010403 inorganic & nuclear chemistry01 natural sciencesCoordination complexResearch CommunicationsCrystalchemistry.chemical_compound134-oxadiazoleGeneral Materials Sciencethio­cyanatechemistry.chemical_classificationthiocyanateCrystallographyThiocyanate010405 organic chemistryHydrogen bondGeneral ChemistryHirshfeld analysisCondensed Matter Physics0104 chemical sciencesCrystallographyNickel134-oxa­diazolechemistryQD901-999hydrogen bondsDiazoleActa Crystallographica Section E: Crystallographic Communications
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