Search results for "titanium"
showing 10 items of 878 documents
Formation of dibutyl carbonate and butylcarbamate via CO2 insertion in titanium(IV) butoxide and reaction with n-butylamine
2016
Abstract The species resulting from insertion of 12CO2 and 13CO2 into titanium(IV) butoxide is for the first time fully characterized by means of infrared and nuclear magnetic resonance spectroscopy. Results show formation of Ti-monobutylcarbonate, that easily undergoes nucleophilic attack by an aliphatic amine. The hydrolysis of the resulting species produces butylcarbamate and dibutylcarbonate as the only main products. Characterization results of the carbonate-like adduct, along with its reactivity with amine molecules open the route to new ways of CO2 utilization as building block for valuable organic compounds.
First titanium-catalyzed 1,4-hydrophosphination of 1,3-dienes
2010
International audience
Effect of TiO2 nanoparticles in thyme under reduced irrigation conditions
2018
The nanotechnology is a relatively new technology that has recently entered the field of agriculture. Nanotechnology covers the integration or manipulation of individual atoms, molecules or molecular masses to a diverse array of structures allowing the production of new characteristics and traits of interest. The aim of this study was to evaluate the effects of foliar application of TiO2 nanoparticles on quantitative traits (plant height, number of branches, dry weight of shoots and roots) and the essential oil content of thyme under different levels of field capacity. Our results showed that the application of TiO2 nanoparticles had significant effects on thyme growth, while the essential …
Single block 3D numerical model for linear friction welding of titanium alloy
2018
A two-stage approach for the simulation of Linear Friction Welding is presented. The proposed model, developed using the commercial simulation package DEFORM, is 3D Lagrangian, thermo-mechanically coupled. The first phase of the process was modelled with two distinct workpieces, while the remaining phases were simulated using a single-block model. The Piwnik–Plata criterion was set up and used to determine the shifting from the dual object to the single-block model. The model, validated against experimental temperature measurements, is able to predict the main field variables distributions with varying process parameters. Titanium alpha and beta phases evolution during the whole process has…
Microstructure and mechanical properties of dissimilar Ti/Nb/Cu/steel laser joints
2020
Abstract The absence of intermetallic phases in Fe/Cu, Cu/Nb and Nb/Ti binary systems opens the possibility to obtain reliable joints between titanium alloys and steels by using a multimaterial copper/niobium insert. Continuous Yb:YAG laser welding of 1 mm thick titanium and 316L stainless steel plates through niobium/copper multimaterial insert was performed. The use of a 100 µm laser beam allowed producing isolated molten zones and thus completely avoiding the formation of brittle intermetallic phases, according to SEM and XRD analysis. The effect of energy per unit length applied to the niobium/copper welds on the mixing process and mechanical properties of the joints was investigated. A…
Friction Stir Welding of Ti6Al4V complex geometries for aeronautical applications: a feasibility study
2020
Abstract While Friction Stir Welding (FSW) of aluminium alloys can be considered a mature technology, even for complex joint morphologies, as T joints welded “in transparency”, welding of hard material still presents several open issues. In fact, welding of titanium alloys is a challenging process due to the chemical, mechanical and thermal characteristics of such materials which are subjected to atmosphere contamination resulting in joint hydrogen, oxygen and nitrogen embrittlement; additionally, due to the high melting temperature, large distortion and residual stress are found in joints obtained by traditional fusion welding processes as gas metal arc welding, electron beam welding and l…
Dissimilar titanium/aluminum friction stir welding lap joints by experiments and numerical simulation
2016
Dissimilar lap joints were produced by friction stir welding (FSW) out of Ti6Al4V titanium alloy and AA2024 aluminum alloy sheets. The joints, welded with varying tool rotation and feed rate, were studied by analyzing the maximum shear strength, Vickers microhardness and optical observations. A dedicated numerical model, able to take into account the presence of the two different alloys, was used to highlight the effects of the process parameters on temperature distribution, strain distribution, and material flow. The combined analysis of experimental measurements and numerical predictions allowed explaining the effects of tool rotation and feed rate on the material flow. It was found that …
Direct laser welding of pure titanium to austenitic stainless steel
2018
Abstract Direct butt joining of pure titanium to 316L stainless steel with continuous Yb:YAG laser was performed with variation of the beam offset from joint line. Mechanical properties of samples were evaluated by tensile tests and three-point flexural tests. The fractured surfaces and cross sections of welds were examined by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD). Tensile properties of welds were strongly determined by the beam offset from joint line and are well described by Weibull statistics. Ultimate tensile strength of 174 ± 69 MPa and ultimate flexural strength of 297 ± 48 MPa were obtained. Brittle fracture took place in…
Aluminum to titanium laser welding-brazing in V-shaped grooveI
2017
International audience; Laser assisted joining of AA5754 aluminum alloy to T40 titanium with use of Al-Si filler wires was carried out. Continuous Yb:YAG laser beam was shaped into double spot tandem and defocalized to cover larger interaction zone in V shaped groove. Experimental design method was applied to study the influence of operational parameters on the tensile properties of the joints. Microstructure examination and fractography study were carried out to understand the relation between local phase content and fracture mode.Within defined window of operational parameters, statistically important factors that influenced the strength of T40 to AA5754 joints in V groove configuration w…
An in vitro cyclic fatigue resistance comparison of conventional and new generation nickel-titanium rotary files
2018
Background New designs and processing of Niquel-Titanium (NiTi) have been introduced to increase resistance to cyclic fatigue. The purpose of this study was to compare the cyclic fatigue resistance of 3 NiTi rotary instruments, ProTaper Next (PTN; Dentsply Maillefer, Ballaigues, Switzerland), Profile Vortex Blue (PVB; Dentsply Tulsa Dental, Tulsa, OK, USA) and ProTaper Universal (PTU; Dentsply Maillefer, Ballaigues, Switzerland). Material and Methods A cyclic fatigue test was conducted operating instruments from ProTaper Next X2, Profile Vortex Blue 25.06 and ProTaper F2. A total of 234 instruments were rotated in 2 simulated stainless steel curved canals with different angles of curvature …