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showing 10 items of 88 documents

Half-width plots, a simple tool to predict peak shape, reveal column kinetics and characterise chromatographic columns in liquid chromatography: Stat…

2013

Peak profiles in chromatography are characterised by their height, position, width and asymmetry; the two latter depend on the values of the left and right peak half-widths. Simple correlations have been found between the peak half-widths and the retention times. The representation of such correlations has been called half-width plots. For isocratic elution, the plots are parabolic, although often, the parabolas can be approximated to straight-lines. The plots can be obtained with the half-widths/retention time data for a set of solutes experiencing the same kinetics, eluted with a mobile phase at fixed or varying composition. When the analysed solutes experience different resistance to mas…

Peak profiles in chromatography are characterised by their height position width and asymmetry; the two latter depend on the values of the left and right peak half-widths. Simple correlations have been found between the peak half-widths and the retention times. The representation of such correlations has been called half-width plots. For isocratic elution the plots are parabolic although often the parabolas can be approximated to straight-lines. The plots can be obtained with the half-widths/retention time data for a set of solutes experiencing the same kinetics eluted with a mobile phase at fixed or varying composition. When the analysed solutes experience different resistance to mass transfer the plots will be solute dependent and should be obtained with the data for each solute eluted with mobile phases at varying composition. The half-width plots approach is a simple tool that facilitates the prediction of peak shape (width and asymmetry) with optimisation purposes reveal the interaction kinetics of solutes in different columns and characterise chromatographic columns. This work shows half-width plots for different situations in isocratic elution including the use of different flows the effect of temperature the modification of the stationary phase surface by an additive the existence of specific interactions within the column and the comparison of columns. The adaptation to gradient elution is also described. Previous knowledge on half-width plots is structured and analysed to which new results are added.Work (thermodynamics)Column characterisationmedia_common.quotation_subjectKineticsLiquid chromatographyAnalytical chemistryHalf-widthsInteraction kineticsBiochemistryAsymmetryAnalytical ChemistryPeak shapeColumn (typography)Position (vector)Mass transferPhase (matter)media_commonChromatographyElutionChemistryOrganic ChemistryGeneral MedicineModels TheoreticalKineticsPredictionChromatography LiquidJournal of Chromatography A
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Assessing mentalization in psychotherapy: first validation of the Mentalization Imbalances Scale

2018

The aim of this study was to provide data on the preliminary validation of a clinician-report multidimensional assessment measure of mentalization (Mentalization Imbalances Scale, MIS). A random national sample of psychotherapists (N=190) completed the MIS to identify mentalization imbalances, and the Personality Disorder Checklist to assess the personality disorders (PDs) of randomly selected patients currently in their care. Factor analysis confirmed the presence of six factors that represented different imbalances of mentalization: cognitive, affective, automatic, external, imbalance toward others, and imbalance toward self. We found several significant relationships between patients’ me…

PsychotherapistTool ArticlePsychotherapy Researchmedia_common.quotation_subjectlcsh:BF1-990Mentalization; Assessment; Psychotherapy Research; Personality DisordersMultidimensional assessmentEMPATHYREFLECTIVE FUNCTIONAssessmentPersonality DisordersMentalizationObsessive compulsivemedicinePersonalityPersonality disordersmedia_commonPersonality disorderBORDERLINE-PERSONALITY-DISORDERMETACOGNITIONPersonality pathologyfood and beveragesCognitionmedicine.diseasePersonality disordersATTACHMENTPsychiatry and Mental healthClinical Psychologylcsh:PsychologyMentalizationScale (social sciences)RELIABILITYPsychology
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Introducing a novel mesh following technique for approximation-free robotic tool path trajectories

2017

Abstract Modern tools for designing and manufacturing of large components with complex geometries allow more flexible production with reduced cycle times. This is achieved through a combination of traditional subtractive approaches and new additive manufacturing processes. The problem of generating optimum tool-paths to perform specific actions (e.g. part manufacturing or inspection) on curved surface samples, through numerical control machinery or robotic manipulators, will be increasingly encountered. Part variability often precludes using original design CAD data directly for toolpath generation (especially for composite materials), instead surface mapping software is often used to gener…

QA750209 industrial biotechnologyEngineeringComputational MechanicsMesh following techniqueCAD02 engineering and technologyTool path generationTriangular meshescomputer.software_genreNDT020901 industrial engineering & automationSoftwarelcsh:TA1740202 electrical engineering electronic engineering information engineeringComputer Aided DesignEngineering (miscellaneous)SimulationCommercial softwareSubtractive colorbusiness.industry020207 software engineeringRoboticsRoboticslcsh:Engineering designComputer Graphics and Computer-Aided DesignHuman-Computer InteractionComputational MathematicsModeling and SimulationComputer-aided manufacturingNumerical controlArtificial intelligencebusinessAlgorithmcomputerJournal of Computational Design and Engineering
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The Social Exclusion Bench Tool (SEBT): A visual way of assessing interpersonal social exclusion

2021

People usually prefer to appear with an inclusive and positive attitude to others’ eyes. For this reason, the self-report scales assessing social exclusion intentions are often biased by social desirability. In this work, we present an innovative graphical tool, named Social Exclusion Bench Tool (SEBT), for assessing social exclusion not influenced by social desirability. The tool is based on the consistency between social distance and physical distance evaluation. The results showed that in two samples of adults from Italy (N = 252) and the UK (N = 254), the SEBT positively correlated with self-report measures of social exclusion, but not with the social desirability measure. The tool has …

QualtricsHeat mapSocial exclusionScienceSocial distanceQClinical BiochemistryQualtricSocial desirabilityContext (language use)Interpersonal communicationMethod ArticleSocial Exclusion Bench Tool (SEBT)Social groupMedical Laboratory TechnologyConsistency (negotiation)Social exclusionPositive attitudePsychologyGraphic toolSocial psychologySocial desirability
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Developing a Tool Point Control Scheme for a Hydraulic Crane Using Interactive Real-time Dynamic Simulation

2010

This paper describes the implementation of an interactive real-time dynamic simulation model of a hydraulic crane. The user input to the model is given continuously via joystick and output is presented continuously in a 3D animation. Using this simulation model, a tool point control scheme is developed for the specific crane, considering the saturation phenomena of the system and practical implementation. This paper describes the implementation of an interactive real-time dynamic simulation model of a hydraulic crane. The user input to the model is given continuously via joystick and output is presented continuously in a 3D animation. Using this simulation model, a tool point control scheme…

Scheme (programming language)VDP::Mathematics and natural science: 400::Mathematics: 410::Applied mathematics: 413Engineeringhydraulic craneInteractive real-time dynamic simulationbusiness.industryControl (management)VDP::Technology: 500::Mechanical engineering: 570Control engineeringComputerApplications_COMPUTERSINOTHERSYSTEMSlcsh:QA75.5-76.95Computer Science ApplicationsDynamic simulationHydraulic craneTool point controlIdentification (information)Control and Systems EngineeringModeling and SimulationPoint (geometry)lcsh:Electronic computers. Computer sciencebusinesscomputerSoftwareSimulationcomputer.programming_language
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THE VALIDATION OF A SELF-ASSESSMENT TOOL FOR THE TEACHER'S PRACTICES THAT EMBRACES THE NEURO-EDUCATIONAL APPROACH

2021

This contribution intends to present a study and research path that, starting from the theoretical framework of neuro-education, has led to the identification of five indicators (transversal area, socio-emotional-affective area, cognitive area, linguistic-communicative area, praxico-motor) on the basis of which a neuro-evaluation tool for teachers was built and validated: Self-assessment questionnaire of neuro-didactic and educational practices for teachers. Neuroscientific research is offering numerous points of reflection-action on the functioning of the brain and on how to modify the teaching and the educational proposal to improve the performance and growth of the person. However, the p…

Self-assessmentMedical educationEducational approachNeuro-education tool validation neuromites principles of neuroeducation self-assessment.PsychologySettore M-PED/04 - Pedagogia Sperimentale
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Fixed speed wind turbine generator model validation and dynamic simulation using Matlab/Simulink

2007

In the last two decades an increasing amount of electricity has been generated from renewable sources in order to mitigate the environmental impact of the conventional power plants. In the next future wind turbines may affect the behaviour of electrical power system. This paper describes the model of a typical fixed speed wind turbine connected to the grid; the model is developed in the simulation tool Matlab/Simulink. It’s composed by the aerodynamic system, the shaft model (two-mass system), the induction generator (fifth order model) and the stall control system of the wind turbine rotor. The validation of the wind turbine model is made in steady-state operation, and the results are veri…

Settore ING-IND/33 - Sistemi Elettrici Per L'EnergiaWind turbine model Model validation Dynamic simulation tool Matlab/Simulink
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Nomograph for rapid technical and economic assessment of solar thermal systems for DHW production

2012

Abstract Different types of tools, software and empirical methods to size and assess the performance of solar thermal systems are available today. A quick and easy-to-use graphical tool is proposed here. It is based on a single diagram, called a nomograph, which embeds technical and economic information, allowing the optimisation of the size and performance of a solar thermal system starting from the main input parameters, such as the specific costs of the system and the auxiliary fuel. The optimal surfaces are calculated as a function of the fuel cost through several regressions made on data from the application of the F-Chart method for a set of system configurations. The authors have fou…

Solar thermal system for DHW Performance evaluation Graphical tool for technical and economic assessment and optimisationSolar thermal system for DHWSettore ING-IND/11 - Fisica Tecnica AmbientaleRenewable Energy Sustainability and the Environmentbusiness.industryComputer scienceTotal costDiagramSample (statistics)Set (abstract data type)Graphical tool for technical and economic assessment and optimisationSoftwareThermalSolar thermal system for DHW; Performance evaluation; Graphical tool for technical and economic assessment and optimisationPerformance evaluationProduction (economics)General Materials Sciencesolar thermal systems rapid assessmentMacrobusinessProcess engineeringSolar Energy
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Tool Path Design in Friction Stir Welding of AA6082-T6 Aluminium Alloy

2007

In the paper, a variation of the Friction Stir Spot Welding (FSSW) process has been considered. In particular, a particular tool path is given after the sinking phase nearby the initial penetration site. The process mechanics was highlighted and the joint strength was considered at the varying of the most relevant process parameters. Furthermore macro and micro analyses were developed in order to highlight the process mechanics and the local material microstructure evolution. The investigated technology appears a promising joining technique in order to develop effective spot joints.

Spot welding Friction Stir Welding Tool path
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Interdependence Between Tool Fracture and Wear

1985

Wear and fracture are the main causes of tool scrapping. However fracture plays a major role for increasing values of the hardness and brittleness of tool materials or when low-cobalt tungsten carbides are used or in interrupted cutting conditions where it is the most relevant factor for tool scrapping. In order to obtain the optimal values of the cutting speed both these factors should be considered. The hypothesis of stochastic independence among them simplifies the mathematical formulation of the optimization problem; but experimental investigations do not agree with this assumption and, as a matter of fact, the probability density function of tool fracture results to be dependent on the…

Stochastic independenceOptimization problemBrittlenessComputer scienceMechanical EngineeringMetallurgyFracture (geology)Mechanical engineeringProbability density functionIndustrial and Manufacturing EngineeringTool materialCIRP Annals
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