Search results for "trol"

ATR–FTIR Spectral Analysis and Soluble Components of PM10 And PM2.5 Particulate Matter over the Urban Area of Palermo (Italy) during Normal Days and …

2019

Several epidemiological studies have shown a close relationship between the mass of particulate matter (PM) and its effects on human health. This study reports the identification of inorganic and organic components by attenuated total reflectance-Fourier-transform infrared spectroscopy (ATR-FTIR) analysis in PM10 and PM2.5 filters collected from three air quality monitoring stations in the city of Palermo (Sicily, Italy) during non-Saharan dust events and Saharan events. It also provides information on the abundance and types of water-soluble species. ATR-FTIR analysis identified sulfate, ammonium, nitrate, and carbonate matter characterized by vibrational frequencies at 603, 615, 670, and …

Asynchronous changes of CO2, H2, and He concentrations in soil gases: A theoretical model and experimental results

2016

Lower mantle hydrogen partitioning between periclase and perovskite : a quantum chemical modelling

2016

Abstract Partitioning of hydrogen (often referred to as H2O) between periclase (pe) and perovskite (pvk) at lower mantle conditions (24–80 GPa) was investigated using quantum mechanics, equilibrium reaction thermodynamics and by monitoring two H-incorporation models. One of these (MSWV) was based on replacements provided by Mg2+ ↔ 2H+ and Si4+ ↔ 4H+; while the other (MSWA) relied upon substitutions in 2Mg2+ ↔ Al3+ + H+ and Si4+ ↔ Al3+ + H+. H2O partitioning in these phases was considered in the light of homogeneous (Bulk Silicate Earth; pvk: 75%–pe:16% model contents) and heterogeneous (Layered Mantle; pvk:78%–pe:14% modal contents) mantle geochemical models, which were configured for lower…

Reaction path models of magmatic gas scrubbing

2016

Gas-water-rock reactions taking place within volcano-hosted hydrothermal systems scrub reactive, water-soluble species (sulfur, halogens) from the magmatic gas phase, and as such play a major control on the composition of surface gas manifestations. A number of quantitative models of magmatic gas scrubbing have been proposed in the past, but no systematic comparison of model results with observations from natural systems has been carried out, to date. Here, we present the results of novel numerical simulations, in which we initialized models of hydrothermal gas-water-rock at conditions relevant to Icelandic volcanism. We focus on Iceland as an example of a "wet" volcanic region where scrubb…

Gas mass derived by infrasound and UV cameras: Implications for mass flow rate

2016

Abstract Mass Flow Rate is one of the most crucial eruption source parameter used to define magnitude of eruption and to quantify the ash dispersal in the atmosphere. However, this parameter is in general difficult to be derived and no valid technique has been developed yet to measure it in real time with sufficient accuracy. Linear acoustics has been applied to infrasonic pressure waves generated by explosive eruptions to indirectly estimate the gas mass erupted and then the mass flow rate. Here, we test on Stromboli volcano (Italy) the performance of such methodology by comparing the acoustic derived results with independent gas mass estimates obtained with UV cameras, and constraining th…

ASSESSING TRACE ELEMENT (DIS)EQUILIBRIUM AND THE APPLICATION OF SINGLE ELEMENT THERMOMETERS IN METAMORPHIC ROCKS

2018

Abstract Empirical and experimental calibration of single element solubility thermometers, such as Zr-in-rutile, Zr-in-titanite, Ti-in-zircon, and Ti-in-quartz, within the past 13 years has greatly expanded our ability to assess the pressure and temperature conditions of individual minerals associated with specific textures in metamorphic rocks. Combined with advances in in situ techniques for analyzing trace concentrations, this has led to an increase in the combined use of single element thermometers, geochronometers, and isotope ratios, often simultaneously, in metamorphic minerals. Here we review the calibration and application of single element thermometers at the pressure and temperat…

Melange: A viscoelastic lattice-particle model applicable to the lithosphere

2012

[1] This article introduces the software Melange, a 3D lattice-particle hybrid model. The software was specifically designed in order to simulate ductile visco-elasto-plastic deformation and can be used to study tectonic processes in the lithosphere from the micro to the macro scale. Melange is under an open source license. The code takes both relevant yield mechanisms for the deformation of lithospheric material into account: dynamic brittle failure and ductile creep, where ductile creep is modeled as viscoelasticity. The software considers effects of the local geology, of the inherent disorder of geomaterials, of rheological layering of the lithosphere and applies repulsion when the mater…

High time resolution fluctuations in volcanic carbon dioxide degassing from Mount Etna

2014

Abstract We report here on the first record of carbon dioxide gas emission rates from a volcano, captured at ≈ 1 Hz. These data were acquired with a novel technique, based on the integration of UV camera observations (to measure SO2 emission rates) and field portable gas analyser readings of plume CO2/SO2 ratios. Our measurements were performedat the North East crater of Mount Etna, southern Italy, and the data reveal strong variability in CO2 emissions over timescales of tens to hundreds of seconds, spanning two orders of magnitude. This carries importantimplications for attempts to constrain global volcanic CO2 release to the atmosphere, and will lead to an increased insight into short te…

Element variations in rhyolitic magma resulting from gas transport

2013

Tuffisite veins are glass-filled fractures formed when magma fragments during degassing within the conduit. These veins form transient channels through which exsolved gases can escape from magma. The purpose of this study is to determine the extent to which chemical heterogeneity within the melt results from gas transport, and assess how this can be used to study magma degassing. Two tuffisite veins from contrasting rhyolitic eruptions at Torfajökull (Iceland) and Chaitén (Chile) were studied in detail. The tuffisite vein from Torfajökull is from a shallow dissected conduit (~70. ka) that fed a degassed lava flow, while the sample from Chaitén was a bomb ejected during the waning phases of …

Understanding volcanoes in the Vanuatu arc

2016

We report the first helium isotope survey of volcanic gases, hot springs and some olivine phenocrysts along the Vanuatu island arc, from Tanna in the south to Vanua Lava in the north. Low CO2 content and low He-3/He-4 ratios in thermal fluids of Epi (4.0 +/- 0.1 R-a), Efate (4.5 +/- 0.1 R-a) and Pentecost (5.3 +/- 0.5 R-a) islands coherently indicate reduced mantle gas leakage and crustal contamination by radiogenic helium on these extinct volcanic systems of the former (Pliocene) arc. Instead, presently active Vanuatu volcanoes display He-3/He-4 and C/He-3 ratios typical of subduction-related volcanic arcs: He-3/He-4 ratios range from 6.4 +/- 0.5 Ra in southernmost Tanna and 7.23 +/- 0.09 …