Search results for "tunne"

Probing DNA conductivity with photoinduced electron transfer and scanning tunneling microscopy.

2012

Abstract The possibility that the stacked DNA bases can mediate vectorial electron transfer has been examined using two different approaches. Experiments on photoinduced electron transfer with intercalated donors and acceptors (either randomly bound or linked dyads of ruthenium complex and viologen) indicate that while DNA may be a better medium than acetonitrile for electron transfer over short distances (2-3-base pair, equivalent to 10-14Å centre-to-centre separation), it is a poor medium for transport over larger separations. Attempts to measure conductivity of individual DNA molecules using scanning tunneling microscopy to image mixed monolayers of mercaptohexanol (MCH) and 30-mer or 10…

Riming of Graupel: Wind Tunnel Investigations of Collection Kernels and Growth Regimes

2009

Abstract Laboratory experiments were carried out in the vertical wind tunnel in Mainz, Germany, to study the collision coalescence growth of single spherical ice particles having initial radii between 290 and 380 μm while they were freely floated in a laminar flow containing a cloud of supercooled droplets with radii between 10 and 20 μm. The experiments were performed in a temperature range between −8 and −12°C, where riming proceeds in the atmosphere, and with cloud liquid water contents lying between 0.9 and 1.6 g m−3 (i.e., values typically found in mixed-phase clouds). The collection kernels were calculated from the mass increase of the rimed ice particles and the average liquid water …

Shapes and oscillations of raindrops with reduced surface tensions: Measurements at the Mainz vertical wind tunnel

2013

Abstract Important characteristics of raindrops pertinent to fields in atmospheric sciences such as weather radar or pollution scavenging are drop shape, oscillation frequency and amplitude, as well as the internal circulation. Atmospheric raindrops are never pure water drops but contain additional components like aerosol particles and dissolved species. Surface active substances, when present, reduce the surface tension of raindrops and, thus, increase the drop deformation which in turn affects breakup and coalescence, pollutant scavenging, and, finally, the formation of precipitation. Experiments were performed at the Mainz vertical wind tunnel with raindrops freely suspended at their ter…

Wind tunnel study on the size distribution of droplets after collision induced breakup of levitating water drops

2018

Abstract Wind tunnel experiments on collisions between drop pairs of 2.5 and 0.5 mm diameter have been performed and the coalescence and breakup events have been recorded by a high-speed digital camera. From the comprehensive analysis of the captured images, the most important parameters utilized in numerical models, such as coalescence efficiency, breakup type, number of fragments and fragment size distribution after breakup were determined. The experimentally obtained parameters have been compared to parameterizations based on earlier laboratory studies of Low and List, and on direct numerical simulations. A very good agreement between experimental results and parameterizations has been f…

Frequency and temperature dependence of the electrical conductivity of KTaO3; Li and PbTiO3; La, Cu: Indication of a low temperature polaron mechanism

2008

Abstract Recently, the concept of polarons has again been at the focus of solid-state research, as it can constitute the basis for understanding the high-temperature superconductivity or the colossal magnetoresistance of materials. More than a decade ago there were some indications that polarons play an important role in explaining low temperature maxima in imaginary part of the dielectric constant e ″ ( T ) in ABO3 perovskites. In the present work we report the ac electrical conductivities of KTaO3; Li and PbTiO3; La, Cu and their frequency and temperature dependence. The real part of the complex ac conductivity was found to follow the universal dielectric response σ ′ ∝ ν s . A detailed t…

Promoting emotional skills in early adolescents with mental health conditions in music therapy : a content analysis of focus group interviews

2023

Introduction: Music therapy is actively used with early adolescents in relation to their emotional skill development. Yet, the conceptualization of emotional skills is typically not systematically addressed in therapeutic practice. This study examined music therapists’ views on the progress of emotional skills when working with early adoles-cents with mental health conditions. The study also explored what kind of methods the therapists use with the target group, and the applicability of a previously pub-lished conceptual model. Method: We conducted a deductive-inductive content analysis of transcripts from four focus group interviews among 13 professional music therapists. Results: The ther…

The promise of spintronics for unconventional computing

2021

Novel computational paradigms may provide the blueprint to help solving the time and energy limitations that we face with our modern computers, and provide solutions to complex problems more efficiently (with reduced time, power consumption and/or less device footprint) than is currently possible with standard approaches. Spintronics offers a promising basis for the development of efficient devices and unconventional operations for at least three main reasons: (i) the low-power requirements of spin-based devices, i.e., requiring no standby power for operation and the possibility to write information with small dynamic energy dissipation, (ii) the strong nonlinearity, time nonlocality, and/o…

Design, Control, and Analysis of Nonlinear Circuits with Tunnel Diode with Piecewise Affine Dynamics

2019

Multiply charged metal cluster anions

2000

Formation, stability patterns, and decay channels of silver dianionic and gold trianionic clusters are investigated with Penning-trap experiments and a shell-correction method including shape deformations. The theoretical predictions pertaining to the appearance sizes and electronic shell effects are in remarkable agreement with the experiments. Decay of the multiply anionic clusters occurs predominantly by electron tunneling through a Coulomb barrier, rather than via fission, leading to appearance sizes unrelated to those of multiply cationic clusters.

Quantum Well States in Two-Dimensional Gold Clusters on MgO Thin Films

2008

The electronic structure of ultra-small Au clusters on thin MgO/Ag(001) films has been analyzed by scanning tunneling spectroscopy and density functional theory. The clusters exhibit two-dimensional (2D) quantum well states, whose shapes resemble the eigen-states of a 2D electron gas confined in a parabolic potential. From the symmetries of the HOMO and LUMO of a particular cluster, its electron filling and charge state is determined. In accordance to a DFT Bader-charge analysis, aggregates containing up to twenty atoms accumulate one to four extra electrons due to a charge transfer from the MgO/Ag interface. The HOMO - LUMO gap is found to close for clusters containing between 70 and 100 a…