Search results for "two-phase"

showing 10 items of 98 documents

Two-phase flow of liquid–liquid mixture in the range of the water droplet pattern

2002

Abstract Phenomena accompanying flow of water–oil mixture during droplet flow of water in oil have been described. Aims used in the determination of characteristic parameters in two-phase liquid–liquid flow have been presented. The method for calculating the equivalent viscosity and pressure drop during flow of liquid–liquid mixture in the range of the water droplet pattern has been given.

Pressure dropRange (particle radiation)ChemistryProcess Chemistry and TechnologyGeneral Chemical EngineeringFlow (psychology)Energy Engineering and Power TechnologyThermodynamicsGeneral ChemistryIndustrial and Manufacturing EngineeringCondensed Matter::Soft Condensed MatterPhysics::Fluid DynamicsViscosityLiquid liquidDroplet flowTwo-phase flowWater in oilChemical Engineering and Processing: Process Intensification
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A Study of the Separation of 1-Dodecene and 1-Tetradecene Hydroformylation Products in Aqueous Medium

2009

Abstract Experimental results of the solubilization of olefins in hydroformylation model systems, comprising 1-dodecene and 1-tridecanal or 1-tetradecene and 1-pentadecanal, water, butanol, sodium dodecylsulfate (SDS), sodium dodecylbenzenesulfonate (SDBS), and/or tri(m-sulfofenyl)phosphine trisodium salt (TPPTS-Na) are presented. The selected systems were used for the hydroformylation of 1-dodecene and 1-tetradecene whereby high yields of aldehydes were obtained. After the reaction, the mixture spontaneously separated into an organic phase with the reaction products and an aqueous phase comprising the catalyst and excess phosphine ligand.

Process Chemistry and TechnologyGeneral Chemical EngineeringButanolSodium dodecylbenzenesulfonateAqueous two-phase systemFiltration and SeparationGeneral ChemistryCatalysischemistry.chemical_compoundchemistryOrganic chemistry1-DodeceneMicroemulsionPhosphineHydroformylationSeparation Science and Technology
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Hidden attractors in dynamical models of phase-locked loop circuits : limitations of simulation in MATLAB and SPICE

2017

During recent years it has been shown that hidden oscillations, whose basin of attraction does not overlap with small neighborhoods of equilibria, may significantly complicate simulation of dynamical models, lead to unreliable results and wrong conclusions, and cause serious damage in drilling systems, aircrafts control systems, electromechanical systems, and other applications. This article provides a survey of various phase-locked loop based circuits (used in satellite navigation systems, optical, and digital communication), where such difficulties take place in MATLAB and SPICE. Considered examples can be used for testing other phase-locked loop based circuits and simulation tools, and m…

SPICEMATLABphase-locked loopmultistabilitytwo-phase PLLnonlinear control systemoptical costas loopsimulointisynchronizationdynamical systemhidden attractor
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Degradation of heterocyclic aromatic amines in oil under storage and frying conditions and reduction of their mutagenic potential.

2007

Heterocyclic aromatic amines (HAA) were systematically studied concerning their partition behavior in water/oil-systems and their thermostability in different animal derived fats and vegetable oils. Partitioning of IQx-compounds and PhIP in water/oil systems was found to depend on the polarity defined by the molecular structure and on the pH-value of the aqueous phase. In particular, beta-carbolines norharman and harman showed a significant strong lipophilic character at alkaline pH. After heating in frying fats at 130 degrees C, contents of IQx compounds and PhIP were reduced by more than 40% and after heating at 180 degrees C less than 10% of the HAA initial concentration was recovered. B…

Salmonella typhimuriumHot TemperatureMutagenToxicologymedicine.disease_causeLipid oxidationHeterocyclic CompoundsmedicineOrganic chemistryPlant OilsCookingAminesThermostabilitychemistry.chemical_classificationDose-Response Relationship DrugMolecular StructureMutagenicity TestsAqueous two-phase systemAromatic amineWaterGeneral MedicineDietary FatschemistryHeterocyclic compoundDegradation (geology)Oxidation-ReductionGenotoxicityFood ScienceMutagensFood and chemical toxicology : an international journal published for the British Industrial Biological Research Association
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Partial photocatalytic oxidation of glycerol in TiO2 water suspensions

2010

2nd European Conference on Environmental Applications of Advanced Oxidation Processes -- SEP 09-11, 2009 -- Nicosia, CYPRUS

Settore ING-IND/24 - Principi Di Ingegneria ChimicaAnataseTitanium DioxideAqueous solutionFormic acidElectrospray ionizationGlycerol partial oxidation Selective photocatalytic oxidation Titanium dioxide Reaction pathwaysInorganic chemistryAqueous two-phase systemGeneral ChemistryCatalysischemistry.chemical_compoundchemistryGlyceraldehydeTitanium dioxideGlycerolSettore CHIM/07 - Fondamenti Chimici Delle TecnologieSelective Photocatalytic OxidationGlycerol Partial OxidationReaction Pathways
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CFD Simulation of Particle Suspension Height in Stirred Vessels

2004

Computational fluid dynamics (CFD) simulation capabilities for stirred solid–liquid dense systems are explored. These systems may give rise to the formation of a thick and well defined clear liquid layer in the upper part of the vessel, whose extension progressively reduces with increasing impeller speed. Experimental measurements of the suspension height (the height of the particle laden layer) were carried out at various agitation speeds for a variety of solid–liquid systems in a fully baffled transparent tank. A clear layer of liquid was actually observed in all runs, with the suspension height almost linearly dependent on agitation speed. CFD simulations of the above described systems w…

Settore ING-IND/26 - Teoria Dello Sviluppo Dei Processi ChimiciMaterials sciencebusiness.industrySettore ING-IND/25 - Impianti ChimiciGeneral Chemical EngineeringEulerian pathGeneral ChemistryMechanicsDense two-phase mixtureComputational fluid dynamicsParticle dipersionAgitatorEuler equationssymbols.namesakeImpellerParticle suspensionSolids suspensionControl theoryCFD simulationsymbolsParticleStirred vesselsbusinessSuspension (vehicle)Layer (electronics)Chemical Engineering Research and Design
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CFD simulations of dense solid–liquid suspensions in baffled stirred tanks: Prediction of the minimum impeller speed for complete suspension

2012

Abstract In the literature on mechanically agitated solid–liquid systems, several methods are described to estimate the minimum impeller speed Njs at which all particles are suspended, but few studies have been devoted so far to their critical comparative assessment [67] . In the present paper, several alternative Njs prediction methods are applied to CFD results obtained for selected test cases covering a broad range of suspension conditions and impeller speeds. Results are compared with one another and with classic empirical correlations [88] . The aim of the work is to assess the adequacy of different methods for predicting Njs and, more generally, to contribute to a viable CFD-based str…

Settore ING-IND/26 - Teoria Dello Sviluppo Dei Processi ChimiciWork (thermodynamics)Engineeringbusiness.industrySettore ING-IND/25 - Impianti ChimiciGeneral Chemical EngineeringMixing (process engineering)Mechanical engineeringGeneral ChemistryMechanicsStirred tank Multi-fluid model Computational fluid dynamics Solid–liquid two-phase flow Complete suspension speed Sufficient suspension speed Unsuspended solids criterionComputational fluid dynamicsIndustrial and Manufacturing EngineeringControl volumeImpellerEnvironmental ChemistrySuspension (vehicle)Reynolds-averaged Navier–Stokes equationsbusinessContactorChemical Engineering Journal
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Conditions of dust sampling in pneumatic conveying through the horizontal pipeline

2007

Abstract The paper presents the results of examinations on the reciprocal relation between the isokinetic coefficient H of sampling, the quantity of measured mass concentration and the measuring usefulness of a dust sample aspired from the stream of solgas conveyed pneumatically in the horizontal pipeline. In gravimetric measurements of two-phase flows, the conditions under which aspiration is carried out, are extremely important. Available theoretical considerations and practical experiments usually concern aspiration in the vertical channels, where the manner of making measurements is universally known and it does not express any reservations. However, it is often necessary to conduct tes…

Spectrum analyzerDust sampleGeneral Chemical EngineeringPipeline (computing)Flow (psychology)MineralogyEnvironmental scienceMass concentration (chemistry)Sampling (statistics)Gravimetric analysisTwo-phase flowMechanicsPowder Technology
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Experimental assessment of application of gravimetric measurements for pneumatic conveying in horizontal pipelines

2008

Abstract Available theoretical considerations and practical experiments usually concern aspiration in the vertical pipelines, where the procedure of making measurements is universally known and it does not express any reservations. However, it is often necessary to conduct test in the systems of horizontal conveying of solgas, where the conditions of taking a representative sample, even for the sake of the significant effect of the gravitational force, many vary from those suggested for measurements in the systems with vertical flow. The present paper contains the results of tests which determine usability of the gravimetric method in measurements of flow parameters of two-phase gas–solid m…

Spectrum analyzerEngineeringbusiness.industryProcess Chemistry and TechnologyGeneral Chemical EngineeringFlow (psychology)Energy Engineering and Power TechnologyMineralogyGeneral ChemistryMechanicsPipeline (software)Industrial and Manufacturing EngineeringPipeline transportVertical flowGravimetric analysisTwo-phase flowbusinessGravitational forceChemical Engineering and Processing: Process Intensification
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Macroscopic capillarity without a constitutive capillary pressure function

2006

This paper challenges the foundations of the macroscopic capillary pressure concept. The capillary pressure function, as it is traditionally assumed in the constitutive theory of two-phase immiscible displacement in porous media, relates the pressure difference between nonwetting and wetting fluid to the saturation of the wetting fluid. The traditional capillary pressure function neglects the fundamental difference between percolating and nonpercolating fluid regions as first emphasized in R. Hilfer [Macroscopic equations of motion for two phase flow in porous media, Phys. Rev. E 58 (1998) 2090]. The theoretical approach proposed here starts from residual saturations as the volume fractions…

Statistics and ProbabilityCapillary pressureMaterials scienceCapillary actionMultiphase flowThermodynamicsMechanicsCondensed Matter PhysicsCapillary numberlaw.inventionPhysics::Fluid DynamicslawTwo-phase flowHydrostatic equilibriumPorous mediumQuasistatic processPhysica A: Statistical Mechanics and its Applications
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