Search results for "uPAR"
showing 10 items of 59 documents
[Cu32(PET)24H8Cl2](PPh4)2: A Copper Hydride Nanocluster with a Bisquare Antiprismatic Core
2020
Atomically precise coinage metal (Au, Ag and Cu) nanoclusters (NCs) have been the subject of immense interest for their intriguing structural, photophysical and catalytic properties. However, the synthesis of Cu NCs is highly challenging because of low reduction potential and high reactivity of copper, demonstrating the need for new synthetic methods using appropriate ligand combinations. By designing a diamine-assisted synthetic strategy, here we report the synthesis and total structure characterization of a box-like dianionic Cu NC, [Cu32(PET)24H8Cl2](PPh4)2 co-protected by 2-phenylethanethiolate (PET), hydride and chloride ligands. Its crystal structure comprises a rare bisquare antipris…
Es pot desenvolupar el capital psicològic en el dia a dia de les organitzacions?
2016
En el present estudi realitzem una reflexió sobre el potencial que té el capital psicològic, per a ser desenvolupat a partir de les pràctiques comunes en les organitzacions, i com això pot ajudar a explicar i millorar el comportament de les persones en el treball. Així mateix, s’avancen algunes de les preguntes que això podria plantejar, i les respostes que podrien resultar de gran valor, tant en el camp acadèmic com en l’aplicat.
Potential and limitation of combining terrestrial and marine growth records from Iceland
2017
Abstract Seasonally formed, perennial growth increments of various organisms may possibly contain information about past environmental changes, well before instrumental measurements occurred. Such annually resolved proxy records have been mainly obtained from terrestrial archives, with a paucity of similar data originating from marine habitats. Iceland represents ideal conditions to develop both, tree ring (dendro) and bivalve shell (sclero) chronologies from adjacent sites. Here we introduce the first network of Icelandic birch (Betula pubescens Ehrh.) and rowan (Sorbus aucuparia) dendrochronologies, as well as ocean quahog (Arctica islandica L.) sclerochronologies. In order to identify th…
The Lure of Katanga Copper : Tanganyika Concessions Limited and the Anatomy of Mining and Mine Exploration 1899–1906
2016
This article provides a rare opportunity to follow the inception of mining and mine exploration economy in the first years of the European presence in colonial Zambia and Katanga as seen through the eyes of prospectors and mining experts working for the London-based company Tanganyika Concessions Limited. It draws on company records as well as the personal records of the early company employees who worked in North Western Rhodesia and adjoining Katanga until 1906. The most thought-provoking documents include diaries, letters and photographs, which depict the organisation and processes of early mining work, modes of mine exploration, and relations within the first mining communities and betw…
Survival and infectivity of Hypoderaeum conoideum and Euparyphium albuferensis cercariae under laboratory conditions.
1999
The survival characteristics of the cercariae of Hypoderaeumconoideum and Euparyphiumalbuferensis (Trematoda: Echinostomatidae) at 20°C and 30°C are described, and the age dependency of their infectivity at 20°C is studied to determine their respective transmission efficiencies. Cercarial survival was found to be age-dependent and was higher at 20°C. For both cercariae, the maximum life-span was 26 h at 20°C and 16 h at 30°C, and their respective times to 50% mortality were similar at each temperature. Both cercariae seem to be well adapted to transmission in their natural habitat, though cercarial infectivity of H. conoideum was higher than that of E. albuferensis, this being correlated wi…
Copper(I) Complexes of Bis(2-(diphenylphosphino)phenyl) Ether: Synthesis, Reactivity, and Theoretical Calculations
2007
The tricoordinated cationic Cu-I complex [Cu(kappa(2)-P,P'-DPEphos)(kappa(1)-P-DPEphos)][BF4] (1) (DPEphos = bis(2-(diphenylphosphino)phenyl) ether) containing a dangling phosphorus center was synthesized from the reaction of [Cu(CH3CN)(4)][BF4] with DPEphos in a 1:2 molar ratio in dichloromethane. When complex 1 is treated with MnO2, elemental sulfur, or selenium, the uncoordinated phosphorus atom undergoes oxidation to form a PE bond resulting in the formation of complexes of the type [Cu(kappa(2)-P,P'-DPEphos)(kappa(2)-P,E-DPEphos-E)][BF4] (2, E = O; 3, E = S; 4, E = Se) containing a Cu-E bond. The zigzag polymeric Cu-I complex [Cu(kappa(2)-P,P'-DPEphos)(mu-4,4'-bpy)](n)[BF4](n) (5) was …
Ligands and receptors: common theme in insect storage protein transport.
1999
The passage of macromolecules through biological membranes is an essential process for all multicellular organisms. Insects have developed a mechanism different from that known for all other eukaryotes investigated so far. This review discusses the function and evolution of this mechanism. Insect pupae do not feed during metamorphosis. Therefore they depend on material that has been accumulated during the larval life. At the end of this period, shortly before pupariation, a rise in titer of ecdysteroid hormones induces the incorporation of a large fraction of storage proteins (hexamerins) from the body fluid into the fat body cells. The transport of hexamerins across the cell-membrane is me…
La mesura de l'ús de les llengües en els mitjans telemàtics
2020
La consolidació de l'entorn digital i totes les seues modalitats de comunicació ha ampliat les possibilitats d'interacció i, per tant, els àmbits d'ús de les llengües. Com a adaptació a aquesta nova realitat, en aquesta aproximació metodològica plantegem la combinació de diferents tècniques no reactives: explotació de fonts secundàries, observació sistemàtica, i mystery shopping. Les fonts d'observació directa ens permeten mesurar de manera efectiva l'ús de les llengües en la comunicació telemàtica. Els autors ho han aplicat específicament en l'administració local i en empreses de serveis. En l'àmbit administratiu, a més, això ens ha servit per a desenvolupar un índex global de presència de…
Atomically Precise, Thiolated Copper–Hydride Nanoclusters as Single-Site Hydrogenation Catalysts for Ketones in Mild Conditions
2019
Copper-hydrides are known catalysts for several technologically important reactions such as hydrogenation of CO, hydroamination of alkenes and alkynes, and chemoselective hydrogenation of unsaturated ketones to unsaturated alcohols. Stabilizing copper-based particles by ligand chemistry to nanometer scale is an appealing route to make active catalysts with optimized material economy; however, it has been long believed that the ligand-metal interface, particularly if sulfur-containing thiols are used as stabilizing agent, may poison the catalyst. We report here a discovery of an ambient-stable thiolate-protected copper-hydride nanocluster [Cu25H10(SPhCl2)18]3- that readily catalyzes hydrogen…
La dote, il ius singulare e il ‘sistema didattico’ di Gaio
2016
This paper discusses the idea that the gap regarding the dowry in Gaius’ Institutes is due to the fact that Gaius intentionally did not deal with this subject because he considered it as 'ius singulare' and that this omission was filled in by a 'liber singularis' outside the Institutes. The existence of a "didactic system" made up of the Gaius’ Institutes and four 'libri singulares' for the classical age of Roman Law is also disputed.