Search results for "uci"

showing 10 items of 5317 documents

El aliud pro alio en Italia entre el Código Civil y el Código del consumo. Nuevas tendencias en tema de causa en concreto

2022

Este trabajo tiene como objeto de análisis las nuevas tendencias en tema del aliud pro alio en el ordenamiento jurídico italiano con especial atención a las relaciones entre la disciplina general del Código Civil, por un lado, y la del Código del Consumo, por otro lado, por medio del concepto de “causa en concreto” del contrato

aliud pro alioresolución del contrat:CIENCIAS JURÍDICAS Y DERECHO [UNESCO]incumplimientoUNESCO::CIENCIAS JURÍDICAS Y DERECHO
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Extensive Evaluation of a Diffusion Denuder Technique for the Quantification of Atmospheric Stable and Radioactive Molecular Iodine

2010

In this paper we present the evaluation and optimization of a new approach for the quantification of gaseous molecular iodine (I(2)) for laboratory- and field-based studies and its novel application for the measurement of radioactive molecular iodine. alpha-Cyclodextrin (alpha-CD) in combination with (129)I(-) is shown to be an effective denuder coating for the sampling of gaseous I(2) by the formation of an inclusion complex. The entrapped (127)I(2) together with the (129)I(-) spike in the coating is then released and derivatized to 4-iodo-N,N-dimethylaniline (4-I-DMA) for gas chromatography-mass spectrometry (GC-MS) analysis. The (127)I(2) collected can be differentiated from the (129)I(-…

alpha-CyclodextrinsTime FactorsAnalytical chemistrychemistry.chemical_elementIodineMass spectrometryGas Chromatography-Mass SpectrometryDiffusionIodine Radioisotopeschemistry.chemical_compoundGermanyEnvironmental ChemistryDerivatizationDetection limitAir PollutantsChromatographyAtmosphereChemistryReproducibility of ResultsGeneral ChemistryIodine RadioisotopesVolumetric flow rateAir Pollutants RadioactiveGasesGas chromatographyGas chromatography–mass spectrometryIrelandEnvironmental MonitoringEnvironmental Science & Technology
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Photocrosslinking of dextran and polyaspartamide derivatives: a combination suitable for colon-specific drug delivery.

2007

Abstract The aim of this study was to prepare and characterize novel hydrogels with polysaccharide–polyaminoacid structure, able to undergo an enzymatic hydrolysis in the colon and potentially useful for treating inflammatory bowel diseases (IBD). Starting materials were methacrylated dextran (DEX-MA) and methacrylated α,β-poly(N-2-hydroxyethyl)- dl -aspartamide (PHM). These polymers were photocrosslinked by exposure of their aqueous solutions at 313 nm without photoinitiators. Different samples, shaped as microparticles, were obtained as a function of polymer concentration and irradiation time. FT-IR analysis confirmed the occurrence of a co-crosslinking between DEX-MA and PHM in all exper…

alpha; beta-poly(n-2-hydroxyethyl)-dl-aspartamide; biodegradable hydrogels; colon drug delivery; dextran; photocrosslinking; α; β-poly(n-2-hydroxyethyl)-dl-aspartamidealphaCell SurvivalColonPhotochemistryDrug CompoundingαPharmaceutical ScienceDosage formchemistry.chemical_compoundDrug StabilityEnzymatic hydrolysismedicineCell AdhesionOrganic chemistryHumansParticle Sizeβ-poly(n-2-hydroxyethyl)-dl-aspartamideDrug CarriersChromatographyDextranaseAqueous solutionChemistryHydrolysisbiodegradable hydrogelstechnology industry and agriculturecolon drug deliveryBeclomethasoneMucinsDextransHydrogelsHydrogen-Ion ConcentrationDextranCross-Linking Reagentsbeta-poly(n-2-hydroxyethyl)-dl-aspartamidedextranDrug deliverySelf-healing hydrogelsMethacrylatesSwellingmedicine.symptomphotocrosslinkingCaco-2 CellsPeptidesJournal of controlled release : official journal of the Controlled Release Society
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Multidimensionality and intra-individual variation in host manipulation by an acanthocephalan

2008

Parasitology, 135 (5)

altered host phenotype; plastic/flexible behaviour; repeatability; Asellus aquaticus; Acanthocephala; intermediate host; isopodZoologyColoraltered host phenotypeAcanthocephalaHost-Parasite InteractionsIsopodaAnimalsAsellus aquaticusrepeatabilitybiologyBehavior AnimalHost (biology)Acanthocephalus luciiEcologyisopodintermediate hostIntermediate hostbiology.organism_classificationIntra individualCrustaceanInfectious DiseasesPhenotypeAnimal Science and ZoologyParasitologyAcanthocephalaplastic/flexible behaviourIsopoda
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Localización y convicción en las alucinaciones auditivas en psicosis

2017

La tesis doctoral, en su introducción presenta una reseña histórica del concepto de alucinación y su desarrollo en la práctica clínica a través del tiempo hasta la actualidad. Después de la introducción, se muestra una propuesta de clasificación de las alucinaciones teniendo en cuenta diversos criterios, en los que se han basado clasificaciones anteriores. 1. Alucinaciones orgánicas 2. Alucinaciones no orgánicas 3. Pseudoalucinaciones 4. Clasificación de las alucinaciones según su modalidad sensorial (independientemente de que sean orgánicas o no orgánicas) Posteriormente y ya con carácter más concreto, el desarrollo del presente trabajo se centra en el fenómeno pseudoalucinatorio, motivo p…

alucinacionespsicosisconvicciónUNESCO::CIENCIAS MÉDICASlocalización:CIENCIAS MÉDICAS [UNESCO]
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Validation of a Portuguese version of the Groningen radiotherapy-induced xerostomia questionnaire

2022

The aim of this study was to validate and determine at pretest level the reliability of the Portuguese version of the Groningen radiotherapy-induced xerostomia questionnaire. This study employed 37 head and neck cancer patients. Each patient signed an informed consent and responded to the Portuguese version of the questionnaire in the form of an interview. This was repeated again after 2 weeks. A standard single question provided a validity check. Data were analyzed using Cronbach?s ? to test its reliability and total and interitem correlation, and intraclass correlation to determine its internal consistency and test-retest reliability. Construct validity supported by objective measurements…

alveolar bone graftingsurgical wound dehiscencePortugalPsychometricsReproducibility of ResultsXerostomiabone regenerationOtorhinolaryngologyHead and Neck Neoplasmsdental implantsSurveys and QuestionnairesHumansSurgerysoft tissue managementGeneral DentistryUNESCO:CIENCIAS MÉDICASMedicina Oral Patología Oral y Cirugia Bucal
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Enantiodifferentiation of N-benzyloxycarbonylaminophosphonic and phosphinic acids and their esters using cyclodextrins by means of capillary electrop…

2005

Capillary electrophoresis was successfully applied for separation of the enantiomers of N-benzyloxycarbonyl-alpha-aminophosphonic and alpha-aminophosphinic acids as well as their ethyl and phenyl monoesters with the use of a range of commercially available cyclodextrins (alpha, beta and hydroxypropyl-gamma-cyclodextrins) as chiral selectors. The dependence of effectiveness of separation on type and concentration of these chiral selectors as well as on pH of background electrolyte was examined in some detail.

aminophosphinatesaminophosphonatesOrganophosphonatescapillary electrophoresisElectrolyteBiochemistryAnalytical ChemistryInclusion compoundchemistry.chemical_compoundCapillary electrophoresisOrganic chemistrychemistry.chemical_classificationChromatographycyclodextrinsMolecular StructureCyclodextrinChemistryOrganic ChemistryenantiodiscriminationElectrophoresis CapillaryReproducibility of ResultsEstersStereoisomerismGeneral MedicineHydrogen-Ion ConcentrationPhosphinic AcidsPhosphinic AcidsPhase compositionEnantiomerJournal of Chromatography A
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Unusual activity pattern of leucine aminopeptidase inhibitors based on phosphorus containing derivatives of methionine and norleucine

2010

Ligands containing bulky aliphatic P1 residues exhibit a high affinity towards cytosolic leucine aminopeptidase, a bizinc protease of biomedical significance. According to this specificity, a series of phosphonic and phosphinic compounds have been put forward as novel putative inhibitors of the enzyme. These phosphonic and phosphinic compounds were derivatives of methionine and norleucine as both single amino acids and dipeptides. The designed inhibitors were synthesised and tested towards the peptidase isolated from porcine kidneys using an improved separation procedure affording superior homogeneity. Unexpectedly, organophosphorus derivatives of methionine and norleucine exhibited moderat…

aminophosphinatesaminophosphonatesSwineStereochemistrymedicine.medical_treatmentNorleucinenorleucineKidneyAminopeptidaseLeucyl Aminopeptidasechemistry.chemical_compoundinhibitorsDrug DiscoverymedicineAnimalsEnzyme Inhibitorscytosolic leucine aminopeptidasemethioninePharmacologychemistry.chemical_classificationProteaseMethionineMolecular StructurePhosphorusphosphorus containing dipeptidesGeneral MedicineAmino acidEnzyme ActivationCytosolEnzymechemistryBiochemistryLeucineJournal of Enzyme Inhibition and Medicinal Chemistry
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Phosphonic Acid Analogues of Phenylglycine as Inhibitors of Aminopeptidases: Comparison of Porcine Aminopeptidase N, Bovine Leucine Aminopeptidase, T…

2019

The inhibitory activity of 14 racemic phosphonic acid analogs of phenylglycine, substituted in aromatic rings, towards porcine aminopeptidase N (pAPN) and barley seed aminopeptidase was determined experimentally. The obtained patterns of the inhibitory activity against the two enzymes were similar. The obtained data served as a basis for studying the binding modes of these inhibitors by pAPN using molecular modeling. It was found that their aminophosphonate fragments were bound in a highly uniform manner and that the difference in their affinities most likely resulted from the mode of substitution of their phenyl rings. The obtained binding modes towards pAPN were compared, with these predi…

aminophosphonateMolecular modelStereochemistryPharmaceutical Sciencelcsh:Medicinelcsh:RS1-441AminopeptidaseArticlelcsh:Pharmacy and materia medica03 medical and health sciences0302 clinical medicineDrug Discoveryinhibitorsaminopeptidases030304 developmental biologychemistry.chemical_classification0303 health sciencesChemistrymolecular modelingAminopeptidase Nlcsh:RAromaticityAffinitiesEnzymefluorine substitutedAminophosphonate030220 oncology & carcinogenesisMolecular Medicinephenylglycine analoguesLeucinePharmaceuticals
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α-Aminoalkylphosphonates as a tool in experimental optimisation of P1 side chain shape of potential inhibitors in S1 pocket of leucine- and neutral a…

2005

Abstract The synthesis and biological activity studies of the series of structurally different α-aminoalkylphosphonates were performed in order to optimise the shape of the side chain of the potential inhibitors in S1 pocket of leucine aminopeptidase [E.C.3.4.11.1]. Analysis of a series of compounds with aromatic, aliphatic and alicyclic P1 side chains enabled to find out the structural features, optimal for that fragment of inhibitors of LAP. The most active among all investigated compounds were the phosphonic analogues of homo-tyrosine ( K i  = 120 nM) and homo-phenylalanine ( K i  = 140 nM), which even as racemic mixtures were better inhibitors in comparison with the best till now-phosph…

aminophosphonatesStereochemistryleucine aminopeptidaseOrganophosphonatesKidneyAminopeptidasesChemical synthesisAminopeptidaseLeucyl AminopeptidaseStructure-Activity RelationshipAlicyclic compoundLeucineDrug DiscoverySide chainAnimalsLeucyl aminopeptidasePharmacologychemistry.chemical_classificationBinding SitesMolecular StructureAminopeptidase NOrganic ChemistryBiological activityGeneral MedicineHydrogen-Ion Concentrationaminopeptidase NinhibitorEnzymechemistryLeucineEuropean Journal of Medicinal Chemistry
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