Search results for "ultraviolet"
showing 10 items of 853 documents
UV–Vis, IR, Raman and theoretical characterization of a novel quinoid oligothiophene molecular material
2003
A quinoid-type oligothiophene, 3 0 ,4 0 -dibutyl-5,5 00 -bis(dicyanomethylene)-5,5 00 -dihidro-2,2 0 :5 0 ,2 00 -terthiophene, which can be viewed as an analog of TCNQ, has been investigated by spectroelectrochemistry and density functional theory calculations, in its neutral and dianionic states. Electrochemical data show that the molecule can be both reduced and oxidized at relatively low potentials. Upon reduction, both experiments and theory agree well with the generation of a dianionic charged species. The model shows that the electronic structure of the dianion is consistent with two anionic dicyanomethylene groups attached to a central terthienyl spine having an aromatic structure. T…
Hands-on optics and photonics outreach in Riga
2014
A long-term exposition focused on optics and photonics was created in Institute of Atomic Physics and Spectroscopy at University of Latvia in 2010. Considering unpopularity of science in Latvia and lack of broadly accessible hands-on outreach activities for school children, as well as rapid development of advanced photonic technologies, this exposition was meant to involve more students to the natural sciences and modern technologies. Exposition covers 10 topics of optics – colors, diffraction, interference, polarization, reflection, liquid crystals, gas discharge, lasers, fluorescence, infrared and ultraviolet radiation. Students' visits are organized as an exciting adventure, which differ…
C172S Substitution in the Chloroplast-encoded Large Subunit Affects Stability and Stress-induced Turnover of Ribulose-1,5-bisphosphate Carboxylase/Ox…
1999
Previous work has indicated that the turnover of chloroplast ribulose-1,5-bisphosphate carboxylase/oxygenase (Rubisco; EC 4.1.1. 39) may be controlled by the redox state of certain cysteine residues. To test this hypothesis, directed mutagenesis and chloroplast transformation were employed to create a C172S substitution in the Rubisco large subunit of the green alga Chlamydomonas reinhardtii. The C172S mutant strain was not substantially different from the wild type with respect to growth rate, and the purified mutant enzyme had a normal circular dichroism spectrum. However, the mutant enzyme was inactivated faster than the wild-type enzyme at 40 and 50 degrees C. In contrast, C172S mutant …
Improvement of the Valencia region ultraviolet index (UVI) forecasting system
2012
The CEAM Foundation (Valencia, Spain) has developed an operational ultraviolet index (UVI) forecasting system based on the Santa Barbara DISORT Atmospheric Radiative Transfer (SBDART) model. The main objective of this system is to provide the general public with a tool to minimize the impact of ultraviolet (UV) radiation, which can cause important human health problems. The system presented in this paper has been developed in collaboration with the Environment Department of the Regional Government of Valencia, and it replaces the one running until 2007. The new system substitutes the previously used Ozone Monitoring Instrument (OMI) observed data with the total ozone column data forecasted …
Aging of biogenic secondary organic aerosol via gas-phase OH radical reactions
2012
The Multiple Chamber Aerosol Chemical Aging Study (MUCHACHAS) tested the hypothesis that hydroxyl radical (OH) aging significantly increases the concentration of first-generation biogenic secondary organic aerosol (SOA). OH is the dominant atmospheric oxidant, and MUCHACHAS employed environmental chambers of very different designs, using multiple OH sources to explore a range of chemical conditions and potential sources of systematic error. We isolated the effect of OH aging, confirming our hypothesis while observing corresponding changes in SOA properties. The mass increases are consistent with an existing gap between global SOA sources and those predicted in models, and can be described b…
Boreal fishes and ultraviolet radiation : actions of UVR at molecular and individual levels
2005
Eeva-Riikka Vehniäinen on väitöskirjatyössään tutkinut UV-säteilyn vaikutuksia siian, hauen ja muikun poikasissa. Ihmisen aiheuttama otsonikerroksen ohentuminen on lisännyt maan pinnalle saapuvan ultravioletti-B-säteilyn (UVB) määrää viime vuosikymmenten aikana, ja lisääntymisen odotetaan jatkuvan vielä noin 2050-luvulle saakka. UVB-säteily on haitallista eliöille, koska se aiheuttaa vaurioita solun keskeisissä rakenteissa: DNA:ssa, proteiineissa ja lipideissä.Vehniäinen arvioi lisääntyvän UVB-säteilyn aiheuttamaa riskiä taloudellisesti ja ekologisesti tärkeille makeanveden kalalajeillemme, siialle, muikulle ja hauelle, niiden herkimmässä elämänvaiheessa välittömästi kuoriutumisen jälkeen. …
Gilding and pigments of Renaissance marble of Abatellis Palace: non-invasive investigation by XRF spectrometry
2012
Most of the artworks constituting the collection of Renaissance statuary of Abatellis Palace in Palermo (Sicily) show evidence of colour layers and fragments of gold foil that probably once covered the whole marble surface. The restoration of some of these statues has allowed to carry out archaeometric studies about the painting technique and to highlight the original materials and inclusion present on the precious marbles by two famous Italian sculptors of the Renaissance, Francesco Laurana and Antonello Gagini. The measurements have been performed in situ through the integrated use of two non-invasive techniques: visible fluorescence stimulated by ultraviolet light and X-ray fluorescence.…
Photoinduced toxicity of retene to Daphnia magna under enhanced UV-B radiation.
2001
Abstract The effects of UV radiation on the acute toxicity of retene (7-isopropyl-1-methylphenanthrene) to Daphnia magna Straus were studied. Dehydroabietic acid (DHAA) from which retene is formed in the vicinity of pulp and paper industry was also studied. Pyrene, anthracene, and phenanthrene were used as model PAH compounds. The time taken for immobilization (ET50) was monitored under biologically effective UV-B dose rates of 240, 365, 565, and 650 mW m−2 (UV-A and visible light also present). Median effective concentrations (EC50) were determined after a 15-min UV exposure (565 mW m−2) followed by 24 h in the dark. Retene ( 10–320 μg l −1 ) was not acutely toxic in the dark. The inductio…
Successful treatment of adult multisystemic Langerhans cell histiocytosis with psoralen-UV-A, prednisolone, mercaptopurine, and vinblastine.
2008
Background Langerhans cell histiocytosis (LCH) is a rare disease with a peak incidence in childhood. There is limited experience with treatment options for adult patients having multisystemic LCH involvement. We report successful treatment of a 70-year-old woman with adult onset of LCH and multisystem disease (diabetes insipidus centralis, bone marrow infiltration, and lung and skin involvement). Observations A 70-year-old woman with erythematous plaques and papules of the submammary and inguinal skin attended our outpatient clinic and was diagnosed as having LCH. Organ involvement was found in the infundibulum of the pituitary gland, associated with diabetes insipidus centralis, bone marro…
Recognition and alignment of variables from UV–vis chromatograms and application to industrial enzyme digests classification
2017
Abstract In the last years, industrial applications of chemometrics have largely increased due to their capacity to extract important information from complex records as chromatograms or spectra data. The use of chemometric methods also can avoid the use of detectors of elevated cost. In this work, a procedure to recognize the relevant chemical information contained in complex UV–vis chromatograms, after a trypsin digestion, to identify the three enzyme main classes (proteases, amylases and cellulases) commonly employed in the cleaning industry, has been developed. In order to recognize the chromatogram peaks, six indices of peak identity or identifiers were defined. A program written in MA…