Search results for "version"
showing 10 items of 1591 documents
Hydrogen bond-mediated conjugates involving lanthanide diphthalocyanines and trifluoroacetic acid (Lnpc2@TFA): Structure, photoactivity, and stability
2020
The interaction between lanthanide diphthalocyanine complexes, LnPc2 (Ln = Nd, Sm, Eu, Gd, Yb, Lu
The impact of conversion on the risk of major complication following laparoscopic colonic surgery: an international, multicentre prospective audit.
2018
BACKGROUND: Laparoscopy has now been implemented as a standard of care for elective colonic resection around the world. During the adoption period, studies showed that conversion may be detrimental to patients, with poorer outcomes than both laparoscopic completed or planned open surgery. The primary aim of this study was to determine whether laparoscopic conversion was associated with a higher major complication rate than planned open surgery in contemporary, international practice.METHODS: Combined analysis of the European Society of Coloproctology 2017 and 2015 audits. Patients were included if they underwent elective resection of a colonic segment from the caecum to the rectosigmoid jun…
Nodal Solutions for Supercritical Laplace Equations
2015
In this paper we study radial solutions for the following equation $$\Delta u(x)+f (u(x), |x|) = 0,$$ where $${x \in {\mathbb{R}^{n}}}$$ , n > 2, f is subcritical for r small and u large and supercritical for r large and u small, with respect to the Sobolev critical exponent $${2^{*} = \frac{2n}{n-2}}$$ . The solutions are classified and characterized by their asymptotic behaviour and nodal properties. In an appropriate super-linear setting, we give an asymptotic condition sufficient to guarantee the existence of at least one ground state with fast decay with exactly j zeroes for any j ≥ 0. Under the same assumptions, we also find uncountably many ground states with slow decay, singular gro…
Experimental characterization of Ruthenium-based Dye Sensitized Solar Cells and study of light-soaking effect impact on performance
2016
In this paper, we present an experimental investigation on the performance of Ruthenium-based Dye Sensitized Solar Cells (DSSCs) at different irradiance levels, incident wavelengths and hours of illumination. In particular, the measurements have been aimed at studying the performance variation due to light soaking effect since this phenomenon has noteworthy practical implications, such as stability tests of DSSCs. Our results show that the short circuit current density, the open circuit voltage and the conversion efficiency η increase with the hours of light soaking. Finally, the observed phenomenon is reversible, and thus the performance decreases again when the cell is kept in the dark.
Assessment of workflow feature selection on forest LAI prediction with sentinel-2A MSI, landsat 7 ETM+ and Landsat 8 OLI
2020
The European Space Agency (ESA)’s Sentinel-2A (S2A) mission is providing time series that allow the characterisation of dynamic vegetation, especially when combined with the National Aeronautics and Space Administration (NASA)/United States Geological Survey (USGS) Landsat 7 (L7) and Landsat 8 (L8) missions. Hybrid retrieval workflows combining non-parametric Machine Learning Regression Algorithms (MLRAs) and vegetation Radiative Transfer Models (RTMs) were proposed as fast and accurate methods to infer biophysical parameters such as Leaf Area Index (LAI) from these data streams. However, the exact design of optimal retrieval workflows is rarely discussed. In this study, the impact of…
Valor de los Ahorros en Impuestos por Deuda en Colombia: Un Estudio Empírico (Value of Debt Tax Shields in Colombia: An Empirical Study)
2011
The English version of this paper can be found at http://ssrn.com/abstract=1919305This paper estimates the value of tax savings, using the method of discounted cash flows for 23 major industrial firms in the Bolsa de Valores de Colombia (Colombian Stock Market) between 2001 and 2010, showing that this value represents on average between 5.74% and 56.73% out of total firm value depending on discount rate for tax savings. Using Data Panel regressions, it also finds that the average leverage of firms is low relative to other countries. Given this fact, we explored the behavior of the total value of the firm, VT and found no evidence that debt creates value.
Pisanie pomiędzy kulturami : twórczość obcojęzyczna pisarek z Europy Środkowej
2015
Harvesting Fluorescence from Efficient Tk -> Sj (j, k > 1) Reverse Intersystem Crossing for ??* Emissive Transition-Metal Complexes
2013
Using a bimetallic Au(I) complex bearing alkynyl-(phenylene)3-diphosphine ligand (A-3), we demonstrate that the fluorescence can be exquisitely harvested upon T1 → Tk (k > 1) excitation followed by Tk → Sj (j, k > 1) intersystem crossing (ISC) back to the S1 state. Upon S0 → S1 355 nm excitation, the S1 → T1 intersystem crossing rate has been determined to be 8.9 × 108 s–1. Subsequently, in a two-step laser pump–probe experiment, following a 355 nm laser excitation, the 532 nm T1 → Tk probing gives the prominent blue 375 nm fluorescence, and this time-dependent pump–probe signal correlates well with the lifetime of the T1 state. Careful examination reveals the efficiency of Tk → Sj (j, k > …
Synthesis of new orthometallated iridium(III) compounds by chemical and electrochemical methods
1987
Abstract Replacement of one phosphine ligand in IrCl 3 (η 2 -PCBr)(η 1 -PCBr) ( 1 ) (PCBr = P( o -BrC 6 F 4 )Ph 2 ), by various P-donor ligands has given compounds of stoichiometry IrCl 3 (η 2 -PCBr)L ( 3 : L = PMePh 2 ; 4 : L = P( p -MeC 6 H 4 ) 3 ; 5 : L = P(OMe) 3 , 6 : L = P(OPh) 3 ). All of these show two irreversible reduction peaks in the range −1.1, −1.3 and ca. −2.0 V. The electrochemical reduction of compound 1 at −1.5 V (at 0°C) leads to a very reactive iridium(I) species, probably IrCl(PCBr) 2 , which undergoes intramolecular orthometallation at room temperature. Three compounds are obtained as the results of this chemical conversion: IrBr 2 (PC)(PCBr) ( 7 ), IrCl 2 (PC)(PCBr) (…
Contexto editorial, cultural y socio-político de la edición príncipe de la «Historia de la doncella Teodor» (Toledo: Pedro Hagenbach, 1500-1501)
2021
The material analysis of the only surviving copy of the editio princeps of the Historia de la doncella Teodor allows us to date it back to the incunabula era and to attribute its printing to Pedro Hagenbach’s workshop. The close relationship amongst Hagenbach’s workshop, the reformist project of Archbishop Cisneros, and the interests of the Catholic Monarchs sets an editorial and cultural context that supports the adaptation of Teodor to the printing press. This work perfectly agreed with the thematic and ideological guidelines for the renewal of Christian customs and values. The forceful religious and intellectual imposition of the young and learned slave, turned into a “fijadalgo” in the …