Search results for "visual"

The Perpetrator's mise-en-scene: Language, Body, and Memory in the Cambodian Genocide

2018

Rithy Panh's film S-21. The Khmer Rouge Killing Machine (2003) was the result of a three-year shooting period in the Khmer Rouge centre of torture where perpetrators and victims exchanged experiences and re-enacted scenes from the past under the gaze of the filmmaker's camera. Yet, a crucial testimony was missing in that puzzle: the voice of the prison's director, Kaing Guek Eav, comrade Duch. When the Extraordinary Chambers in the Courts of Cambodia (ECCC) were finally established in Phnom Penh to judge the master criminals of Democratic Kampuchea, the first to be indicted was this desk criminal. The film Duch, Master of the Forges of Hell (R. Panh, 2011) deploys a new confrontation – an a…

<title>Two-dimensional and dynamic (2DD) method of visualization of the flow characteristics in a convection boundary layer using infrared ther…

2000

The paper presents the 2D and dynamic (2DD) method of using infrared (IR) thermography for the visualization of the cooling efficiency of a heated wall, as this method was applied in an experimental investigation. The 2DD method allows the outer surface temperature measured by the IR thermography device to be worked out relative to the bulk coolant-fluid temperature. In this way the 2DD method makes visible the qualitative and quantitative flow characteristics within the thin contact layers at the inner surface of the wall. This flow characteristics, and more specifically the pattern of stream lines (for the detection of dead zones) and the distribution of the temperature differences betwee…

2018

This study presents new ways of visualising technology-enhanced collaborative inquiry-based learning (CIBL) processes in an undergraduate physics course. The data included screen-capture videos fro...

New planar polynitrile dianion and its first coordination polymer with unexpected short M⋯M contacts (tcno2−=[(NC)2CC(O)C(CN)2]2−)

2008

International audience; A new planar polynitrile dianion ([tcno]2− = [(NC)2CC(O)C(CN)2]2−) has been synthesized as its potassium salt, K2[tcno] (1). The crystallization of 1 by the slow evaporation of an aqueous solution at room temperature gave two types of colourless crystals having two different shapes [1-A: fine plates and 1-B: needles] for which the crystal structure determinations showed similar geometries for the polynitrile anion in both the structures. The combination of this novel dianion with Cu(II) led to the coordination complex [Cu(tcno)2(H2O)2] (2), which constitutes the first coordination complex of this dianion. The structure of 2 can be described as a coordination polymer …

Rational design of aminoanthraquinones for colorimetric detection of heavy metal ions in aqueous solution

2011

A family of water-soluble colorimetric chemosensors incorporating an anthraquinone signalling subunit functionalized with a polyamine chain that bears hydrophilic diethoxyphosphoryl moieties was prepared with the aim of assaying metal cations. The outstanding UV-Vis absorption properties of the 1-aminoanthraquinone chromophore allowed the efficient visual detection and quantification of copper(II) ions by chelators L(1)-L(3) in buffered aqueous solution. Moreover, the visible response of L(2) is not interfered by addition of large excesses of 13 common metal ions, whereas chemosensor L(3) produces also a color change in the presence of equimolar amounts of lead(II). Considering the 134 nm g…

A Two-State Computational Investigation of Methane C-H and Ethane C-C Oxidative Addition to [CpM(PH3)]n+ (M=Co, Rh, Ir;n=0, 1)

2006

Reductive elimination of methane from methyl hydride half-sandwich phosphane complexes of the Group 9 metals has been investigated by DFT calculations on the model system [CpM(PH(3))(CH(3))(H)] (M = Co, Rh, Ir). For each metal, the unsaturated product has a triplet ground state; thus, spin crossover occurs during the reaction. All relevant stationary points on the two potential energy surfaces (PES) and the minimum energy crossing point (MECP) were optimized. Spin crossover occurs very near the sigma-CH(4) complex local minimum for the Co system, whereas the heavier Rh and Ir systems remain in the singlet state until the CH(4) molecule is almost completely expelled from the metal coordinati…

1H-NMR study of a cobalt-substituted blue copper protein: Pseudomonas aeruginosa Co(II)-azurin.

1995

Substitution of copper by cobalt in blue copper proteins gives a paramagnetic metalloderivative suitable for paramagnetic NMR studies. A thorough analysis of the 1H-NMR spectrum of Pseudomonas aeruginosa Co(II)-azurin is presented here. All the observable contact-shifted signals as well as many other paramagnetic signals from protons placed up to about 1.0 nm around the metal center, including some residues belonging to functionally important parts of the protein like the hydrophobic patch and the His35 region, have been assigned. The results obtained permit the detection and study of structural variations like those originated by the His35 ionization, and allow us to draw a feasible pictur…

Molecular, Supramolecular Structures Combined with Hirshfeld and DFT Studies of Centrosymmetric M(II)-azido {M=Ni(II), Fe(II) or Zn(II)} Complexes of…

2021

The supramolecular structures of the three metal (II) azido complexes [Fe(4bzpy)4(N3)2]

“Art as a Way to Life”: Bereavement and the Healing Power of Arts and Writing

2003

Reading, writing, music, and fine arts are widely acknowledged to have therapeutic value to those bereaved. Narratives of coping with the help of arts are commonly told. Yet, the experiences of bereavement and the healing powers of arts and writing are rarely discussed and analyzed in social sciences. In this article, I search for a way to study the therapeutic power of arts and writing on a personal level. Using empathy as a metaphorical tool, I read an unpublished autobiography about a mother's grief and coping process through my own experiences of bereavement. I strive for emotional verisimilitude and apply a poetic form when citing the autobiography to highlight the evocative tone of t…

One-dimensional oxalato-bridged copper(II) complex possessing two structurally different metallic centres

2001

Abstract The crystal structure of the oxalato-bridged copper(II) compound [Cu2(μ-ox)2(ampy)3]n 1 (ox=oxalate dianion, ampy=2-amino-3-methylpyridine) consists of infinite corrugated one-dimensional chains in which two types of copper(II) centres, five- and six-coordinated, are bridged sequentially by asymmetric bis-bidentate oxalato ligands. Magnetic susceptibility measurements show the occurrence of a significant intrachain antiferromagnetic coupling (J=−22.9 cm −1 ) .