Search results for "wt"
showing 10 items of 5424 documents
Cyclodextrins in polymer synthesis: polymerization of methyl methacrylate under atom-transfer conditions (ATRP) in aqueous solution
2000
Host guest complexes of methyl methacrylate (MMA) and randomly methylated β-cyclodextrin (m-β-CD, 1 a) were polymerized in aqueous medium using atom-transfer radical polymerization. Ethyl 2-bromoisobutyrate (EBIB) was used as an initiator, copper(I) bromide as the catalyst, and bipyridine (bipy) or 4,4′-di-(5-nonyl)-2,2´-bipyridine (dNbipy) as ligands. The unthreading of m-β-CD during the polymerization led to water-insoluble poly(methyl methacrylate) (PMMA). It was found that using dNbipy resulted in higher monomer conversion than using bipy as the ligand under similar conditions. Furthermore, it is shown that the polymerization of MMA under these conditions has a living character. The pol…
Group transfer and anionic polymerization: A critical comparison
1990
The mechanism of group transfer polymerization (GTP) of methacrylates in THF is investigated by using data on kinetics of homo- and copolymerization, polymer microstructure and molecular weight distribution. By comparison with corresponding data on anionic polymerization it is concluded that the mechanisms of monomer addition to the active chain end is very similar for both anionic and group transfer polymerization and that GTP is ionic in character. On the other hand, GTP uniquely is characterized by the existence of a catalyst exchange equilibrium. The position of this equilibrium determines the rates of polymerization, and the dynamics determine the molecular weight distribution.
Preparation of Hyperbranched Polyacrylates by Atom Transfer Radical Polymerization. 2. Kinetics and Mechanism of Chain Growth for the Self-Condensing…
1997
The self-condensing vinyl polymerization (SCVP) of 2-((2-bromopropionyl)oxy)ethyl acrylate (BPEA) has resulted in the formation of hyperbranched polyacrylates. The polymerization mechanism used to polymerize the BPEA was atom transfer radical polymerization (ATRP), a “living”/controlled radical polymerization. This paper details the study of the kinetics of polymerization and the growth of the macromolecule during the polymerization. The results obtained in the polymerization were compared to the theoretical predictions for SCVP. It was determined that the polymerization deviated from the ideal case, as a consequence of the establishment of a dynamic equilibrium in ATRP resulting in the add…
Polymerization of 3-alkylthiophenes with FeCl3
1992
We report on the mechanism of direct oxidation of 3-alkylthiophenes using ferric chloride (FeCl3) as the polymerization oxidant/catalyst to produce high molecular weight poly(3-alkylthiophenes) (P3ATs), conjugated polymers that have potential as electrically and optically active polymers. This study shows that the FeCl3 must exist in the solid state in the reaction mixture to be active as an oxidant in the polymerization of P3AT. A feasible polymerization mechanism for 3-alkylthiophene was developed on the basis of the crystal structure of FeCl3 and quantum chemical computations of thiophene derivatives. The polymerization is hypothesized to proceed through a radical mechanism rather than a…
Effect of hydrogen on the ethylene polymerization process over Ziegler-Natta catalysts supported on MgCl2(THF)2. II. Kinetic studies
2000
This article reports on a study of the effects of hydrogen on the activity of vanadium and titanium catalysts supported on MgCl 2 (THF) 2 in ethylene polymerization. It was found that hydrogen did not change the stable nature of the active sites and the polydispersity index of the polyethylene obtained. The propagation rate, expressed as k p , was found to be independent of the presence and concentration of hydrogen, indicating that this reacting agent does not modify the reactivity of the active sites. However, the presence of hydrogen in the polymerization medium is responsible for partial deactivation of the active sites just before polymerization is initiated.
Peculiar behavior of degenerative chain transfer polymerization of a phosphonated methacrylate
2009
Living/controlled radical polymerization of dimethyl(methacryloyloxy)methyl phosphonate (MAPC) has been attempted using degenerative transfer to produce block copolymers. RAFT polymerization of this monomer is sensitive to very low level of oxygen and in any case limited to low monomer conversion. Reverse iodine transfer polymerization (RITP) leads to higher monomer conversion with a limited amount of living polymer (55% by H NMR), precluding an efficient synthesis of block copolymers. A PMMA-b-PMAPC diblock copolymer was therefore synthesized by iodine transfer polymerization (ITP) of MAPC from a PMMA-Imacro-chain transfer agent prepared by RITP. The diblock copolymer, purified by selectiv…
On Codimensions of Algebras with Involution
2020
Let A be an associative algebra with involution ∗ over a field F of characteristic zero. One associates to A, in a natural way, a numerical sequence \(c^{\ast }_n(A),\)n = 1, 2, …, called the sequence of ∗-codimensions of A which is the main tool for the quantitative investigation of the polynomial identities satisfied by A. In this paper we focus our attention on \(c^{\ast }_n(A),\)n = 1, 2, …, by presenting some recent results about it.
Varieties of Superalgebras of Polynomial Growth
2017
∗ The author was partially supported by MIUR of Italy.
Upper bounds for the zeros of ultraspherical polynomials
1990
AbstractFor k = 1, 2, …, [n2] let xnk(λ) denote the Kth positive zero in decreasing order of the ultraspherical polynomial Pn(λ)(x). We establish upper bounds for xnk(λ). All the bounds become exact when λ = 0 and, in some cases (see case (iii) of Theorem 3.1), also when λ = 1. As a consequence of our results, we obtain for the largest zero xn1(λ)0.. We point out that our results remain useful for large values of λ. Numerical examples show that our upper bounds are quite sharp.
Central Polynomials of Algebras and Their Growth
2020
A polynomial in noncommutative variables taking central values in an algebra A is called a central polynomial of A. For instance the algebra of k × k matrices has central polynomials. For general algebras the existence of central polynomials is not granted. Nevertheless if an algebra has such polynomials, how can one measure how many are there?