Search results for "xrf"
showing 10 items of 106 documents
Obsidian from the Site of Piano dei Cardoni, Ustica (Palermo, Italy): Preliminary Results on the First Occupation of the Island
2021
Abstract New investigations on Ustica (Palermo, Sicily) originated from the need to improve our knowledge of the island’s archaeological and environmental heritage. Through field surveys, particular attention was paid to human occupation in the Neolithic phases and focused on the less investigated southern side of the island. The systematic survey of the area of Piano dei Cardoni in 2018 brought to light a new Middle/Late Neolithic site, already partially documented in the literature. The island was settled for the first time during these phases, as also testified from the area of Punta Spalmatore. The presence of Serra d’Alto, incised dark burnished, and Diana styles suggests that the site…
Obsidian in the Upper Palaeolithic of Iberia
2021
Submitted by André Pereira (andrepereira@letras.ulisboa.pt) on 2021-07-28T13:04:08Z No. of bitstreams: 1 obsidian-in-the-upper-palaeolithic-of-iberia.pdf: 35662679 bytes, checksum: 4c261781e3211c52c02d47cc36e26d98 (MD5) Approved for entry into archive by Manuel Botelheiro Moreno (manuelmoreno@campus.ul.pt) on 2021-07-28T16:31:42Z (GMT) No. of bitstreams: 1 obsidian-in-the-upper-palaeolithic-of-iberia.pdf: 35662679 bytes, checksum: 4c261781e3211c52c02d47cc36e26d98 (MD5) Made available in DSpace on 2021-07-28T16:32:40Z (GMT). No. of bitstreams: 1 obsidian-in-the-upper-palaeolithic-of-iberia.pdf: 35662679 bytes, checksum: 4c261781e3211c52c02d47cc36e26d98 (MD5) Previous issue date: 2021 info:eu…
Un disco-coraza de hierro de la Bastida de les Alcusses (moixent, valencia)
2017
Se presenta un disco-coraza de hierro procedente del oppidum ibérico de la Bastida de les Alcusses documentado con motivo de la revisión completa de los hallazgos de las excavaciones realizadas entre 1928 y 1931. La pieza es una lámina seudocircular en cuyo perímetro se distribuyen unos pequeños remaches para suspender el disco a las correas de sujeción, realizadas probablemente en cuero. Después de presentar el disco y los resultados de las analíticas EDXRF que permiten identificar los metales utilizados en la producción del disco (hierro) y los remaches (plata y cobre), se analiza su contexto de hallazgo, se encuadra históricamente esta categoría de armamento defensivo. Finalmente, se int…
A combined physical-chemical and microbiological approach to unveil the fabrication, provenance, and state of conservation of the Kinkarakawa-gami ar…
2020
AbstractKinkarakawa-gami wallpapers are unique works of art produced in Japan between 1870 and 1905 and exported in European countries, although only few examples are nowadays present in Europe. So far, neither the wallpapers nor the composing materials have been characterised, limiting the effective conservation–restoration of these artefacts accounting also for the potential deteriogen effects of microorganisms populating them. In the present study, four Kinkarakawa-gami wallpapers were analysed combining physical–chemical and microbiological approaches to obtain information regarding the artefacts’ manufacture, composition, dating, and their microbial community. The validity of these met…
Decorated pottery study: Analysis of pigments by x-ray absorbance spectroscopy measurements
2007
Characterization of pigments on decorated pottery fragments has been fully carried out by nondestructive x-ray absorbance spectroscopy (XAS). The samples were a series of pottery shards excavated from the archeological site of Caltagirone (Sicily, Italy), a well-known ceramic production center. Aesthetical criteria and morphological observations allowed us to attribute the samples to quite different historical periods, starting from the 18th century B.C. up to the 16th century A.D. An extensive time interval led us to suppose that different materials and techniques were used for the production of the ceramic paste and also for the preparation of pigments. XAS measurements were performed at …
Lāzerinducētās sagraušanas spektroskopijas un enerģijas dispersīvās rengenfluoriscences metožu pielietojums zāļu tēju paraugu pētījumos
2022
Lāzerinducētās sagraušanas spektroskopijas un enerģijas dispersīvās rengenfluoriscences metožu pielietojums zāļu tēju paraugu pētījumos. Černiševs R.., darba vadītāji Mg.chem. Bērtiņš M., Dr.sc.ing. Brangule A. Bakalaura darbs, 39 lappuses, 16 attēli, 13 tabulas, 28 literatūras avoti. Latviešu valodā. Darbā tika veikta zinātniskās literatūras izpēte un apkopojums par spektroskopijas metodēm, ko var izmantot ķīmisko elementu kvalitatīvo un kvantitatīvo noteikšanai. Praktiskajā daļā tika veikta zāļu tēju analīze izmantojot rentgenfluoriscences spektroskopiju un lāzerinducētās sagraušanas spektroskopijas metodēm.
Bone diagenesis of archaeological human remains from Apulia (Italy) investigated by ATR-FTIR and XRF spectroscopy
2023
The analysis of the organic and mineral content of biological samples allows to define post-mortem alterations and the preservation status of ancient human remains. Here, we report a physical-chemical characterization of bone specimens from some skeletal remains found in Apulia (Italy) dating back to the prehistoric, classic-hellenistic, and medieval periods. Specific infrared band ratios from Attenuated Total Reflectance-Fourier Transform InfraRed and X-ray fluorescence spectroscopies were considered to evaluate the extent of the diagenetic process and the elemental composition of bone.Physical-chemical post-mortem transformations were related to the soil composition and specificity of tis…
Multi-analytical study of the medieval wall paintings from the rupestrian church Grotta del Crocifisso at Lentini (eastern Sicily): new evidence of t…
2022
AbstractThis study presents the results of the examination and characterisation of the wall paintings that decorate the rupestrian church named Grotta del Crocifisso, which is located in the territory of Lentini (eastern Sicily, few tens of kilometres from Catania and Syracuse). The earliest mural paintings in the church date back to the twelfth century AD. A multi-analytical approach was adopted for the characterisation of stone materials, secondary degradation products, and pigments. For this purpose, the following techniques were used: reflected light microscopy (RLM), polarised light microscopy on thin sections (PLM), X-ray powder diffraction (XRPD), mercury intrusion porosimetry (MIP),…
El prestigio de los objetos: mangos de marfil en el mundo ibérico
2020
El estudio se centra en una serie de mangos de marfil de características morfotécnicas similares, recuperados en espacios de hábitat y funerarios ibéricos y datados entre el s. IV y el s. II a. C. Se trata de objetos de prestigio al alcance de una élite aristocrática, que han sido elaborados con materias primas exóticas (marfil) y técnicas decorativas inusuales que indican una especialización. A través de análisis de composición por infrarrojo cercano por Transformada de Fourier (FT-NIR) y de fluorescencia de rayos X (pXRF) se ha podido documentar la presencia de incrustaciones de ámbar adheridas a la superficie de los mangos mediante el uso del estaño como soldadura blanda y el empleo de a…
The blue enamels in the baroque decorations of the churches of Palermo, Sicily: Fe2+-coloured glasses from lime kilns
2009
Deep blue glasses coloured by octahedral Fe 2+ cations are often reported as textbook examples of blue pigmentation. However, despite the possibility of laboratory synthesis under reducing conditions, to date there are no well-reported occurrences of their production and use in the past. A thorough historical, ethnographic, mineralogical, and chemico-physical investigation of the 'smaltini di calcara' from several baroque churches in Palermo, Sicily, has revealed that the blue enamels widely used for altar decorations in the 17th and 18th centuries are actually a unique case of ancient blue glasses pigmented by divalent iron cations in distorted octahedral coordination. This mixed-alkali gl…