Search results for "yield"
showing 10 items of 1338 documents
Hyaluronan-Based Graft Copolymers Bearing Aggregation-Induced Emission Flurogens
2017
In order to develop a technology platform based on two natural compounds from biorenewable resources, a short series of hyaluronan (HA) copolymers grafted with propargylated ferulic acid (HA-FA-Pg) were designed and synthesized to show different grafting degree values and their optical properties were characterized in comparison with reference compounds containing the same ferulate fluorophore. Interestingly, these studies revealed that the ferulate fluorophore was quite sensitive to the restriction of intramolecular motion and its introduction into the rigid HA backbone, as in HA-FA-Pg graft copolymers, led to higher photoluminescence quantum yield values than those obtained with the isola…
Magnetic–fluorescent Langmuir–Blodgett films of fluorophore-labeled ferritin nanoparticles
2009
Abstract We have covalently coupled fluorophore 4-(2-hydroxyethoxy)-7-nitro-2,1,3-benzoxadiazole (NBD) to the external ferritin shell through lysine residues. An increase in the luminescence quantum yield of the fluorescent ferritin particles and a blue shift in its emission peak compared to individual fluorophore were observed. The study of the particles by transmission electron microscopy showed that the native iron core ferritin is intact and that no degradation occurs during chemical functionalization of the protein shell. The NBD-labeled ferritin particles are water soluble, which allowed their controlled deposition by the Langmuir–Blodgett (LB) technique. Superparamagnetic and fluores…
Kinetic Studies of the Assembly of Plant Light Harvesting Complex II
1998
Photosynthesis relies on the correct assembly of pigment binding proteins within the thylakoid membrane. Yet, very little is known about the folding of such membrane proteins. The biochemical difficulties connected with these highly hydrophobic proteins are reflected in the low number of crystal structures available for membrane proteins to date. One of the few available, however, is that of LCHII (1). In addition, LHCII is one of only a handful of membrane proteins that can be regenerated in vitro to a native-like conformation (2,3). These two features make it a good candidate for studying its folding and assembly kinetics. Here, a preliminary study on the assembly kinetics of LHCII as a f…
Core hole screening and decay rates of double core ionized first row hydrides.
2013
Because of the high intensity, X-ray free electron lasers allow one to create and probe double core ionized states in molecules. The decay of these multiple core ionized states crucially determines the evolution of radiation damage in single molecule diffractive imaging experiments. Here we have studied the Auger decay in hydrides of first row elements after single and double core ionization by quantum mechanical ab initio calculations. In our approach the continuum wave function of the emitted Auger electron is expanded into spherical harmonics on a radial grid. The obtained decay rates of double K-shell vacancies were found to be systematically larger than those for the respective single …
Model of a Constructive Fuctional Optimization of the Cardan Cross
2015
This paper aims to establish an optimization model using the Ansys program, and taking into account the specific constraints depending on the functional role of the specific area. We present certain calculation parameters applied to the cardanic transmission of the Dacia, this cardanic transmission being considered an optimization model. The entire cardanic transmission was analyzed, resulting that the cardan crosses are parts which are strained the most, and that is why it will be here that the optimization will be focused, in terms of minimizing the Von Mises stress.
Efficacy of spot form of net blotch suppression in barley from seed, fertiliser and foliar applied fungicides
2022
Abstract Spot form of net blotch (SFNB), caused by Pyrenophora teres f. maculata is a prevalent and damaging foliar disease of barley (Hordeum vulgare). Fungicides are commonly used to manage SFNB infection and reduce production loss in susceptible varieties. This study determined the efficacy of suppression of SFNB and associated grain yield and quality improvements from application of fungicides to seed, fertiliser and/or foliar treatments. Eight field experiments were conducted in south-eastern Australia during 2016–2018. Two experiments compared single applications of different commercially available seed, fertiliser and foliar fungicides. Six experiments evaluated different growth stag…
Self-consistent GW calculations of electronic transport in thiol- and amine-linked molecular junctions
2011
The electronic conductance of a benzene molecule connected to gold electrodes via thiol, thiolate, or amino anchoring groups is calculated using nonequilibrium Green functions in combination with the fully self-consistent GW approximation for exchange and correlation. The calculated conductance of benzenedithiol and benzenediamine is one-fifth that predicted by standard density functional theory (DFT), in very good agreement with experiments. In contrast, the widely studied benzenedithiolate structure is found to have a significantly higher conductance due to the unsaturated sulfur bonds. These findings suggest that more complex gold-thiolate structures where the thiolate anchors are chemic…
Levels of self-consistency in the GW approximation
2009
We perform $GW$ calculations on atoms and diatomic molecules at different levels of self-consistency and investigate the effects of self-consistency on total energies, ionization potentials and on particle number conservation. We further propose a partially self-consistent $GW$ scheme in which we keep the correlation part of the self-energy fixed within the self-consistency cycle. This approximation is compared to the fully self-consistent $GW$ results and to the $G W_0$ and the $G_0W_0$ approximations. Total energies, ionization potentials and two-electron removal energies obtained with our partially self-consistent $GW$ approximation are in excellent agreement with fully self-consistent $…
Paramagnetic ionic liquids as “liquid fixed-bed” catalysts in flow application
2011
Abstract The structural diversity of Ionic Liquids is well-known and widely used to generate solvents designed for special applications. Magnetic as well as catalytic properties have been described previously. To our best knowledge we report the first time about the combination of both, the magnetic and catalytic behaviour of imidazole based magnetic ionic liquids was used to establish a so-called liquid fixed-bed (LFB) in a micro-/meso-structured reactor. As proof of priciple the esterification of Ac 2 O with cyclohexanol was investigated by bubbling generated regular microdroplets of the reaction mixture through the magnetically fixed ionic liquid catalyst. With residence times of approx.…
Bisferrocenyl-functionalized pseudopeptides: access to separated ionic and electronic contributions for electrochemical anion sensing
2016
Pseudopeptidic receptors containing ferrocene fragments have been prepared and their response to a series of anions was measured by a voltammetry of microparticles methodology. Such water-insoluble compounds yield anion-assisted reversible solid-state oxidations differing in their open-circuit potential and their midpeak potential recorded in cyclic voltammetric measurements. The difference between those potentials provides the individual thermodynamic contributions of electron and proton transfer, revealing that the mechanism of an ion-sensitive electrode can differ in potentiometry and voltammetry. The studied receptors are potentially interesting for potentiometric sensing, showing relat…