Search results for "zones"

Phenoloxidases in ascidian hemocytes: characterization of the pro-phenoloxidase activating system.

2003

The phenoloxidase (PO) activity of the hemocytes lysate supernatant from three ascidians species, assayed by means of 3-methyl-2-benzothiazolinone hydrazone hydrochloride, have been compared. PO-containing hemocytes were identified by a cytochemical reaction and the enzymatic activity measured by a spectrophotometric assay of lysate supernatant from hemocyte populations separated on a discontinuous Percoll density gradient. In Styela plicata, the enzyme appeared to be contained in morula cells only. In Ciona intestinalis, PO activity was shown in univacuolar refractile granulocyte and granular hemocyte. In Phallusia mammillata both compartment cell and granular hemocytes were positive. Enzy…

Effects of levosimendan on hemodynamics, local cerebral blood flow, neuronal injury, and neuroinflammation after asphyctic cardiac arrest in rats.

2014

Despite advances in cardiac arrest treatment, high mortality and morbidity rates after successful cardiopulmonary resuscitation are still a major clinical relevant problem. The post cardiac arrest syndrome subsumes myocardial dysfunction, impaired microcirculation, systemic inflammatory response, and neurological impairment. The calcium-sensitizer levosimendan was able to improve myocardial function and initial resuscitation success after experimental cardiac arrest/cardiopulmonary resuscitation. We hypothesized that levosimendan exerts beneficial effects on cerebral blood flow, neuronal injury, neurological outcome, and inflammation 24 hours after experimental cardiac arrest/cardiopulmonar…

Elastoplastic analysis by active macro-zones with linear kinematic hardening and von Mises materials.

2014

In this paper a strategy to perform elastoplastic analysis with linear kinematic hardening for von Mises materials under plane strain conditions is shown. The proposed approach works with the Symmetric Galerkin Boundary Element Method applied to multidomain problems using a mixed variables approach, to obtain a more stringent solution. The elastoplastic analysis is carried out as the response to the loads and the plastic strains, the latter evaluated through the self-equilibrium stress matrix. This matrix is used both, in the predictor phase, for trial stress evaluation and, in the corrector phase, for solving a nonlinear global system which provides the elastoplastic solution of the active…

Milrinone is preferred to levosimendan for mesenteric perfusion in hypoxia-reoxygenated newborn piglets treated with dopamine

2012

INTRODUCTION There is little information regarding the comparative hemodynamic effects of adding milrinone or levosimendan to dopamine infusion in hypoxia-reoxygenated (H-R) newborns. RESULTS Severely hypoxic piglets had cardiogenic shock with depressed cardiac index (CI) and mean arterial pressure (MAP). The hemodynamics deteriorated gradually after initial recovery upon reoxygenation. Heart rate and CI improved with milrinone (D+M) and levosimendan (D+L) administration (P < 0.05 vs. control). Both regimens improved carotid arterial flow and carotid vascular resistance; D+M additionally improved superior mesentric arterial flow (all P < 0.05 vs. control). No effect was found on renal arter…

Seasonal wetlands in the Pacific coast of Costa Rica and Nicaragua: environmental characterisation and conservation state.

2015

Seasonal wetlands in the Pacific coast of Costa Rica and Nicaragua: environmental characterisation and conservation status On the Pacific coast of Nicaragua and Costa Rica, rainfall patterns and clay-rich soils allow the development of extensive wetlands. These environments constitute unique habitats for the maintenance of aquatic biodiversity and provide significant ecological services to the surrounding seasonal dry forest. Despite these benefits, wetlands have been severely reduced in the last four decades, and little information is available on their biology and current conservation status. Here, we describe the main limnological traits of 30 sites representing different types of wetlan…

Zonation by ammonites and foraminifers of the Vraconnian-Turonian interval: A comparison of the Boreal and Tethyan domains (NW Europe / Central Tunis…

2008

International audience; Since the end of the 19th century the interval comprising the uppermost Upper Albian, the Cenomamian, the Turonian and the basal Coniacian has been subdivided, first into ammonite zones, then, beginning in the middle of the 20th century, into zones of planktonic foraminifera. These two groups, one macrofossil, the other microfossil, are particularly effective for bio-chronostratigraphy thanks to their rapid rates of evolution. But differences in the faunal makeup between the Boreal domain (northwestern Europe) and the Tethyan domain (Mediterranean) have for a long time hindered precise correlation of the two domains. Today, in a time interval covering about 16 millio…

Self-ordering of metallogrid complexes via directed hydrogen-bonding.

2012

Reaction of imidazole aldehydes with dihydrazino derivatives of 2-phenylpyrimidine provides a family of bis(acylhydrazone) ligands which form [2 × 2] metallogrid complexes with transition metal ions including Fe(II), Co(II), Cu(II) and Zn(II). The free ligands show H-bonding interactions, both donor and acceptor, largely involving the imidazole units, while binding of the metal ions occupies all the acceptor sites and leaves only the pyrrolic-NH site as an H-bond donor, although its deprotonation by a strong base can regenerate an acceptor. These H-bonding interactions have been studied by (1)H NMR spectroscopy in solution and in the solid state by means of several crystal structure determi…

Azine-bridged octanuclear copper(II) complexes assembled with a one-stranded ditopic thiocarbohydrazone ligand.

2005

A DFT study of [3 + 2] cycloaddition reactions of an azomethine imine with N-vinyl pyrrole and N-vinyl tetrahydroindole

2016

The mechanism and selectivities of the [3+2] cycloaddition (32CA) reactions of azomethine imine (AI) 8 with two N-vinyl five-membered heterocycles (NVFH), 9a and 9b, have been theoretically studied using DFT methods at the MPWB1K/6-31G(d) computational level. The possible ortho/meta regio- and endo/exo stereoselective channels were explored and characterised. The low polar character of these 32CA reactions, which is the consequence of the high nucleophilic character of both reagents, as well as the non-effective reactivity of these NVFH as nucleophiles, accounts for the high calculated activation energies, 16.1 (9a) and 16.8 (9b) kcalmol-1 in chlorobenzene. Analysis of the relative electron…

A Molecular Electron Density Theory Study of the Reactivity of Azomethine Imine in [3+2] Cycloaddition Reactions

2017

The electronic structure and the participation of the simplest azomethine imine (AI) in [3+2] cycloaddition (32CA) reactions have been analysed within the Molecular Electron Density Theory (MEDT) using DFT calculations at the MPWB1K/6-311G(d) level. Electron localisation function (ELF) topological analysis reveals that AI has a pseudoradical structure, while the conceptual DFT reactivity indices characterise this TAC as a moderate electrophile and a good nucleophile. The non-polar 32CA reaction of AI with ethylene takes place through a one-step mechanism with low activation energy, 5.3 kcal/mol-1. A bonding evolution theory (BET) study indicates that this reaction takes place through a non-…