Search results for "öljy"

Nano-magnetic potassium impregnated ceria as catalyst for the biodiesel production

2019

Abstract The main objective of this work comprises the investigation of biodiesel production from rapeseed oil using potassium impregnated Fe3O4-CeO2 nanocatalyst. The various concentration of potassium impregnated Fe3O4-CeO2 was screened for catalytic conversion of rapeseed oil to triglyceride methyl ester. The 25 wt % potassium impregnated Fe3O4-CeO2 nanocatalyst showed best biodiesel production. Nanocatalyst was characterized by FTIR, XRD, SEM, TEM, BET and Hammett indicator for basicity test. The characterization of biodiesel was performed with GC-MS, 1H and 13C NMR. Moreover, the optimum reaction parameters such as catalyst amount (wt %), oil to methanol ratio, reaction time and reacti…

Communication strategies used by 'British Petroleum (BP)' to deal with legitimacy before and after the Deepwater Horizon Accident

2016

Oil spills pose serious threats to the legitimacy of the companies involved and the oil industry in general. The objective of this study is to conduct research on the communication strategies used by ‘British Petroleum’ (BP) to maintain its legitimacy before the Deepwater Horizon (DH) oil spill caused in April 2010 and to repair its legitimacy after the DH accident. There is existing literature on the legitimacy theory and the communication strategies as well as DH accident and its causes. A qualitative study based on the sustainability reports of BP from 2006 to 2015 and its press releases in relation to the DH accident from April 2010 to April 2016 is conducted to discover its preferred c…

Novel Functionality of Lithium-Impregnated Titania as Nanocatalyst

2019

The present work incorporates the synthesis of a multifunctional catalyst for the transesterification of waste cooking oil (WCO) to biodiesel and recovery of rare earth elements (REEs). For this purpose, TiO2 nanoparticles and TiO2 doped with lithium ions were prepared. The influence of lithium ions on the catalytic performance of TiO2 was attained by impregnation of the different molar ratios of lithium hydroxide to bare TiO2. Then each catalyst was screened for catalytic conversion of WCO to fatty acid methyl ester (FAME) and also for REEs recovery. All synthesized materials were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), Transmission electron microsc…

Assessment of the impacts of an oil spill on the populations of common guillemot (Uria aalge) and long-tailed duck (Clangula hyemalis) - an expert kn…

2012

The amount of operated oil transports continues to increase in the Gulf of Finland and in the case of an accident hazardous amounts of oil may be spilled into the sea. The oil accident may be harmful for the common guillemot and long-tailed duck populations. In this study expert knowledge regarding the behaviour and population dynamics of common guillemot and long-tailed duck in the Gulf of Finland was used to build a model to assess the impacts of an oil spill on the mortality and population size of these species. The Bayesian networks were used in the modelling. Based on the results the breeding colony of guillemots in Aspskär may survive in the consequence of recolonization. In conclusio…

Novel concepts on the recovery of by-products from alkaline pulping

2016

Innovative biorefinery concepts were developed for the separation and utilization of organic materials, especially aliphatic carboxylic acids, lignin, and extractives, which are formed as by-products during wood-based alkaline delignification processes. The partial recovery of sodium as NaOH and aliphatic carboxylic acids from hardwood soda-AQ black liquor was studied via electrodialysis. The lignin was partly (about 59 % of the initial lignin) precipitated from black liquor by carbonation (pH to about 8.5) followed by electrodialysis or H2SO4 (pH to about 2), with subsequent precipitation of more lignin and the liberation of aliphatic acids. The Na2SO4 formed was successfully separated fro…

Valorization potential of technical lignins from Norway spruce (Picea abies) via pyrolysis

2022

Analytical pyrolysis (Py-GC/MS) on mg-scale of Norway spruce (Picea abies)-derived kraft lignin, ethanosolv lignin, and dried lignin-rich soda-anthraquinone (AQ) black liquors was studied at 500 °C to compare the valorization potential of these materials, focusing on the type and yield of condensable pyrolysis products. Of particular interest was the relatively selective formation of guaiacol (2-methoxyphenol) from the dried soda-AQ black liquors in contrast to the formation of complex phenolic product mixtures from the pyrolysis of the kraft and ethanosolv lignins. It was shown that this finding could be attributed to differences in composition and structure as was assessed by various NMR …

Application of Potassium Ion Impregnated Titanium Dioxide as Nanocatalyst for Transesterification of Linseed Oil

2018

The current work comprises the investigation of biodiesel production from linseed oil using TiO2 and a potassium L-tartrate monobasic (C4H5KO6)-modified TiO2 nanocatalyst. Different amounts of C4H5KO6 were considered for TiO2 modification. The nanocatalyst TiO2–0.5C4H5KO6 (1:0.5 molar ratio) showed the best conversion rate for biodiesel production. The nanocatalyst was characterized by FTIR, XRD, TEM, BET, and XPS, and the Hammett indicator–benzenecarboxylic acid titration method was used for basicity measurement. The biodiesel was characterized by GC-MS and 1H and 13C NMR. Furthermore, the optimum reaction parameters for transesterification reaction were analyzed, and the yield was determi…

Epäterve kilpailu : käsiteanalyyttinen tutkimus ilmiöstä ja sen esiintymisestä huoltoasema-alalla vuosina 1984-2006

2007

Effect of different co-solvents on biodiesel production from various low-cost feedstocks using Sr–Al double oxides

2020

The main objective of the present paper comprises the investigation of biodiesel production from low-cost feedstock such as lard oil and waste cooking oil (WCO) using Sr-Al double oxides. Nanocatalyst was characterised FTIR, XRD, SEM, TEM, BET and XPS. The Sr:Al with 3:1 molar ratio showed the best catalytic activity in the conversion of both oils to fatty acid methyl ester. The effect of acetone and tetrahydrofuran (THF) as a co-solvent for transesterification were compared and the best result was obtained with 5 % THF. The mutual effect of the nanocatalyst and co-solvent on biodiesel production was investigated. The characterisation of biodiesel synthesised from lard oil and WCO was perfo…

Sensitivity of different early developmental periods of Baltic herring (Clupea harengus) to water-accommodated fraction of crude oil

2013

The probability for the oil accident to occur at the Gulf of Finland has been increasing last ten years and it is predicted to continue so. The risk is high based on the accident probability and the probable harm caused; some spawning areas of the Baltic herring (Clupea harengus membras) are located in the vicinity of ports and ship fairways with heavy traffic, so any oil spillage there could affect recruitment of this commercially important species. In this study, newly fertilized embryos, the older embryos and the hatched larvae of Baltic herring were exposed to water-accommodated fraction (WAF) made from crude oil. Oil exposure increased most the mortality of the hatched larvae, and larv…