0000000000004940

AUTHOR

Gabriele Giancane

0000-0001-5089-5429

showing 2 related works from this author

Supramolecular Design of Low-dimensional Carbon Nano-hybrids encoding a Polyoxometalate-bis-Pyrene Tweezer

2014

A novel bis-pyrene tweezer anchored on a rigid polyoxometalate scaffold fosters a unique interplay of hydrophobic and electrostatic supramolecular interactions, to shape carbon nanostructures (CNSs)-based extended architectures.

Materials Chemistry2506 Metals and AlloysSurfaces Coatings and FilmCarbon nanotubelaw.inventionCatalysiCoatings and Filmschemistry.chemical_compoundlawhybrid materialsMaterials ChemistryCarbon nanostructures; recognition; hybrid materials; polyoxometalatesMaterials Chemistry2506 Metals and AlloyPyrenesPyreneElectronic Optical and Magnetic MaterialChemistry (all)Metals and AlloysTungsten CompoundsSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsSurfacesSpectrophotometryPolyoxometalatePyrenerecognitionLangmuir-Schaefer filmsHybrid materialHydrophobic and Hydrophilic InteractionsCarbon nanostructuresMaterials scienceStatic ElectricitySupramolecular chemistrychemistry.chemical_elementNanotechnologyCeramics and CompositeCarbon nanotubeCatalysisNano-ElectronicpolyoxometalatesChemistry (all); Catalysis; Ceramics and Composites; Electronic Optical and Magnetic Materials; Surfaces Coatings and Films; Materials Chemistry2506 Metals and Alloys; 2506Optical and Magnetic Materialscarbon nanotubeHybrid materialPolyoxometalateGeneral ChemistryCarbon nanostructuresCarbonNanostructureschemistryCeramics and Composites2506Supramolecular chemistryCarbon
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Hierarchical Self-Assembly of Halogen-Bonded Block Copolymer Complexes into Upright Cylindrical Domains

2017

Summary Self-assembly of block copolymers into well-defined, ordered arrangements of chemically distinct domains is a reliable strategy for preparing tailored nanostructures. Microphase separation results from the system, minimizing repulsive interactions between dissimilar blocks and maximizing attractive interactions between similar blocks. Supramolecular methods have also achieved this separation by introducing small-molecule additives binding specifically to one block by noncovalent interactions. Here, we use halogen bonding as a supramolecular tool that directs the hierarchical self-assembly of low-molecular-weight perfluorinated molecules and diblock copolymers. Microphase separation …

Materials scienceBlock copolymerGeneral Chemical Engineering116 Chemical sciencesSupramolecular chemistryNanotechnologyblock copolymer02 engineering and technologyhierarchical self-assembly010402 general chemistry01 natural sciencesBiochemistryMicelleArticleSDG9: Industry innovation and infrastructuresupramolecular complexesMaterials ChemistryCopolymerEnvironmental ChemistryNon-covalent interactionsMoleculeLamellar structureta116chemistry.chemical_classificationHalogen bondta114Biochemistry (medical)General Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesblock copolymerschemistryChemical engineeringIndustry innovation and infrastructure [SDG9]nanofabricationhalogen bondSettore CHIM/07 - Fondamenti Chimici Delle TecnologieSelf-assembly0210 nano-technology
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