0000000000013007
AUTHOR
Ansis Mezulis
Thermophoretic separation of a ferrofluid–water emulsion: preliminary experiments
Abstract The Soret effect in an emulsion (microdroplets of hydrocarbon based ferrofluid in water) is evaluated from the separation measurements in vertical thermodiffusion column. The particle concentration in column ends is detected from the resonance frequency of LC oscillators with inductance coils mounted inside the column ends. The Soret coefficient S T of droplets is calculated from the initial part of dynamic separation curves. The measured value S T =−480 K −1 agrees qualitatively well with the calculated one found assuming the Maragoni-type transfer of liquid particles.
Transport properties of an ionic magnetic colloid: experimental study of increasing the ionic strength
Abstract The phase separation of an ionic magnetic colloid in zero magnetic field by increasing the ionic strength is well known [Universite Paris VI, France, 1987; J. Colloid Interface Sci. 132 (1989) 1]. The present work deals with investigation of an ionic ferrofluid by increasing the ionic strength in the range of 0–0.14 mol/l, being safely below the threshold value at which the effect of phase separation occurs. By the optical grid setup [Fourth International conference PAMIR, France, 2000], the main transport properties of a ferrofluid, i.e. translational mass diffusion and thermal diffusion (Soret) coefficients, are measured. The obtained results show a strong dependence of mass diff…
Prospects of Decarbonizing Industrial Areas in the Baltic States by Means of Alternative Fuels
This work has been supported by the National Research Programme, project “Trends, Challenges and Solutions of Latvian Gas Infrastructure Development” (LAGAS), No. VPP-EM-INFRA-2018/1-0003.
Magnetic Soret effect in a hydrocarbon based colloid containing surfacted Mn–Zn ferrite particles
Abstract The Soret effect has been investigated in a hydrocarbon based magnetic fluid containing surfacted Mn 0.5 Zn 0.5 Fe 2 O 4 nanoparticles with a magnetic volume concentration of 2.3%. The magnetic fluid fills up a vertical diffusion column which consists of a flat vertical channel between two walls and two reservoirs at the ends of the channel. One wall of the channel is being heated while the another one is cooled, maintaining a temperature gradient over the channel's width that leads to separation of particles due to the Soret effect as well as the convective flow in the channel. The combination of the two mentioned effects brings up a measurable change of the concentration of magne…
Thermoosmotic transfer of sterically stabilized ferrofluid particles in non-isothermal capillary porous layer
Experiments on thermodiffusive transfer of ferrofluid nanoparticles in capillary porous layer are presented. The layer consists of a number of capillary filter sheets pressed between two plates of different temperatures. Steady profiles of particle concentration are detected after the experiment from magnetization of each filter sheet. It is shown that particle separation in porous layer is remarkably influenced by thermoosmotic forces. The observed effect is different for colloids of various surfactants and of various carrier liquids.
Non-isothermal separation of ferrofluid particles through grids: Abnormal magnetic Soret effect
Abstract Nanoparticle transport through thin non-isothermal ferrofluid layer between permeable walls is investigated. The transient mass flux is determined from measurements of particle concentration changes in two fluid chambers of different temperatures which are attached on both sides of the layer. Experiments are performed employing fluid samples of small ordinary magnetic Soret effect, which is detected by thermal grating technique. The separation measurements say that a magnetic field, aligned along a temperature gradient, causes a remarkable increase in the mass diffusion coefficient and a simultaneous decrease in particle thermodiffusion mobility. It is proposed that the observed ef…
Analysis of the Role of the Latvian Natural Gas Network for the use of Future Energy Systems: Hydrogen from Res
The research has been funded by the Ministry of Economics of the Republic of Latvia, project “Trends, Challenges and Solutions of Latvian Gas Infrastructure Development (LAGAS)”, project No. VPP EM-INFRA-2018/1-0003.
Formation of magnetoconvection by photoabsorptive methods in ferrofluid layers
Abstract A periodic concentration grating was induced in a layer of ferrofluid by photoabsorption and thermophoresis under the action of the applied uniform magnetic field. The application of the external field causes the appearance of an internal demagnetizing field within the layer and of magnetic forces due to the non-uniform distribution of concentration. The induced magnetic forces cause the appearance of parasitic microconvection within the layer. The experimental observations of the formation stage of the grating are interpreted to explain magnetoconvection, making use of numerical simulations.
Thermodiffusion motion of electrically charged nanoparticles
AbstractThe present work deals with experimental studies to examine the theoretical model of thermodiffusion of electrically charged nanoparticles. Three different ionic magnetic colloid samples have been synthesized and profoundly analyzed. The theoretical model is a classical one, based on the calculation of the temperature and the electric potential distribution around nanoparticles. The discrepancy between experimental data and theory turns out not to exceed 20%. We focus on applying different approximations between calculated electrical double layer in the theoretical model and experimental determination of the surface charge density of colloidal particles. We assume this is the main r…
Computer Simulation to Optimize the VFA Alpha Prototype with a Hydraulic Piston Compressor and an Integrated Booster
The research has been supported by the European Regional Development Fund project "Competence Centre of Mechanical Engineering", contract No.1.2.1.1/18/A/008 signed between the Competence Centre of Mechanical Engineering and the Central Finance and Contracting Agency, Research No. 3.1 "Additional research and integra tion of the technology of hydraulic piston, aiming to develop and demonstrate economically efficient compressed natural gas smart commercial vehicle fuelling appliance". Our special gratitude to Gaspard Bouteau, PhD, Research Engineer, who conducted research in Engie Lab CRIGEN. Scientific co-authorship of the Laboratory of Materials for Energy Harvesting and Storage, ISSP UL h…
Soret coefficient of nanoparticles in ferrofluids in the presence of a magnetic field
Experiments on a nonstationary separation of nanometer-sized Mn0.5Zn0.5Fe2O particles of hydrocarbon-based ferrocolloids in a flat vertical thermal diffusion column are performed. By using a modified separation theory which accounts for a one-dimensional mixed (thermal and concentration) convection in the column, the Soret coefficient of lyophilized nanoparticles from the separation curves are calculated. It is shown that in a zero magnetic field particles are transferring toward decreasing temperatures. The thermal diffusion ratio αT reaches a value αT≈+20. A significant influence of a uniform magnetic field B on particle separation is observed. If B is oriented along the temperature gradi…
Non-isothermal mass transfer of ferrocolloids through porous membrane
Abstract The present paper deals with transport properties of ferrofluid nanoparticles in non-isothermal capillary-porous layer. Experiment establishes that the temperature difference, which is applied across the layer, induces a thermoosmotic pressure gradient directed toward increasing temperature. The measurement results are interpreted in a frame of phenomenology of linear irreversible thermodynamics. The transport coefficients are evaluated comparing the measured separation curves with approximate solution of the corresponding mass transfer problem.