6533b7ddfe1ef96bd12746d4

RESEARCH PRODUCT

Transport properties of an ionic magnetic colloid: experimental study of increasing the ionic strength

Ansis MezulisM MaiorovElmars Blums

subject

FerrofluidWork (thermodynamics)ColloidRange (particle radiation)Nuclear magnetic resonanceMaterials scienceIonic strengthThermodynamicsIonic bondingCondensed Matter PhysicsThermal diffusivityElectronic Optical and Magnetic MaterialsMagnetic field

description

Abstract The phase separation of an ionic magnetic colloid in zero magnetic field by increasing the ionic strength is well known [Universite Paris VI, France, 1987; J. Colloid Interface Sci. 132 (1989) 1]. The present work deals with investigation of an ionic ferrofluid by increasing the ionic strength in the range of 0–0.14 mol/l, being safely below the threshold value at which the effect of phase separation occurs. By the optical grid setup [Fourth International conference PAMIR, France, 2000], the main transport properties of a ferrofluid, i.e. translational mass diffusion and thermal diffusion (Soret) coefficients, are measured. The obtained results show a strong dependence of mass diffusion coefficient and no dependence of the Soret coefficient upon increasing the ionic strength. It is possible to explain both these effects theoretically; nevertheless, there is the lack of an exact theoretical model due to its complexity.

https://doi.org/10.1016/s0304-8853(02)00667-4