Influence of Host-Guest and Host-Host Interactions on the Spin-Crossover 3D Hofmann-type Clathrates {FeII(pina)[MI(CN)2]2·xMeOH (MI = Ag, Au)

[EN] The synthesis, structural characterization and magnetic properties of two new isostructural porous 3D compounds with the general formula {FeII(pina)[MI(CN)2]2}·xMeOH (x = 0¿5; pina = N-(pyridin-4-yl)isonicotinamide; MI = AgI and x ~ 5 (1·xMeOH); MI = AuI and x ~ 5 (2·xMeOH)) are presented. The single-crystal X-ray diffraction analyses have revealed that the structure of 1·xMeOH (or 2·xMeOH) presents two equivalent doubly interpenetrated 3D frameworks stabilized by both argentophilic (or aurophilic) interactions and interligand C¿O···HC H-bonds. Despite the interpenetration of the networks, these compounds display accessible void volume capable of hosting up to five molecules of methano…

Guest Effect on Nanopatterned Spin-Crossover Thin Films

International audience; Nanopatterned thin films of the metal–organic framework {Fe(bpac)[Pt(CN)4]} (bpac=bis(4‐pyridyl)acetylene) are elaborated by the combination of a sequential assembly process and a lithographic method. Raman microspectroscopy is used to probe the temperature dependence of the spin state of the iron(II) ions in the films (40–90 nm in thickness), and reveals an incomplete but cooperative spin transition comparable to that of the bulk material. Adsorption/desorption of pyridine guest molecules is found to have a substantial influence on the spin‐crossover properties of the thin layers. This interplay between host–guest and spin‐crossover properties in thin films and nano…

Chiral and Racemic Spin Crossover Polymorphs in a Family of Mononuclear Iron(II) Compounds

[EN] Understanding the origin of cooperativity and the equilibrium temperature of transition (T1/2) displayed by the spin-crossover (SCO) compounds as well as controlling these parameters are of paramount importance for future applications. For this task, the occurrence of polymorphism, presented by a number of SCO complexes, may provide deep insight into the influence of the supramolecular organization on the SCO behavior. In this context, herein we present a novel family of mononuclear octahedral FeII complexes with formula cis- [Fe(bqen)(NCX)2], where bqen is the chelating tetradentate ligand N,N¿-bis(8-quinolyl)ethane-1,2-diamine and X = S, Se. Depending on the preparation method, these…

Enhanced Interplay between Host–Guest and Spin-Crossover Properties through the Introduction of an N Heteroatom in 2D Hofmann Clathrates

Controlled modulation of the spin-crossover (SCO) behavior through the sorption-desorption of invited molecules is an extensively exploited topic because of its potential applications in molecular sensing. For this purpose, understanding the mechanisms by which the spin-switching properties are altered by guest molecules is of paramount importance. Here, we show an experimental approach revealing a direct probe of how the interplay between SCO and host-guest chemistry is noticeably activated by chemically tuning the host structure. Thus, the axial ligand 4-phenylpyridine (4-PhPy) in the 2D Hofmann clathrates {Fe(4-PhPy)2[M(CN)4]} (PhPyM; M = Pt, Pd) is replaced by 2,4-bipyridine (2,4-Bipy),…

Enhanced porosity in a new 3D Hofmann-like network exhibiting humidity sensitive cooperative spin transitions at room temperature

The porous coordination polymers (PCPs) of general formula {Fe(bpac)[M(CN)4]}·guest (M = Pt, Pd) exhibit larger channels than previously synthesised 3D-Hofmann-like PCP. The channels are partially occupied by uncoordinated guest bpac ligands and labile H2O molecules. These PCPs exhibit very scarce cooperative spin crossover behaviour around room temperature with a large hysteresis loop (up to 49 K) and also display sensitivity to humidity and guest molecules. The inclusion of bpac molecules in the 3D network can be avoided by adding competitive volatile molecules during the crystallization process, affording the guest-free material. The spin crossover behavior of different guest and guest-f…

High quality nano-patterned thin films of the coordination compound {Fe(pyrazine)[Pt(CN)4]} deposited layer-by-layer

International audience; An optimised procedure was developed for the layer-by-layer deposition of the Hofmann clathrate-like coordination compound {Fe(pyrazine)[Pt(CN)4]} either as continuous or as nano-patterned thin films. Characterization of the thickness and topography of the thin films by atomic force microscopy (AFM) and by surface plasmon resonance (SPR) spectroscopy, which also yields the layer's refractive index and losses, are reported. We found that the films are of good optical quality and the results of both AFM and SPR experiments are in good agreement with the theoretical predictions of the films thicknesses.

Reversible guest-induced gate-opening with multiplex spin crossover responses in two-dimensional Hofmann clathrates.

Spin crossover (SCO) compounds are very attractive types of switchable materials due to their potential applications in memory devices, actuators or chemical sensors. Rational chemical tailoring of these switchable compounds is key for achieving new functionalities in synergy with the spin state change. However, the lack of precise structural information required to understand the chemical principles that control the SCO response with external stimuli may eventually hinder further development of spin switching-based applications. In this work, the functionalization with an amine group in the two-dimensional (2D) SCO compound {Fe(5-NH2Pym)2[MII(CN)4]} (1M, 5-NH2Pym = 5-aminopyrimidine, MII =…

Correction: Effect of nanostructuration on the spin crossover transition in crystalline ultrathin films

Correction for ‘Effect of nanostructuration on the spin crossover transition in crystalline ultrathin films’ by Víctor Rubio-Giménez et al., Chem. Sci., 2019, DOI: 10.1039/c8sc04935a.

Bistable Hofmann-Type FeII Spin-Crossover Two-Dimensional Polymers of 4-Alkyldisulfanylpyridine for Prospective Grafting of Monolayers on Metallic Surfaces

Aiming at investigating the suitability of Hofmann-type two-dimensional (2D) coordination polymers {FeII(Lax)2[MII(CN)4]} to be processed as single monolayers and probed as spin crossover (SCO) junctions in spintronic devices, the synthesis and characterization of the MII derivatives (MII = Pd and Pt) with sulfur-rich axial ligands (Lax = 4-methyl- and 4-ethyl-disulfanylpyridine) have been conducted. The thermal dependence of the magnetic and calorimetric properties confirmed the occurrence of strong cooperative SCO behavior in the temperature interval of 100-225 K, featuring hysteresis loops 44 and 32.5 K/21 K wide for PtII-methyl and PtII/PdII-ethyl derivatives, while the PdII-methyl deri…

Discrimination between two memory channels by molecular alloying in a doubly bistable spin crossover material

[EN] A multistable spin crossover (SCO) molecular alloy system [Fe1-xMx(nBu-im)(3)(tren)](P1-yAsyF6)(2) (M = Zn-II, Ni-II; (nBu-im)(3)(tren) = tris(n-butyl-imidazol(2-ethylamino))amine) has been synthesized and characterized. By controlling the composition of this isomorphous series, two cooperative thermally induced SCO events featuring distinct critical temperatures (T-c) and hysteresis widths (Delta T-c, memory) can be selected at will. The pristine derivative 100As (x = 0, y = 1) displays a strong cooperative two-step SCO and two reversible structural phase transitions (PTs). The low temperature PTLT and the SCO occur synchronously involving conformational changes of the ligand's n-buty…

Extrinsicvs.intrinsic luminescence and their interplay with spin crossover in 3D Hofmann-type coordination polymers

The research of new multifunctional materials, as those undergoing spin crossover (SCO) and luminescent properties, is extremely important in the development of further optical and electronic switching devices. As a new step towards this ambitious aim, the coupling of SCO and fluorescence is presented here following two main strategies: whether the fluorescent agent is integrated as a part of the main structure of a 3D SCO coordination polymer {FeII(bpan)[MI(CN)2]2} (bpan = bis(4-pyridyl)anthracene, MI = Ag (FebpanAg), Au (FebpanAu)) or is a guest molecule inserted within the cavities of the 3D switchable framework {FeII(bpb)[MI(CN)2]2}·pyrene (bpb = bis(4-pyridyl)butadiyne, MI = Ag (FebpbA…

Thermo- and photo-modulation of exciplex fluorescence in a 3D spin crossover Hofmann-type coordination polymer

[EN] The search for bifunctional materials showing synergies between spin crossover (SCO) and luminescence has attracted substantial interest since they could be promising platforms for new switching electronic and optical technologies. In this context, we present the first three-dimensional Fe-II Hofmann-type coordination polymer exhibiting SCO properties and luminescence. The complex {Fe-II(bpben)[Au(CN)(2)]}@pyr (bpben = 1,4-bis(4-pyridyl)benzene) functionalized with pyrene (pyr) guests undergoes a cooperative multi-step SCO, which has been investigated by single crystal X-ray diffraction, single crystal UV-Vis absorption spectroscopy, and magnetic and calorimetric measurements. The resu…

Heteroleptic Iron(II) Spin-Crossover Complexes Based on a 2,6-Bis(pyrazol-1-yl)pyridine-type Ligand Functionalized with a Carboxylic Acid

Two new heteroleptic complexes [Fe- (1bppCOOH)(3bpp-bph)](ClO4)2·solv (1·solv, solv = various solvents; 1bppCOOH = 2,6-bis(1H-pyrazol-1-yl)- isonicotinic acid; 3bpp-bph = 2,6-bis(5-([1,1′-biphenyl]-4- yl)-1H-pyrazol-3-yl)pyridine) and [Fe(1bppCOOH)- (1bppCOOEt)](ClO4)2 ·0.5Me2CO (2·0.5Me2CO, 1bppCOOEt = ethyl 2,6-bis(1H-pyrazol-1-yl)isonicotinate) were designed and prepared. The heteroleptic compound 1· solv was obtained by the combination of stoichiometric amounts of Fe(ClO4)2, 1bppCOOH, and 3bpp-bph, and it was designed to fine-tune the spin crossover (SCO) properties with respect to the previously reported homoleptic compound [Fe(1bppCOOH)2](ClO4)2. Indeed, the introduction of a new subs…

Tunable Spin-Crossover Behavior of the Hofmann-like Network {Fe(bpac)[Pt(CN) 4 ]} through Host-Guest Chemistry

A study of the spin-crossover (SCO) behavior of the tridimensional porous coordination polymer {Fe(bpac)[Pt(CN)4]} (bpac=bis(4-pyridyl) acetylene) on adsorption of different mono- and polyhalobenzene guest molecules is presented. The resolution of the crystal structure of {Fe(bpac)[Pt(CN) 4]}A?G (G=1,2,4-trichlorobenzene) shows preferential guest sites establishing I?A?A?A?I? stacking interactions with the host framework. These host-guest interactions may explain the relationship between the modification of the SCO behavior and both the chemical nature of the guest molecule (electronic factors) and the number of adsorbed molecules (steric factors). Copyright © 2013 WILEY-VCH Verlag GmbH & …

Effect of nanostructuration on the spin crossover transition in crystalline ultrathin films† †Electronic supplementary information (ESI) available: Materials and methods, supplementary figures and tables. See DOI: 10.1039/c8sc04935a

Film thickness and microstructure critically affect the spin crossover transition of a 2D coordination polymer.

Epitaxial Thin-Film vs Single Crystal Growth of 2D Hofmann-Type Iron(II) Materials: A Comparative Assessment of their Bi-Stable Spin Crossover Properties

Integration of the ON-OFF cooperative spin crossover (SCO) properties of FeII coordination polymers as components of electronic and/or spintronic devices is currently an area of great interest for potential applications. This requires the selection and growth of thin films of the appropriate material onto selected substrates. In this context, two new series of cooperative SCO two-dimensional FeII coordination polymers of the Hofmann-type formulated {FeII(Pym)2[MII(CN)4]·xH2O}n and {FeII(Isoq)2[MII(CN)4]}n (Pym = pyrimidine, Isoq = isoquinoline; MII = Ni, Pd, Pt) have been synthesized, characterized, and the corresponding Pt derivatives selected for fabrication of thin films by liquid-phase …

Ultrathin Films of 2D Hofmann-Type Coordination Polymers: Influence of Pillaring Linkers on Structural Flexibility and Vertical Charge Transport

Searching for novel materials and controlling their nanostructuration into electronic devices is a challenging task ahead of chemists and chemical engineers. Even more so when this new application requires an exquisite control over the morphology, crystallinity, roughness and orientation of the films produced. In this context, it is of critical importance to analyze the influence of the chemical composition of perspective materials on their properties at the nanoscale. We report the fabrication of ultrathin films (thickness < 30 nm) of a family of FeII Hofmann-like coordination polymers by using an optimized liquid phase epitaxy (LPE) set-up. The series [Fe(L)2{Pt(CN)4}] (L = pyridine, pyri…

Switchable Spin-Crossover Hofmann-Type 3D Coordination Polymers Based on Tri- and Tetratopic Ligands

[EN] Fe-II spin-crossover (SCO) coordination polymers of the Hofmann type have become an archetypal class of responsive materials. Almost invariably, the construction of their architectures has been based on the use of monotopic and linear ditopic pyridine like ligands. In the search for new Hofmann-type architectures with SCO properties, here we analyze the possibilities of bridging ligands with higher connectivity degree. More precisely, the synthesis and structure of {Fe-II(L-N3)[M-I(CN)(2)](2)}center dot(Guest) (Guest = nitro-benzene, benzonitrile, o-dichlorobenzene; M-I = Ag, Au) and {Fe-II(L-N4)[Ag-2(CN)(3)][Ag(CN)(2)]}center dot H2O are described, where L-N3 and L-N4 are the tritopic…

Synergetic effect of host-guest chemistry and spin crossover in 3D Hofmann-like metal-organic frameworks [Fe(bpac)M(CN)4] (M=Pt, Pd, Ni).

The synthesis and characterization of a series of three-dimensional (3D) Hofmann-like clathrate porous metal-organic framework (MOF) materials [Fe(bpac)M(CN) 4] (M=Pt, Pd, and Ni; bpac=bis(4-pyridyl)acetylene) that exhibit spin-crossover behavior is reported. The rigid bpac ligand is longer than the previously used azopyridine and pyrazine and has been selected with the aim to improve both the spin-crossover properties and the porosity of the corresponding porous coordination polymers (PCPs). The 3D network is composed of successive {Fe[M(CN) 4]} n planar layers bridged by the bis-monodentate bpac ligand linked in the apical positions of the iron center. The large void between the layers, w…

Cover Feature: Cyanido‐Bridged Fe II –M I Dimetallic Hofmann‐Like Spin‐Crossover Coordination Polymers Based on 2,6‐Naphthyridine (Eur. J. Inorg. Chem. 3‐4/2018)

Thermal and pressure-induced spin crossover in a novel three-dimensional Hoffman-like clathrate complex

The synthesis and crystal structure of the interpenetrated metal–organic framework material Fe(bpac)2[Ag(CN)2]2 (bpac = 4,4′-bis(pyridyl)acetylene) are reported along with the characterization of its spin crossover properties by variable temperature magnetometry and Mossbauer spectroscopy. The complex presents an incomplete stepped spin transition as a function of temperature that is modified upon successive thermal cycling. The pressure-induced transition has also been investigated by means of high pressure Raman spectroscopy using a diamond anvil cell. The results show that it is possible to reach the thermally-inaccessible fully low spin state at room temperature by applying hydrostatic …

Cyanido-Bridged FeII-MI Dimetallic Hofmann-Like Spin-Crossover Coordination Polymers Based on 2,6-Naphthyridine

[EN] Two new 3D spin-crossover (SCO) Hofmann-type coordination polymers {Fe(2,6-naphthy)[Ag(CN)2][Ag2(CN)3]} (1; 2,6-naphthy = 2,6-naphthyridine) and {Fe(2,6-naphthy)- [Au(CN)2]2}·0.5PhNO2 (2) were synthesized and characterized. Both derivatives are made up of infinite stacks of {Fe[Ag(CN)2]2- [Ag2(CN)3]}n and {Fe[Au(CN)2]2}n layered grids connected by pillars of 2,6-naphthy ligands coordinated to the axial positions of the FeII centers of alternate layers.

{[Hg(SCN)3]2(n-L)}2-: An Efficient Secondary Building Unit for the Synthesis of 2D Iron(II) Spin-Crossover Coordination Polymers

[EN] We report an unprecedented series of two-dimensional (2D) spin-crossover (SCO) heterobimetallic coordination polymers generically formulated as {Fe-II[(He(SCN)(3))(2)](L)(x))}center dot Solv, where x = 2 for L = tvp (trans-(4,4'-vinylenedipyridine)) (1tvp), bpmh ((1E,2E)-1,2-bis(pyridin-4-ylmethylene)hydrazine) (1bpmh center dot nCH(3)OH; n = 0, 1), by eh ( (1E,2E)-1,2-bis (1-(pyridin-4-yl) ethyliden e) hydrazine) (Ibpeh center dot nH(2)O; n = 0, 1) and x = 2.33 for L = 0 0 bpbz (1,4-bis(pyridin-4-yl)benzene) (1bpbz center dot nH(2)O; n = 0, 2/ 3). The results confirm that self-assembly of Fell, [Hg-II(SCN)(4)](2-), and ditopic rodlike bridging ligands L containing 4-pyridyl moieties f…

CCDC 2018380: Experimental Crystal Structure Determination

Related Article: Rubén Turo-Cortés, Carlos Bartual-Murgui, Javier Castells-Gil, M. Carmen Muñoz, Carlos Martí-Gastaldo, José Antonio Real|2020|Chemical Science|11|11224|doi:10.1039/D0SC04246C

CCDC 1965274: Experimental Crystal Structure Determination

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CCDC 2018391: Experimental Crystal Structure Determination

Related Article: Rubén Turo-Cortés, Carlos Bartual-Murgui, Javier Castells-Gil, M. Carmen Muñoz, Carlos Martí-Gastaldo, José Antonio Real|2020|Chemical Science|11|11224|doi:10.1039/D0SC04246C

CCDC 1852557: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, M. Carmen Muñoz, Sacramento Ferrer, Carlos Bartual-Murgui, José A. Real|2018|Inorg.Chem.|57|12195|doi:10.1021/acs.inorgchem.8b01842

CCDC 1572177: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1572180: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1879899: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

CCDC 1879896: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

CCDC 1572183: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 2072901: Experimental Crystal Structure Determination

Related Article: Rubén Turo-Cortés, Francisco Javier Valverde-Muñoz, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José Antonio Real|2021|Inorg.Chem.|60|9040|doi:10.1021/acs.inorgchem.1c01010

CCDC 1572184: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1910592: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2019|Inorg.Chem.|58|10038|doi:10.1021/acs.inorgchem.9b01189

CCDC 2018392: Experimental Crystal Structure Determination

Related Article: Rubén Turo-Cortés, Carlos Bartual-Murgui, Javier Castells-Gil, M. Carmen Muñoz, Carlos Martí-Gastaldo, José Antonio Real|2020|Chemical Science|11|11224|doi:10.1039/D0SC04246C

CCDC 1565402: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco Javier-Valverde-Muñoz, Maksym Seredyuk, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Eur.J.Inorg.Chem.||289|doi:10.1002/ejic.201700920

CCDC 1879901: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

CCDC 1572181: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1989161: Experimental Crystal Structure Determination

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CCDC 1989160: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

CCDC 1989157: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

CCDC 1917753: Experimental Crystal Structure Determination

Related Article: Víctor García-López, Mario Palacios-Corella, Verónica Gironés-Pérez, Carlos Bartual-Murgui, José Antonio Real, Eric Pellegrin, Javier Herrero-Martín, Guillem Aromí, Miguel Clemente-León, Eugenio Coronado|2019|Inorg.Chem.|58|12199|doi:10.1021/acs.inorgchem.9b01526

CCDC 1847351: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Manuel Meneses-Sánchez, Lucía Piñeiro-López, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Chemical Science|9|8446|doi:10.1039/C8SC02677G

CCDC 2072905: Experimental Crystal Structure Determination

Related Article: Rubén Turo-Cortés, Francisco Javier Valverde-Muñoz, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José Antonio Real|2021|Inorg.Chem.|60|9040|doi:10.1021/acs.inorgchem.1c01010

CCDC 1910990: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

CCDC 2072902: Experimental Crystal Structure Determination

Related Article: Rubén Turo-Cortés, Francisco Javier Valverde-Muñoz, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José Antonio Real|2021|Inorg.Chem.|60|9040|doi:10.1021/acs.inorgchem.1c01010

CCDC 1879898: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

CCDC 2072900: Experimental Crystal Structure Determination

Related Article: Rubén Turo-Cortés, Francisco Javier Valverde-Muñoz, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José Antonio Real|2021|Inorg.Chem.|60|9040|doi:10.1021/acs.inorgchem.1c01010

CCDC 2072903: Experimental Crystal Structure Determination

Related Article: Rubén Turo-Cortés, Francisco Javier Valverde-Muñoz, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José Antonio Real|2021|Inorg.Chem.|60|9040|doi:10.1021/acs.inorgchem.1c01010

CCDC 1852556: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, M. Carmen Muñoz, Sacramento Ferrer, Carlos Bartual-Murgui, José A. Real|2018|Inorg.Chem.|57|12195|doi:10.1021/acs.inorgchem.8b01842

CCDC 1910594: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2019|Inorg.Chem.|58|10038|doi:10.1021/acs.inorgchem.9b01189

CCDC 2018389: Experimental Crystal Structure Determination

Related Article: Rubén Turo-Cortés, Carlos Bartual-Murgui, Javier Castells-Gil, M. Carmen Muñoz, Carlos Martí-Gastaldo, José Antonio Real|2020|Chemical Science|11|11224|doi:10.1039/D0SC04246C

CCDC 1847352: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Manuel Meneses-Sánchez, Lucía Piñeiro-López, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Chemical Science|9|8446|doi:10.1039/C8SC02677G

CCDC 1572182: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1989159: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

CCDC 1585097: Experimental Crystal Structure Determination

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CCDC 2018381: Experimental Crystal Structure Determination

Related Article: Rubén Turo-Cortés, Carlos Bartual-Murgui, Javier Castells-Gil, M. Carmen Muñoz, Carlos Martí-Gastaldo, José Antonio Real|2020|Chemical Science|11|11224|doi:10.1039/D0SC04246C

CCDC 1910992: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

CCDC 1910593: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2019|Inorg.Chem.|58|10038|doi:10.1021/acs.inorgchem.9b01189

CCDC 2090594: Experimental Crystal Structure Determination

Related Article: Manuel Meneses-Sánchez, Rubén Turo-Cortés, Carlos Bartual-Murgui, Iván da Silva, M. Carmen Muñoz, José Antonio Real|2021|Inorg.Chem.|60|11866|doi:10.1021/acs.inorgchem.1c01925

CCDC 1852560: Experimental Crystal Structure Determination

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CCDC 1879900: Experimental Crystal Structure Determination

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CCDC 1565404: Experimental Crystal Structure Determination

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CCDC 1965275: Experimental Crystal Structure Determination

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CCDC 1585098: Experimental Crystal Structure Determination

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CCDC 2090601: Experimental Crystal Structure Determination

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CCDC 2018390: Experimental Crystal Structure Determination

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CCDC 1910991: Experimental Crystal Structure Determination

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CCDC 1917752: Experimental Crystal Structure Determination

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CCDC 2018379: Experimental Crystal Structure Determination

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CCDC 1965272: Experimental Crystal Structure Determination

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CCDC 2090600: Experimental Crystal Structure Determination

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CCDC 1852559: Experimental Crystal Structure Determination

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CCDC 1965273: Experimental Crystal Structure Determination

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CCDC 1892385: Experimental Crystal Structure Determination

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CCDC 1565403: Experimental Crystal Structure Determination

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CCDC 2072904: Experimental Crystal Structure Determination

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CCDC 2018384: Experimental Crystal Structure Determination

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CCDC 2072898: Experimental Crystal Structure Determination

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CCDC 2072899: Experimental Crystal Structure Determination

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CCDC 2018386: Experimental Crystal Structure Determination

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CCDC 1585096: Experimental Crystal Structure Determination

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CCDC 1910989: Experimental Crystal Structure Determination

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CCDC 2018388: Experimental Crystal Structure Determination

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CCDC 1585094: Experimental Crystal Structure Determination

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CCDC 1910591: Experimental Crystal Structure Determination

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CCDC 1585095: Experimental Crystal Structure Determination

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CCDC 1965271: Experimental Crystal Structure Determination

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CCDC 1852562: Experimental Crystal Structure Determination

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CCDC 1989162: Experimental Crystal Structure Determination

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CCDC 1965270: Experimental Crystal Structure Determination

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CCDC 1862017: Experimental Crystal Structure Determination

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CCDC 1572179: Experimental Crystal Structure Determination

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CCDC 2090596: Experimental Crystal Structure Determination

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CCDC 1572178: Experimental Crystal Structure Determination

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CCDC 2090597: Experimental Crystal Structure Determination

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CCDC 1989158: Experimental Crystal Structure Determination

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CCDC 2090599: Experimental Crystal Structure Determination

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CCDC 2018382: Experimental Crystal Structure Determination

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CCDC 2018383: Experimental Crystal Structure Determination

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CCDC 2018387: Experimental Crystal Structure Determination

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CCDC 1852558: Experimental Crystal Structure Determination

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CCDC 1585093: Experimental Crystal Structure Determination

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CCDC 1917754: Experimental Crystal Structure Determination

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CCDC 1847353: Experimental Crystal Structure Determination

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CCDC 2090598: Experimental Crystal Structure Determination

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CCDC 2018385: Experimental Crystal Structure Determination

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CCDC 1879897: Experimental Crystal Structure Determination

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CCDC 920626: Experimental Crystal Structure Determination

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CCDC 1917750: Experimental Crystal Structure Determination

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CCDC 2090595: Experimental Crystal Structure Determination

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CCDC 2018393: Experimental Crystal Structure Determination

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CCDC 1917751: Experimental Crystal Structure Determination

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CCDC 2018378: Experimental Crystal Structure Determination

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CCDC 1852561: Experimental Crystal Structure Determination

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