6533b860fe1ef96bd12c2fcc

RESEARCH PRODUCT

Cyanido-Bridged FeII-MI Dimetallic Hofmann-Like Spin-Crossover Coordination Polymers Based on 2,6-Naphthyridine

Maksym SeredukMaksym SeredyukFrancisco Javier Valverde-muñozCarlos Bartual-murguiJosé Antonio RealM. Carmen MuñozLucía Piñeiro-lópez

subject

Void (astronomy)SilverStereochemistryIron02 engineering and technology010402 general chemistry01 natural sciencesInorganic ChemistryNitrobenzenechemistry.chemical_compoundN ligandsSpin crossoverMoleculechemistry.chemical_classificationPolymerMetal-organic frameworks021001 nanoscience & nanotechnologySpin crossover0104 chemical sciencesCrystallographychemistryFISICA APLICADAMetal-organic frameworkGold0210 nano-technology

description

[EN] Two new 3D spin-crossover (SCO) Hofmann-type coordination polymers {Fe(2,6-naphthy)[Ag(CN)2][Ag2(CN)3]} (1; 2,6-naphthy = 2,6-naphthyridine) and {Fe(2,6-naphthy)- [Au(CN)2]2}·0.5PhNO2 (2) were synthesized and characterized. Both derivatives are made up of infinite stacks of {Fe[Ag(CN)2]2- [Ag2(CN)3]}n and {Fe[Au(CN)2]2}n layered grids connected by pillars of 2,6-naphthy ligands coordinated to the axial positions of the FeII centers of alternate layers.

yearjournalcountryeditionlanguage
2017-10-11
10.1002/ejic.201700920https://hdl.handle.net/10251/138958