6533b7ddfe1ef96bd1273e43

RESEARCH PRODUCT

High quality nano-patterned thin films of the coordination compound {Fe(pyrazine)[Pt(CN)4]} deposited layer-by-layer

Christophe ThibaultJosé Antonio RealCarlos Bartual-murguiAzzedine BousseksouZouheir SekkatGábor MolnárTarik MahfoudLionel SalmonAmal Akou

subject

Pyrazine010405 organic chemistryChemistryLayer by layerAnalytical chemistryGeneral Chemistry010402 general chemistry01 natural sciencesCatalysis0104 chemical scienceschemistry.chemical_compoundNano-Materials ChemistryThin filmSurface plasmon resonance[SPI.NANO]Engineering Sciences [physics]/Micro and nanotechnologies/MicroelectronicsSpectroscopyRefractive indexLayer (electronics)

description

International audience; An optimised procedure was developed for the layer-by-layer deposition of the Hofmann clathrate-like coordination compound {Fe(pyrazine)[Pt(CN)4]} either as continuous or as nano-patterned thin films. Characterization of the thickness and topography of the thin films by atomic force microscopy (AFM) and by surface plasmon resonance (SPR) spectroscopy, which also yields the layer's refractive index and losses, are reported. We found that the films are of good optical quality and the results of both AFM and SPR experiments are in good agreement with the theoretical predictions of the films thicknesses.

10.1039/c1nj20212jhttps://hal.laas.fr/hal-01767588