0000000000023348

AUTHOR

Lukas P.v. Kaluza

showing 2 related works from this author

ChemInform Abstract: A Short Synthesis of Pyridines from Deprotonated α-Aminonitriles by an Alkylation/RCM Sequence.

2016

DeprotonationStereochemistryChemistrySalt metathesis reactionGeneral MedicineAlkylationSequence (medicine)ChemInform
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A short synthesis of pyridines from deprotonated α-aminonitriles by an alkylation/RCM sequence

2016

Abstract α-Aminonitriles can serve as versatile key precursors for the synthesis of nitrogen containing heterocycles. After unsuccessful trials involving the [1,2]-Stevens rearrangement of nitrile-stabilized ammonium ylides, we herein report a simple three-step synthesis of substituted pyridines based on an alkylation/ring-closing metathesis/aromatization sequence.

DeprotonationStevens rearrangementOlefin metathesis010405 organic chemistryChemistryStereochemistryGeneral ChemistryAlkylation010402 general chemistry01 natural sciences0104 chemical sciencesSequence (medicine)Zeitschrift für Naturforschung B
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