0000000000103341
AUTHOR
Mikko Heikkilä
showing 8 related works from this author
Intensified job demands, stress of conscience and nurses' experiences during organizational change
2022
Background:Nurses frequently face ethically demanding situations in their work, and these may lead to stress of conscience. Working life is currently accelerating and job demands are intensifying. These intensified job demands include (1) work intensification, (2) intensified job-related planning demands, (3) intensified career-related planning demands, and (4) intensified learning demands. At the same time, many healthcare organizations are implementing major organizational changes that have an influence on personnel.Aim:The aim of the study was to investigate the association between intensified job demands and stress of conscience, and whether their association is moderated by organizatio…
Ethical dilemmas and well-being in teachers’ work : A three-wave, two-year longitudinal study
2023
The aim of the present longitudinal study was two-fold: First, to explore what kinds of ethical dilemma groups can be identified among Finnish teachers (n = 310) and second, to examine how these groups differ from each other with respect to occupational well-being and recovery from job strain over the two-year follow-up. Using Latent Profile Analysis, three ethical dilemma prevalence groups were identified: rare (27%), occasional (51%), and frequent dilemmas (22%). Teachers in frequent dilemmas group reported highest burnout, however, their recovery from job strain improved and their burnout (exhaustion) diminished over time. To reduce teachers’ ethical dilemmas different approaches are pro…
Evaluation and Comparison of Novel Precursors for Atomic Layer Deposition of Nb2O5 Thin Films
2012
Atomic layer deposition (ALD) of Nb2O5 thin films was studied using three novel precursors, namely, tBuN═Nb(NEt2)3, tBuN═Nb(NMeEt)3, and tamylN═Nb(OtBu)3. These precursors are liquid at room temperature, present good volatility, and are reactive toward both water and ozone as the oxygen sources. The deposition temperature was varied from 150 to 375 °C. ALD-type saturative growth modes were confirmed at 275 °C for tBuN═Nb(NEt2)3 and tBuN═Nb(NMeEt)3 together with both oxygen sources. Constant growth rate was observed between a temperature regions of 150 and 325 °C. By contrast, amylN═Nb(OtBu)3 exhibited limited thermal stability and thus a saturative growth mode was not achieved. All films we…
Suppression of Forward Electron Injection from Ru(dcbpy)2(NCS)2 to Nanocrystalline TiO2 Film As a Result of an Interfacial Al2O3 Barrier Layer Prepar…
2009
Subnanometer-thick Al2O3 barrier layers on nanocrystalline TiO2 film were prepared with atomic layer deposition (ALD). The method allowed variation of barrier thicknesses at atomic resolution also deep in nanoporous structures, which makes it a superior method as compared to, e.g., sol−gel techniques. In this letter we present results on the effect of Al2O3 barriers of various thicknesses on forward electron injection in dye-sensitized solar cells. A decrease in the amplitude of the oxidized Ru(dcbpy)2(NCS)2 dye absorption signal due to singlet injection was observed already after one deposition cycle that produces a discontinuous layer with nominal thickness of 1 A. More than two layer coa…
Studies on atomic layer deposition of IRMOF-8 thin films
2015
Deposition of IRMOF-8 thin films by atomic layer deposition was studied at 260–320 C. Zinc acetate and 2,6-naphthalenedicarboxylic acid were used as the precursors. The as-deposited amorphous films were crystallized in 70% relative humidity at room temperature resulting in an unknown phase with a large unit cell. An autoclave with dimethylformamide as the solvent was used to recrystallize the films into IRMOF-8 as confirmed by grazing incidence x-ray diffraction. The films were further characterized by high temperature x-ray diffraction (HTXRD), field emission scanning electron microscopy, Fourier transform infrared spectroscopy (FTIR), time-of-flight elastic recoil detection analysis (TOF-…
Mechanical properties of aluminum, zirconium, hafnium and tantalum oxides and their nanolaminates grown by atomic layer deposition
2015
ABSTRACT The mechanical properties of two different metal oxide nanolaminates comprised of Ta 2 O 5 and Al 2 O 3 , HfO 2 or ZrO 2 , grown on soda–lime glass substrate by atomic layer deposition, were investigated. Ta 2 O 5 and Al 2 O 3 layers were amorphous, whereas ZrO 2 and HfO 2 possessed crystalline structure. Thickness of single oxide layers was varied between 2.5 and 15 nm. The total thickness of the laminate structures was in the range of 160–170 nm. The hardness values of single layer oxides on glass ranged from 6.7 GPa (Ta 2 O 5 ) to 9.5 GPa (Al 2 O 3 ). Corresponding elastic moduli were 96 GPa and 101 GPa. The hardnesses of laminates were in the range of 6.8–7.8 GPa and elastic mo…
Studies on atomic layer deposition of MOF-5 thin films
2013
International audience; Deposition of MOF-5 thin films from vapor phase by atomic layer deposition (ALD) was studied at 225-350 degrees C. Zinc acetate (ZnAc2) and 1,4-benzenedicarboxylic acid (1,4-BDC) were used as the precursors. The resulting films were characterized by UV-Vis spectrophotometry, Fourier transform infrared spectroscopy (FTIR), optical microscopy, X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), time-of-flight elastic recoil detection analysis (TOF-ERDA), isopropanol adsorption tests, and nanoindentation. It was found out that the as-deposited films were amorphous but crystallized in humid conditions at room temperature. The crystalline films h…
Maataloustuotemarkkinoiden sijoittajakäyttäytymisen muutoksen vaikutus USA:n maataloustuote- ja osakemarkkinoiden korreloituneisuuteen
2017
Tässä tutkimuksessa perehdytään siihen, kuinka maataloustuotemarkkinoiden sijoittajakäyttäytymisen muutos vaikuttaa osake- ja maataloustuotemarkkinoiden väliseen korrelaatioon. Tutkittava aineisto koostuu maissin, vehnän, soijapavun, sokerin ja kaakaon päivittäisistä futuurihinnoista vuosilta 1973–2016. Tutkimuksessa osakemarkkinoita kuvaa S&P 500 -indeksi ja raaka-ainemarkkinoita S&P GSCI -indeksi. Aluksi arvioidaan muuttujien keskinäisiä riippuvuussuhteita VAR-mallin avulla. Tämän jälkeen estimoidaan osake- ja maataloustuotemarkkinoiden volatiliteetit ja korrelaatiot DCC-GARCH -mallin avulla sekä arvioidaan muuttujien volatiliteettien ja korrelaatioiden muutosta kahden otoksen t-testin av…