Deep sub-threshold $K^\ast (892)^{\circ}$ production in collisions of Ar + KCl at 1.76 A GeV

Coherent Electronic Coupling versus Localization in Individual Molecular Dimers

International audience; The electronic excitation transfer and coherent electronic coupling strength were investigated in molecular dimers by spectrally resolved confocal fluorescence spectroscopy. The direct probe of electronic coupling strength distribution was possible due to static disorder in polymer host by single molecule measurements. The dimers with delocalized excitation were also found in comparison to emission originated from localized states. The delocalized and localized state transitions were observed for dimers which were attributed to structural fluctuations of guest-host system.

pp and ππ intensity interferometry in collisions of Ar+KCl at 1.76A GeV

Results on pp, π+π+, and π-π- intensity interferometry are reported for collisions of Ar+KCl at 1.76$A$~GeV beam energy, studied with the High Acceptance Di-Electron Spectrometer (HADES) at SIS18/GSI. The experimental correlation functions as a function of the relative momentum are compared to model calculations allowing the determination of the space-time extent of the corresponding emission sources. The π π source radii are found significantly larger than the pp emission radius. The present radii do well complement the source-size excitation functions of the collision system of size $A+A \simeq 40+40$. The pp source radius at fixed beam energy is found to increase linearly with the cube r…

Single-molecule spectroscopy of molecular aggregates at low temperature

We have conducted single-molecule spectroscopy of a fluorescent polyphenylene dendrimer consisting of four peripheral perylenemonoimides which serve as energy donors and a central terrylenediimide which is the energy acceptor. After selective excitation of the donors the low-temperature emission spectra of single dendrimers show the purely electronic zero-phonon line as the most prominent feature of the acceptor. These sharp emission lines are subjected to appreciable spectral shifts. Fluorescence excitation spectroscopy of individual dendrimers in the spectral region of the donor absorption allows to extract energy transfer rates for single donors within the dendrimer. Although the energy …

Deep sub-threshold K*(892)0 production in collisions of Ar + KCl at 1.76A GeV

Results on the deep sub-threshold production of the short-lived hadronic resonance K*(892)0 are reported for collisions of Ar + KCl at 1.76A GeV beam energy, studied with the High Acceptance Di-Electron Spectrometer (HADES) at SIS18/GSI. The K*(892)0 production probability per central collision of \( P_{K^{*0}}=(4.4\pm 1.1 \pm 0.5)\times 10^{-4}\) and the K*(892)0/K0 ratio of \( P_{K^{*0}}/P_{K^0}=(1.9\pm 0.5\pm 0.3)\times 10^{-2}\) are determined at the lowest energy so far (i.e. deep below the threshold for the corresponding production in nucleon-nucleon collisions, \( \sqrt{s_{NN}}-\sqrt{s_{thr}}=-340\) MeV). The K*0/K0 ratio is compared with results of other experiments and with the pre…

Single molecule spectroscopy of multichromophoric assemblies

We have investigated multichromophoric assemblies composed of a variable number of chromophores by single molecule spectroscopy. Specific spectral signatures have allowed to distinguish at the single molecule level between molecular dimers representing strong and weak electronic dipole-dipole coupling. By using fluorescence excitation spectroscopy at low temperature, the sharp purely electronic zero-phonon lines of single chromophores within a single dendrimer containing four chromophores could be isolated in the frequency domain.

Chapter 2 Single molecule spectroscopy of multichromophoric dendrimers at room and liquid helium temperatures

Publisher Summary This chapter discusses the single molecule spectroscopy of multichromophoric dendrimers at room and liquid helium temperatures. Single molecule spectroscopy has become an important tool for the optical study of the electronic interactions of proximate chromophores as the electronic interactions can be studied without averaging over the properties of an intrinsically heterogeneous ensemble. Single perylenemonoimide (PMI) chromophores are selectively addressed in the frequency domain within spatially isolated multichromophoric dendrimers, which are dispersed in a polymer film. Although the chromophores are interacting, they still can be addressed separately. This feature in …

HADES experiment: di-lepton spectroscopy in p + p (2.2 GeV) and C+C (1 and 2 A GeV) collisions

The HADES (High Acceptance Di-Electron Spectrometer) is a tool designed for lepton pair (e+e−) spectroscopy in pion, proton and heavy ion induced reactions in the 1–2AGeV energy range. One of the goals of the HADES experiment is to study in-medium modifications of hadron properties like effective masses, decay widths, electromagnetic form factors etc. Such effects can be probed with vector mesons ( ρ,ω,ɸ ) decaying into e+e− channel. The identification of vector mesons by means of a HADES spectrometer is based on invariant mass reconstruction of e+e− pairs. The combined information from all spectrometer sub-detectors is used to reconstruct the di-lepton signal. The recent results from 2.2Ge…

Watching the photo-oxidation of a single aromatic hydrocarbon molecule

International audience; The photooxidation of single dye molecules (see scheme) can be followed by confocal fluorescence microscopy. The self-sensitized reaction with singlet oxygen leads to a suite of products, which may be differentiated spectrally. Tentative structures for certain photoproducts have been obtained from quantum-chemical calculations.

Frequency selective excitation of single chromophores within shape-persistent multichromophoric dendrimers

Isolated multichromophoric dendrimers containing four perylenemonoimide chromophores were investigated in a confocal microscope which allowed imaging of the same set of dendrimers over a wide temperature range. Emission spectra at low temperature (2 K) reveal narrow zero-phonon lines although the electron-phonon coupling is not negligible. By using fluorescence excitation spectroscopy, the sharp purely electronic zero-phonon lines of single chromophores within a single multichromophoric unit could be isolated in the frequency domain. Selective excitation into a higher energy chromophoric site is followed by rapid directional energy transfer into the lowest energy site from which emission th…

Fluoreszenzmikroskopische Verfolgung des photooxidativen Abbaus eines einzelnen aromatischen Kohlenwasserstoffmoleküls