6533b857fe1ef96bd12b4fbd

RESEARCH PRODUCT

Watching the photo-oxidation of a single aromatic hydrocarbon molecule

Florian KulzerPatrice BordatT. ChristThomas Basché

subject

chemistry.chemical_classificationSingle-molecule spectroscopyphotochemistryChemistrySinglet oxygenConfocalGeneral ChemistryPhotochemistryCatalysisFluorescence spectroscopySingle Molecule Spectroscopychemistry.chemical_compoundbiological sciencesFluorescence microscopeMolecule[CHIM]Chemical SciencesPhysics::Chemical PhysicsAromatic hydrocarbonFluorescence spectroscopy

description

International audience; The photooxidation of single dye molecules (see scheme) can be followed by confocal fluorescence microscopy. The self-sensitized reaction with singlet oxygen leads to a suite of products, which may be differentiated spectrally. Tentative structures for certain photoproducts have been obtained from quantum-chemical calculations.

10.1002/1521-3773(20011119)40:22https://hal.archives-ouvertes.fr/hal-01567191