0000000000129284
AUTHOR
José Herráez
A combined single range and single image device for low-cost measurement of building facade features
The dimensions of building facades and window apertures are usually determined by making direct measurements using tapes and plummets. This approach, however, has a number of drawbacks including the physical risk to which the persons making the measurements are exposed. This paper proposes an indirect approach based on close range photogrammetry that is inexpensive, simple, fast and safe, and which does not require specialist staff or direct ground control measurements. The method is based on taking a picture using a digital camera and measuring the distance to the object using a handheld laser distance meter. Both items of equipment are mounted on a specially designed support that allows t…
Contribution to modeling the viscosity Arrhenius-type equation for some solvents by statistical correlations analysis
Abstract Estimation and knowledge of transport properties of fluids are essential for heat and mass flow. Viscosity is one of the important properties which are affected by temperature and pressure. In the present work, based on the use of econometric and statistical techniques for parametric and non-parametric regression analysis and statistical correlation tests, we propose an equation modeling the relationship between the two parameters of viscosity Arrhenius-type equation, such as the Arrhenius energy ( E a ) or the pre-exponential factor ( A s ). In addition, we introduce a third interesting parameter called Arrhenius temperature ( T A ), to enrich the discussion. Empirical validation …
Viscous Synergy of Pure Monoalcohol Mixtures in Water and Its Relation to Concentration
Pure or aqueous alcohols are the solvents most widely used in industry, including in the manufacture of pharmaceuticals and cosmetic products. However, water–alcohol mixtures generate hydrogen-bonded molecular associations that lead to volume contraction and an increase in viscosity greater than that expected in the absence of any interaction between the components of the mixture. This phenomenon is referred to as viscous synergy. The present study investigates viscous synergy in monoalcohol systems containing up to five carbon atoms, since beyond hexanol all alcohols are practically insoluble in water. In all cases, determinations were made of the proportions of water and alcohol for which…
In Vitro Percutaneous Penetration of Acyclovir from Solvent Systems and Carbopol 971-P Hydrogels: Influence of Propylene Glycol
The mechanism underlying propylene glycol (PG) effects on acyclovir (ACV) penetration through human epidermis were studied. Solvent systems and Carbopol gels containing increasing percentage of PG (from 0% to 70%, w/w) were used. Viscosity studies of both vehicles were carried out to characterise the influence of rheological behaviour. In solvent systems skin permeation values of ACV increase as the concentration of PG increase yielding a maximum enhancement ratio (ER = 10) for 70% PG. The release rate of ACV from gels was determined. Higuchi's model was used to estimate the apparent diffusion coefficient of the drug. These values show a decrease as the content of PG in the vehicle increase…
Two photogrammetric methods for measuring flat elements in buildings under construction
Usually, determining the dimensions of flat surfaces in buildings under construction, such as window cavities and facade coating materials, are done by direct measuring methods using tapes and plummets. Sometimes these methods suppose a slow and highly risky work for operators. This research proposes the substitution of these procedures by indirect methods based on close range photogrammetry and laser distance measurement. First, we show the design, construction and calibration of a system composed by a digital camera and a lasermeter mounted on a support with multiple turning positions. Next, two different facade element measuring methodologies are shown. The first method is based on takin…
Rheological study and thermodynamic analysis of the binary system (water/ethanol): Influence of concentration
Water is the most widely used solvent in the chemical and pharmaceutical industry, since it is the most physiological and best tolerated excipient. However, in some cases water cannot be used as a solvent because the active substance or solute is insoluble or only slightly soluble in water. For this and other reasons, nonwater solvents may be used possessing the common characteristic of being soluble or mixable in water; as a result, such solvents can be used to prepare binary or tertiary mixtures, etc., with different purposes such as increasing water solubility, or modifying the viscosity or absorption of the dissolved substance, for example. Ethanol, along with other alcohols either alon…
Treatment of Herráez equation correlating viscosity in binary liquid mixtures exhibiting strictly monotonous distribution
Recently, Herraez et al. proposed a new correlation equation, which introduces a correcting polynomial as an exponential-acting upon the molar fraction of one of mixture components. This equation is found to be widely applicable with more reasonable accuracy in systems exhibiting monotonous distribution than those presenting an extremum. In previous works, we have found that the first adjustable parameter of this equation is a universal exponent (0.5 or 1) for dioxane–water and isobutyric acid–water mixtures characterising the presence of solute–solute or solute–solvent interaction at very high dilution. In this work, we have tested this equation in 48 systems, and we have noted that severa…
A study of the refractive index and surface tension synergy of the binary water/ethanol: influence of concentration
Pure alcohols or alcohols mixed with water are the most widely used solvents in a great variety of industrial applications, including the formulation of pharmaceutical and cosmetic products. As a result of water/alcohol molecular associations, variations result in the physico-chemical characteristics of the system, such as density, viscosity, refractive index and surface tension. The present study investigates the refractive index and the surface tension of ethanol and water mixtures at a temperature of 25°C, for different molar fractions. The data obtained allow us to study the corresponding refractive index and the surface tension synergies; in this sense, an absolute maximum refractive i…
Consistency of Carbopol 971-P NF gels and influence of soluble and cross-linked PVP.
A study is made of the polymerization process of polyacrylic acid, commercially known as Carbopol® 971 NF, assessing its consistency as a function of the degree of neutralization at pH values from 3 to 12, approximately. Percentage concentrations ranging from 0.1 to 1.4% (w/w) were studied. The gels obtained were non-Newtonian, and pseudoplastic. As concentration and pH rise, the consistency of the gels increase to a maximum, which appears between pH 6 and 8, allowing their use as vehicles in bioadhesive formulations for mucosal application. Over the increasing viscosity interval, functions were obtained to indicate the consistency of the gel as a function of pH and concentration. Since the…
Control of structural problems in cultural heritage monuments using close-range photogrammetry and computer methods
This paper deals with the conservation of monumental buildings. Several methods used for the architectonic documentation are analysed in this study. Computers methods and close-range photogrammetry are proposed as a preventive method which allows to detect, measure and track the temporal evolution of some structural problems detected, and also to assess the degree of conservation of the materials employed. A group of monuments belonging to the Spanish historical heritage is analysed. In order to carry out the analysis a wire-frame model and a photo-realistic textured model were made. Work focused later on the area where structural problems were more acute.
Correlation analysis of the power law parameters for viscosity of some engineering fluids
Knowledge and estimation of transport properties of fluids which are sensitive to temperature variation like viscosity are necessary in mass flow and heat transfer computation. In the present work,...
Viscosity Arrhenius parameters correlation: extension from pure to binary fluid mixtures
Knowledge of fluids’ physicochemical properties is mandatory for the design and optimisation of industrial processes and products. A data quantity of most importance, in this regard, turns out to be the value of fluid viscosity. Many empirical and semi-empirical formulas have been proposed in the literature to describe the viscosity of pure liquids and binary liquid mixtures. Recently, an interesting equation is proposed for pure solvents correlating the two parameters in the viscosity Arrhenius-type equation, namely the activation energy (Ea) and the pre-exponential factor (As). This paper aims to extend the said correlation to binary liquid mixtures. To achieve this purpose, statistical m…