0000000000131875
AUTHOR
J. Williams
Chemical and meteorological influences on the lifetime of NO<sub>3</sub> at a semirural mountain site during "PARADE"
Abstract. Through measurements of NO2, O3, and NO3 during the PARADE campaign (PArticles and RAdicals, Diel observations of mEchanisms of oxidation) in the German Taunus mountains we derive nighttime, steady state lifetimes (τss) of NO3 and N2O5. During some nights, high NO3 (~ 200 pptv) and N2O5 (~ 1 ppbv) mixing ratios are associated with values of τss that exceeded one hour for NO3 and three hours for N2O5 near the ground. Such long boundary layer lifetimes for NO3 and N2O5 are usually only encountered in very clean/unreactive air masses whereas the PARADE measurement site is impacted by both biogenic emissions from the surrounding forest and anthropogenic emissions from the nearby urban…
Characterisation of NO production and consumption: new insights by an improved laboratory dynamic chamber technique
Biogenic NOx emissions from natural and anthropogenically influenced soils are currently estimated to amount to 9 Tg a−1, hence a significant fraction of global NOx emissions (45 Tg a−1). During the last three decades, a large number of field measurements have been performed to quantify biogenic NO emissions. To study biogenic NO emissions as a function of soil moisture, soil temperature, and soil nutrients, several laboratory approaches have been developed to estimate local/regional NO emissions by suitable upscaling. This study presents an improved and automated laboratory dynamic chamber system (consisting of six individual soil chambers) for investigation and quantification of all quant…
Measurement of the branching fraction and theCP-violating asymmetry for the decayB0→KS0π0
The authors measure the branching fraction and the CP-violating asymmetry of B{sup 0} {yields} K{sub S}{sup 0}{pi}{sup 0} decays with 227 million {Upsilon}(4S) {yields} B{bar B} events collected with the BABAR detector at the PEP-II asymmetric-energy e{sup +}e{sup -} collider at SLAC. They obtain a branching fraction {Beta}(B{sup 0} {yields} K{sup 0}{pi}{sup 0}) = (11.4 {+-} 0.9 {+-} 0.6) x 10{sup -6} and CP-violating asymmetry parameters C{sub K{sub S}{sup 0}{pi}{sup 0}} = 0.06 {+-} 0.18 {+-} 0.03 and S{sub K{sub S}{sup 0}{pi}{sup 0}} = 0.35{sub -0.33}{sup +0.30} {+-} 0.04, where the first error is statistical and the second systematic.
A comparison of HONO budgets for two measurement heights at a field station within the boreal forest in Finland
Atmospheric concentrations of nitrous acid (HONO), one of the major precursors of the hydroxyl radical (OH) in the troposphere, significantly exceed the values predicted by the assumption of a photostationary state (PSS) during daytime. Therefore, additional sources of HONO were intensively investigated in the last decades. This study presents budget calculations of HONO based on simultaneous measurements of all relevant species, including HONO and OH at two different measurement heights, i.e. 1 m above the ground and about 2 to 3 m above the canopy (24 m above the ground), conducted in a boreal forest environment. We observed mean HONO concentrations of about 6.5 × 108 molecules cm−3 (26 p…
Efficient generation of energetic ions in multi-ion plasmas by radio-frequency heating
We describe a new technique for the efficient generation of high-energy ions with electromagnetic ion cyclotron waves in multi-ion plasmas. The discussed ‘three-ion’ scenarios are especially suited for strong wave absorption by a very low number of resonant ions. To observe this effect, the plasma composition has to be properly adjusted, as prescribed by theory. We demonstrate the potential of the method on the world-largest plasma magnetic confinement device, JET (Joint European Torus, Culham, UK), and the high-magnetic-field tokamak Alcator C-Mod (Cambridge, USA). The obtained results demonstrate efficient acceleration of 3He ions to high energies in dedicated hydrogen–deuterium mixtures.…
The summertime Boreal forest field measurement intensive (HUMPPA-COPEC-2010): an overview of meteorological and chemical influences
This paper describes the background, instrumentation, goals, and the regional influences on the HUMPPACOPEC intensive field measurement campaign, conducted at the Boreal forest research station SMEAR II (Station for Measuring Ecosystem-Atmosphere Relation) in Hyyti¨al¨a, Finland from 12 July–12 August 2010. The prevailing meteorological conditions during the campaign are examined and contrasted with those of the past six years. Back trajectory analyses show that meteorological conditions at the site in 2010 were characterized by a higher proportion of southerly flow than in the other years studied. As a result the summer of 2010 was anomalously warm and high in ozone making the campaign rel…
The summertime Boreal forest field measurement intensive (HUMPPA-COPEC-2010): an overview of meteorological and chemical influences
This paper describes the background, instrumentation, goals, and the regional influences on the HUMPPACOPEC intensive field measurement campaign, conducted at the Boreal forest research station SMEAR II (Station for Measuring Ecosystem-Atmosphere Relation) in Hyyti¨al¨a, Finland from 12 July–12 August 2010. The prevailing meteorological conditions during the campaign are examined and contrasted with those of the past six years. Back trajectory analyses show that meteorological conditions at the site in 2010 were characterized by a higher proportion of southerly flow than in the other years studied. As a result the summer of 2010 was anomalously warm and high in ozone making the campaign rel…
Novel method for determination of tritium depth profiles in metallic samples
Tritium accumulation in fusion reactor materials is considered a serious radiological issue, therefore a lot of effort has been concentrated on the development of radiometric techniques. A novel method, based on gradual dissolution, for the determination of the total tritium content and its depth profiles in metallic samples is demonstrated. This method allows for the measurement of tritium in metallic samples after their exposure to a hydrogen and tritium mixture, tritium containing plasma or after irradiation with neutrons resulting in tritium formation. In this method, successive layers of metal are removed using an appropriate etching agent in the controlled regime and the amount of evo…
Measurement of theB0→D*−Ds*+andDs+→ϕπ+branching fractions
The authors present measurements of the branching fractions {Beta}(B{sup 0} {yields} D*{sup -}D*{sub s}{sup +}) and {Beta}(D{sub s}{sup +} {yields} {phi}{pi}{sup +}), based on 123 x 10{sup 6} {Upsilon}(4S) {yields} B{bar B} decays collected by the BABAR detector at the PEP-II asymmetric-energy e{sup +}e{sup -} B factory. A partial reconstruction technique is used to measure {Beta}(B{sup 0} {yields} D*{sup -}D*{sub s}{sup +}) and the decay chain is fully reconstructed to measure the branching fraction product {Beta}(B{sup 0} {yields} D*{sup -} D*{sub s}{sup +}) x {Beta}(D{sub s}{sup +} {yields} {phi}{pi}{sup +}). Comparing these two measurements provides a model-independent determination of …
Measurement of the branching fraction and decay rate asymmetry ofB−→Dπ+π−π0K−
The authors report the observation of the decay B{sup -} {yields} D{sub {pi}{sup +}{pi}{sup -}{pi}{sup 0}}K{sup -}, where D{sub {pi}{sup +}{pi}{sup -}{pi}{sup 0}} indicates a neutral D meson detected in the final state {pi}{sup +}{pi}{sup -}{pi}{sup 0}, excluding K{sub S}{sup 0}{pi}{sup 0}. This doubly Cabibbo-suppressed decay chain can be used to measure the CKM phase {gamma}. Using about 229 million e{sup +}e{sup -} {yields} B{bar B} events recorded by the BABAR experiment at the PEP-II e{sup +}e{sup -} storage ring, they measure the branching fraction {Beta}(B{sup -} {yields} D{sub {pi}{sup +}{pi}{sup -}{pi}{sup 0}K{sup -}}) = (5.5 {+-} 1.0 (stat.) {+-} 0.7 (syst.)) x 10{sup -6} and the …
Online atmospheric pressure chemical ionization ion trap mass spectrometry (APCI-IT-MSn) for measuring organic acids in concentrated bulk aerosol – a laboratory and field study
The field application of an aerosol concentrator in conjunction with an atmospheric pressure chemical ionization ion trap mass spectrometer (APCI-IT-MS) at the boreal forest station SMEAR II at Hyytiälä, Finland, is demonstrated in this study. APCI is a soft-ionization technique allowing online measurements of organic acids in the gas and particle phase. The detection limit for the acid species in the particle phase was improved by a factor of 7.5 to 11 (e.g. ∼40 ng m3 for pinonic acid) by using the miniature versatile aerosol concentration enrichment system (mVACES) upstream of the mass spectrometer. The APCI-IT-MS was calibrated in the negative ion mode with two biogenic organic acid …
Hydroxyl radicals in the tropical troposphere over the Suriname rainforest: comparison of measurements with the box model MECCA
As a major source region of the hydroxyl radical OH, the Tropics largely control the oxidation capacity of the atmosphere on a global scale. However, emissions of hydrocarbons from the tropical rainforest that react rapidly with OH can potentially deplete the amount of OH and thereby reduce the oxidation capacity. The airborne GABRIEL field campaign in equatorial South America (Suriname) in October 2005 investigated the influence of the tropical rainforest on the HO<sub>x</sub> budget (HO<sub>x</sub> = OH + HO<sub>2</sub>). The first observations of OH and HO<sub>2</sub> over a tropical rainforest are compared to steady state concentrations ca…
Comparison of the structure of the plasma-facing surface and tritium accumulation in beryllium tiles from JET ILW campaigns 2011-2012 and 2013-2014
In this study, beryllium tiles from Joint European Torus (JET) vacuum vessel wall were analysed and compared regarding their position in the vacuum vessel and differences in the exploitation conditions during two campaigns of ITER-Like-Wall (ILW) in 2011-2012 (ILW1) and 2013-2014 (ILW2) Tritium content in beryllium samples were assessed. Two methods were used to measure tritium content in the samples - dissolution under controlled conditions and tritium thermal desorption. Prior to desorption and dissolution experiments, scanning electron microscopy and energy dispersive x-ray spectroscopy were used to study structure and chemical composition of plasma-facing-surfaces of the beryllium sampl…
Measurement of branching fractions and charge asymmetries for exclusive B decays to charmonium
We report measurements of branching fractions and charge asymmetries of exclusive decays of neutral and charged B mesons into two-body final states containing a charmonium state and a light strange meson. The charmonium mesons considered are J/Psi, Psi(2S) and Chi_c1, and the light meson is either K or K*. We use a sample of about 124 million BBbar events collected with the BABAR detector at the PEP-II storage ring at the Stanford Linear Accelerator Center.
Early outcomes and complications following cardiac surgery in patients testing positive for coronavirus disease 2019: An international cohort study
The outbreak of severe acute respiratory syndromecoronavirus-2, the cause of coronavirus disease 2019 (COVID-19) in December 2019 represented a global emergency accounting for more than 2.5 million deaths worldwide.1 It has had an unprecedented influence on cardiac surgery internationally, resulting in cautious delivery of surgery and restructuring of services.2 Understanding the influence of COVID-19 on patients after cardiac surgery is based on assumptions from other surgical specialties and single-center studies. The COVIDSurg Collaborative conducted a multicenter cohort study, including 1128 patients, across 235 hospitals, from 24 countries demonstrating perioperative COVID-19 infection…
Measurement ofCPobservables for the decaysB±→DCP0K*±
We present a study of the decay B^- → D^0_(CP)K^± and its charge conjugate, where D^0_CP) is reconstructed in CP-even, CP-odd, and non-CP flavor eigenstates, based on a sample of 232 x 10^6 Y(4S) → BB decays collected with the BABAR detector at the PEP-II e^+e^- storage ring. We measure the partial-rate charge asymmetries A_(CP±) and the ratios R_(CP±) of the B → D^0K decay branching fractions as measured in CP^± and non-CP D^0 decays: A_(CP±) 0:35 ± 0.13(stat) ± 0.04(syst), A_(CP-)= -0.06 ± 0.13(stat) ± 0.04(syst), R_(CP+) = 0.90 ± 0.12(stat) ± 0.049syst), and R_(CP-) = 0:86 ± 0.10(stat) ± 0.05(syst).
Chemical and meteorological influences on the lifetime of NO3 at a semi-rural mountain site during PARADE
Through measurements of NO2, O3 and NO3 during the PARADE campaign (PArticles and RAdicals, Diel observations of mEchanisms of oxidation) in the German Taunus mountains we derive nighttime steady-state lifetimes (τss) of NO3 and N2O5. During some nights, high NO3 (∼ 200 pptv) and N2O5 (∼ 1 ppbv) mixing ratios were associated with values of τss that exceeded 1 h for NO3 and 3 h for N2O5 near the ground. Such long boundary-layer lifetimes for NO3 and N2O5 are usually only encountered in very clean/unreactive air masses, whereas the PARADE measurement site is impacted by both biogenic emissions from the surrounding forest and anthropogenic emissions from the nearby urbanised/industrialised cen…
Summertime total OH reactivity measurements from boreal forest during HUMPPA-COPEC 2010
Ambient total OH reactivity was measured at the Finnish boreal forest station SMEAR II in Hyytiälä (Latitude 61&deg;51' N; Longitude 24&deg;17' E) in July and August 2010 using the Comparative Reactivity Method (CRM). The CRM – total OH reactivity method – is a direct, in-situ determination of the total loss rate of hydroxyl radicals (OH) caused by all reactive species in air. During the intensive field campaign HUMPPA-COPEC 2010 (<b>H</b>yytiälä <b>U</b>nited <b>M</b>easurements of <b>P</b>hotochemistry and <b>P</b>articles in <b>A</b>ir – <b>C</b>omprehensive <b>O</b>rganic <b>P&l…
The Association of Intraoperative driving pressure with postoperative pulmonary complications in open versus closed abdominal surgery patients – a posthoc propensity score–weighted cohort analysis of the LAS VEGAS study
Abstract Background It is uncertain whether the association of the intraoperative driving pressure (ΔP) with postoperative pulmonary complications (PPCs) depends on the surgical approach during abdominal surgery. Our primary objective was to determine and compare the association of time–weighted average ΔP (ΔPTW) with PPCs. We also tested the association of ΔPTW with intraoperative adverse events. Methods Posthoc retrospective propensity score–weighted cohort analysis of patients undergoing open or closed abdominal surgery in the ‘Local ASsessment of Ventilatory management during General Anaesthesia for Surgery’ (LAS VEGAS) study, that included patients in 146 hospitals across 29 countries.…
Improved measurement of the 02+→01+ E0 transition strength for 72Se using the SPICE spectrometer
The selenium isotopes lie at the heart of a tumultuous region of the nuclear chart where shape coexistence effects grapple with neutron-proton pairing correlations, triaxiality, and the impending proton drip line. In this work, a study of 72Se by internal conversion electron and γ-ray spectroscopy was undertaken with the SPICE and TIGRESS arrays. New measurements of the branching ratio and lifetime of the 02+ state were performed, yielding a determination of ρ2(E0;02+→01+)=29(3) milliunits. Two-state mixing calculations were performed that highlighted the importance of interpretation of such E0 strength values in the context of shape coexistence. peerReviewed
Sensitivity of the Cherenkov Telescope Array to a dark matter signal from the Galactic centre
Full list of authors: Acharyya, A.; Adam, R.; Adams, C.; Agudo, I.; Aguirre-Santaella, A.; Alfaro, R.; Alfaro, J.; Alispach, C.; Aloisio, R.; Alves Batista, R.; Amati, L.; Ambrosi, G.; Angüner, E. O.; Antonelli, L. A.; Aramo, C.; Araudo, A.; Armstrong, T.; Arqueros, F.; Asano, K.; Ascasíbar, Y. Ashley, M.; Balazs, C.; Ballester, O.; Baquero Larriva, A.; Barbosa Martins, V.; Barkov, M.; Barres de Almeida, U.; Barrio, J. A.; Bastieri, D.; Becerra, J.; Beck, G.; Becker Tjus, J.; Benbow, W.; Benito, M.; Berge, D.; Bernardini, E.; Bernlöhr, K.; Berti, A.; Bertucci, B.; Beshley, V.; Biasuzzi, B.; Biland, A.; Bissaldi, E.; Biteau, J.; Blanch, O.; Blazek, J.; Bocchino, F.; Boisson, C.; Bonneau Arbe…
Summertime total OH reactivity measurements from boreal forest during HUMPPA-COPEC 2010
Ambient total OH reactivity was measured at the Finnish boreal forest station SMEAR II in Hyyti¨al¨a (Latitude 61510 N; Longitude 24170 E) in July and August 2010 using the Comparative Reactivity Method (CRM). The CRM – total OH reactivity method – is a direct, in-situ determination of the total loss rate of hydroxyl radicals (OH) caused by all reactive species in air. During the intensive field campaign HUMPPA-COPEC 2010 (Hyyti¨al¨a United Measurements of Photochemistry and Particles in Air – Comprehensive Organic Precursor Emission and Concentration study) the total OH reactivity was monitored both inside (18 m) and directly above the forest canopy (24 m) for the first time. The compariso…
Machine learning risk prediction of mortality for patients undergoing surgery with perioperative SARS-CoV-2: the COVIDSurg mortality score
The British journal of surgery 108(11), 1274-1292 (2021). doi:10.1093/bjs/znab183
Daytime formation of nitrous acid at a coastal remote site in Cyprus indicating a common ground source of atmospheric HONO and NO
Characterization of daytime sources of nitrous acid (HONO) is crucial to understand atmospheric oxidation and radical cycling in the planetary boundary layer. HONO and numerous other atmospheric trace constituents were measured on the Mediterranean island of Cyprus during the CYPHEX (CYprus PHotochemical EXperiment) campaign in summer 2014. Average volume mixing ratios of HONO were 35 pptv (±25 pptv) with a HONO ∕ NOx ratio of 0.33, which was considerably higher than reported for most other rural and urban regions. Diel profiles of HONO showed peak values in the late morning (60 ± 28 pptv around 09:00 local time) and persistently high mixing ratios during daytime (45 ± 18 pptv), indicating …
Modelling of JET hybrid plasmas with emphasis on performance of combined ICRF and NBI heating
International audience; During the 2015--2016 JET campaigns, many efforts have been devoted to the exploration of high-performance plasma scenarios envisaged for DT operation in JET. In this paper, we review various key recent hybrid discharges and model the combined ICRF NBI heating. These deuterium discharges with deuterium beams had the ICRF antenna frequency tuned to match the cyclotron frequency of minority H at the centre of the tokamak coinciding with the second harmonic cyclotron resonance of D. The modelling takes into account the synergy between ICRF and NBI heating through the second harmonic cyclotron resonance of D beam ions, allowing us to assess its impact on the neutron rate…
Meta-analysis of 74,046 individuals identifies 11 new susceptibility loci for Alzheimer's disease
Eleven susceptibility loci for late-onset Alzheimer's disease (LOAD) were identified by previous studies; however, a large portion of the genetic risk for this disease remains unexplained. We conducted a large, two-stage meta-analysis of genome-wide association studies (GWAS) in individuals of European ancestry. In stage 1, we used genotyped and imputed data (7,055,881 SNPs) to perform meta-analysis on 4 previously published GWAS data sets consisting of 17,008 Alzheimer's disease cases and 37,154 controls. In stage 2, 11,632 SNPs were genotyped and tested for association in an independent set of 8,572 Alzheimer's disease cases and 11,312 controls. In addition to the APOE locu…