0000000000134793
AUTHOR
F. X. Meixner
HONO Emissions from Soil Bacteria as a Major Source of Atmospheric Reactive Nitrogen
From Soil to Sky Trace gases emitted either through the activity of microbial communities or from abiotic reactions in the soil influence atmospheric chemistry. In laboratory column experiments using several soil types, Oswald et al. (p. 1233 ) showed that soils from arid regions and farmlands can produce substantial quantities of nitric oxide (NO) and nitrous acid (HONO). Ammonia-oxidizing bacteria are the primary source of HONO at comparable levels to NO, thus serving as an important source of reactive nitrogen to the atmosphere.
Characterisation of NO production and consumption: new insights by an improved laboratory dynamic chamber technique
Biogenic NOx emissions from natural and anthropogenically influenced soils are currently estimated to amount to 9 Tg a−1, hence a significant fraction of global NOx emissions (45 Tg a−1). During the last three decades, a large number of field measurements have been performed to quantify biogenic NO emissions. To study biogenic NO emissions as a function of soil moisture, soil temperature, and soil nutrients, several laboratory approaches have been developed to estimate local/regional NO emissions by suitable upscaling. This study presents an improved and automated laboratory dynamic chamber system (consisting of six individual soil chambers) for investigation and quantification of all quant…
Recent trends of temperature change under hot and cold desert climates: Comparing the Sahara (Libya) and Central Asia (Xinjiang, China)
Abstract According to trend computations at three stations each in Sahara desert (Libya), characterized by a “hot” desert type (“BWh”, according to the Koeppen climate classification), and in Central Asia (Xinjiang, China) identified as a “cold” desert type (“BWk”, after Koeppen), increasing annual temperatures were detected over the period 1955–2005 corresponding with global temperature warming. From 1955–1978, negative (decreasing) temperature trends were, however, observed at all three hot desert stations and at two of the three cold desert stations. From 1979–2005, strikingly positive temperature trends were seen at all six stations. In seasonal respects, winter (December to February) a…
Hydroxylamine released by nitrifying microorganisms is a precursor for HONO emission from drying soils
AbstractNitrous acid (HONO) is an important precursor of the hydroxyl radical (OH), the atmosphere´s primary oxidant. An unknown strong daytime source of HONO is required to explain measurements in ambient air. Emissions from soils are one of the potential sources. Ammonia-oxidizing bacteria (AOB) have been identified as possible producers of these HONO soil emissions. However, the mechanisms for production and release of HONO in soils are not fully understood. In this study, we used a dynamic soil-chamber system to provide direct evidence that gaseous emissions from nitrifying pure cultures contain hydroxylamine (NH2OH), which is subsequently converted to HONO in a heterogeneous reaction w…