0000000000141608
AUTHOR
Michael Berger
Metal-free electrochemical fluorodecarboxylation of aryloxyacetic acids to fluoromethyl aryl ethers
Electrochemical decarboxylation of aryloxyacetic acids followed by fluorination provides easy access to fluoromethyl aryl ethers. This electrochemical fluorodecarboxylation offers a sustainable approach with electric current as traceless oxidant. Using Et3N·5HF as fluoride source and as supporting electrolyte, this simple electrosynthesis affords various fluoromethoxyarenes in yields up to 85%.
Synergistic use of MERIS and AATSR as a proxy for estimating Land Surface Temperature from Sentinel-3 data
Land Surface Temperature (LST) is one of the key parameters in the physics of land-surface processes on regional and global scales, combining the results of all surface-atmosphere interactions and energy fluxes between the surface and the atmosphere. With the advent of the ESA's Sentinel 3 (S3) satellite, accurate LST retrieval methodologies exploiting the synergy between OLCI and SLSTR instruments can be developed. In this paper we propose a candidate methodology for retrieving LST from data acquired with the forthcoming S3 instruments. The LST algorithm is based on the Split-Window (SW) technique with an explicit dependence on surface emissivity, in contrast to the AATSR level 2 algorithm…
FluorMODgui V3.0 : a graphic user interface for the spectral simulation of leaf and canopy chlorophyll fluorescence
The FluorMODgui Graphic User Interface (GUI) software package developed within the frame of the FluorMOD project Development of a Vegetation Fluorescence Canopy Model is presented in this manuscript. The FluorMOD project was launched in 2002 by the European Space Agency (ESA) to advance the science of vegetation fluorescence simulation through the development and integration of leaf and canopy fluorescence models based on physical methods. The design of airborne or space missions dedicated to the measurement of solar-induced chlorophyll fluorescence using remote-sensing instruments require physical methods for quantitative feasibility analysis and sensor specification studies. The FluorMODg…
Electrochemical Fluorocyclization of N-Allylcarboxamides to 2-Oxazolines by Hypervalent Iodine Mediator
A resource saving protocol for the synthesis of 5-fluoromethyl-2-oxazolines by using electrochemistry has been realized. Thereby, a hypervalent iodine species I(III) is generated by anodic oxidation in the presence of Et3N·5HF and mediates the cyclization of N-allylcarboxamide to 5-fluoromethyl-2-oxazoline. This method allows application to various substrates furnishing the 2-oxazolines with yields up to 68%. The protocol is easy to conduct under constant current conditions offering a sustainable alternative over conventional reagent-based pathways.
High spatio- temporal resolution land surface temperature mission - a copernicus candidate mission in support of agricultural monitoring
International audience; Evolution in the Copernicus Space Component (CSC) is foreseen in the mid-2020s to meet priority Copernicus user needs not addressed by the existing infrastructure, and/or to reinforce services by monitoring capability in the thematic domains of CO 2 , polar, and agriculture/forestry. This evolution will be synergetic with the enhanced continuity of services for the next generation of CSC. The “High Spatio-Temporal Resolution Land Surface Temperature Monitoring (LSTM) Mission”, identified as one of the CSC Expansion High Priority Candidate Missions (HPCM), currently undergoes an ESA preparatory phase (phase A/B1) study to establish mission feasibility. The LSTM missio…
The WISE 2000 and 2001 Field Experiments in Support of the SMOS Mission:Sea Surface L-Band Brightness Temperature Observations and Their Application to Sea Surface Salinity Retrieval.
Camps, Adriano ... et al.-- 20 pages, 16 figures, 3 tables
Fluorocyclization of N-Propargylamides to Oxazoles by Electrochemically Generated ArIF2
A sustainable synthesis of 5-fluoromethyl-2-oxazoles by use of electrochemistry has been demonstrated. Hypervalent ArIF2 is generated by direct electrochemical oxidation of iodoarene ArI in Et3N·5HF and mediates the fluorocyclization of N-propargylamides to 5-fluoromethyl-2-oxazoles. The stoichiometry in ArI turned out to be a key parameter in controlling the product selectivity. This electrochemical protocol provides access to fluorinated oxazoles starting from simply available N-propargylamides with yields up to 65% and offers a green alternative over conventional reagent-based approaches.
Diaphragmatic Hernia following Pediatric Liver Transplantation: An Underappreciated Complication Prone to Recur.
Abstract Introduction Postoperative diaphragmatic hernia (DH) is a rare but potentially life-threatening complication following pediatric liver transplantation (LT). In the current literature, a total of 49 such hernias have been reported in 17 case series. We present eight additional cases, three of which reoccurred after surgical correction, and review the current literature with a focus on recurrence. Materials and Methods The study sample included children (<18 years of age) who underwent LT between June 2013 and June 2020 at five large transplant centers and who subsequently presented with DH. During the study period, a total of 907 LT was performed. Eight DH were recognized, and ri…
ESA's sentinel missions in support of Earth system science
Abstract The spatial and temporal characteristics of the new Sentinel missions, primarily designed to provide routine multidisciplinary observations for operational services, are also very suitable for addressing some of the challenges associated with advancing Earth System sciences. The Sentinels are ensuring long-term observational commitment and will operate a range of instruments with different spectral bands and spatial resolutions with global coverage and high revisit times. The complexity of Earth System models has been increasing gradually and most simulations of future climate and Earth system evolution are based on coupled models that include aspects of physics, bio/geo-chemistry,…