The kinetics of anionic polymerization of styrene in 1,2-dimethoxiethane

Kinetic measurements in a flow apparatus in combination with conductance measurements, permit the determination of the two equilibrium constants Kes and Kdiss* and the three propagation rate constants k(±)c, k(±)s and k(−) as a function of temperature. The great differences in the polymerization rate in various solvents are mainly caused by their influence on the equilibrium constants. The influence of the solvent on the rate constants is not greater than in other chemical reactions.

Energie- und Entropieparameter der Zustandsformen von Carbanionen aus der Polymerisationskinetik und aus Leitfähigkeitsmessungen an Polystyrylnatrium in polaren organischen Lösungsmitteln

Zustände und Reaktionen des Carbanions bei der anionischen Polymerisation des Styrols