The kinetics of anionic polymerization of styrene in 1,2-dimethoxiethane

6533b7d1fe1ef96bd125caf4

RESEARCH PRODUCT

The kinetics of anionic polymerization of styrene in 1,2-dimethoxiethane

J. M. Alvarino Bardo Schmitt G. V. Schulz M. Chmeliř

subject

Solvent chemistry.chemical_compound Anionic addition polymerization Reaction rate constant Polymerization Chemistry Kinetics Polymer chemistry General Engineering Physical chemistry Chemical reaction Equilibrium constant Styrene

description

Kinetic measurements in a flow apparatus in combination with conductance measurements, permit the determination of the two equilibrium constants Kes and Kdiss* and the three propagation rate constants k(±)c, k(±)s and k(−) as a function of temperature. The great differences in the polymerization rate in various solvents are mainly caused by their influence on the equilibrium constants. The influence of the solvent on the rate constants is not greater than in other chemical reactions.

year	journal	country	edition	language
2007-03-08	Journal of Polymer Science: Polymer Symposia

https://doi.org/10.1002/polc.5070420118

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