0000000000172205
AUTHOR
Linda Ansone-bertina
Biochar from Waste Derived Fuels as Low-Cost Adsorbent for Waste Hydrocarbons
Abstract The aim of this study is to prove technical feasibility of combined refuse derived fuel (RDF) torrefaction and oily wastewater treatment approach by using RDF derived biochar as a sorption media. Biochars prepared from refuse derived fuels in torrefaction, carbonization and pyrolysis modes were analysed as fuels and as hydrocarbon sorbents. Changes of elemental composition and properties of material during thermal treatment and subsequent washing process have been analysed. Experimental evaluation of sorption behaviour of toluene and diesel fuel on obtained biochar performed. Our results show that torrefaction/carbonization of RDF coupled with the subsequent washing of biochar is a…
Biomass Waste Processing into Artificial Humic Substances
Abstract To address the biomass waste processing problem and transform it into refractory forms of carbon, recently suggested hydrothermal carbonization (HTC) of biomass in alkaline environment can be considered as a prospective and climate neutral approach. Biomass HTC provides possibilities to obtain form of biochar (hydrochar) and artificial humic substances, however the conditions of the HTC have not been much studied. Optimization by Response Surface Methodology of the HTC using microwave treatment with three experimental variables (treatment temperature, length of microwave treatment, amount of biomass per volume) provides the possibility to significantly increase the yield of humic s…
Sorption of V and VI group metalloids (As, Sb, Te) on modified peat sorbents
AbstractThe present work investigates arsenic, antimony and tellurium sorption using iron modified peat. The results were obtained using batch tests and the sorption was studied as a function of initial metalloid concentration, pH and sorption time, as well as the presence of competing substances. The obtained results indicate that modification of peat with Fe compounds significantly enhances the sorption capacity of the sorbents used for sorption of arsenic, antimony and tellurium. The optimal pH interval for the sorption of Sb(III) is 6.5–9 and for As(V) and Sb(V) – 3–6, while As(III) and tellurium sorption using Fe-modified peat is favourable in a wider interval of 3–9. The presence of c…
Immobilised Humic Substances as Low-Cost Sorbents for Emerging Contaminants
Environmental pollution with contaminants of emerging concern (CECs) is a worldwide problem that is receiving increasing attention. Although these substances have been released in the aquatic environment for a long time, wastewater treatment plants are still incapable of removing emerging contaminants completely. Consequently, trace metals, metalloids and pharmaceuticals, as well as surfactant leftovers, are often found in environmental samples. Environmentally friendly and cost-effective sorbents such as humic substances can be used for purification if their sorption properties are increased by immobilization. To our knowledge, immobilized humic substances have not been widely studied as s…
FeOOH-modified clay sorbents for arsenic removal from aqueous solutions
The presence of arsenic (As) in natural and anthropogenic soils causes severe pollution of groundwater due to its harmful carcinogenic effects. The present work describes the research activities for searching of appropriate innovative sorbents based on clay material for As sorption using iron oxy-hydroxide modification. Natural and manufactured clay was chosen for comparison of modification efficiency in order to obtain best sorption results for As(V). The results of pilot testing were obtained and the sorption was studied as a function of initial arsenic concentration. Obtained results indicate that modification of clay with Fe compounds significantly improves the sorption capacity of a ne…
Thermal decomposition study of major refuse derived fuel components
Abstract Refuse Derived Fuel (RDF) composed on biomass, paper, textiles, wood, synthetic polymers and other combustible materials is an alternative energy resource to implement Waste-to-Energy strategy. The aim of this study is to investigate the thermal decomposition characteristics of materials forming RDF by thermogravimetric analysis. Thermogravimetric (TG) analysis of RDF components demonstrates major differences in processes behind the thermal decomposition processes of waste components. Biomass decomposition can be divided into two distinct stages for wood, cotton, cotton wool and other biomass samples whereas three distinct stages can be distinguished for cardboard and paper samples…
Metal–Organic Frameworks (MOFs) Containing Adsorbents for Carbon Capture
This research was funded by the European Regional Development Fund project “Innovation of the waste‐to‐energy concept for the low carbon economy: development of novel carbon capture technology for thermochemical processing of municipal solid waste (carbon capture and storage from waste—CCSW)”, grant number 1.1.1.1/19/A/013.