Effects of Weak Links in the Nonlinear Microwave Response of MgB2 Superconductor

We report experimental results of second-harmonic (SH) response at microwave frequency in several ceramic MgB2 samples, prepared by different methods. The SH signal has been investigated as a function of the temperature and DC magnetic field. The investigation has been carried out at low magnetic fields, where nonlinear processes arising from motion of Abrikosov fluxons are ineffective. We show that the low-temperature SH emission is ascribable to processes involving weak links. Comparison among the peculiarities of the SH signal radiated by the different samples shows that the presence of weak links strongly depends on the sample preparation method, as well as the purity and morphology of …

An experiment on wind energy

We discuss an experiment on wind energy performed with home-made apparatus. The experiment reproduces a laboratory windmill, which can pump water from a lower level to a higher one. By measuring the gain of the gravitational potential energy of the pumped water, one can determine the power extracted from the wind. The activity was carried out with high-school students, in the framework of the Italian National Plan for Scientific Degrees-Physics. The proposed experiment allows teachers to discuss renewable energy sources with students whose knowledge of physics is limited to mechanics. It gives students the possibility to gain experience with energy and to increase their awareness of this re…

Harmonic emission at microwave frequencies in Ba0.6K0.4BiO3 crystals

Abstract Nonlinear microwave emission by Ba0.6K0.4BiO3 crystals is investigated. Second- and third-harmonic signals are studied as a function of the temperature and the applied magnetic field at different values of the input power level. The experimental data are discussed in the framework of models previously reported in the literature. We show that there are several mechanisms responsible for harmonic emission in Ba0.6K0.4BiO3 crystals: they play a different role depending on the temperature and the intensity of the applied field. We suggest that harmonic emission at temperatures far from Tc is due to nonlinear processes in weak links or flux motion, while nonlinearity near Tc is ascribab…

Magnetic hysteresis in the microwave surface resistance of Nb samples in the critical state

We discuss the hysteretic behavior of the field-induced variations of the microwave surface resistance in superconductors in the critical state. Measurements have been performed in a bulk sample of Nb and a powdered one at different values of the temperature. We discuss a model, based on the Coffey and Clem theory, in which we take into account the flux distribution inside the sample, due to the critical state. The experimental results are justified quantitatively in the framework of our model. We show that by fitting the experimental data it is possible to determine the value of the critical current density and its field dependence.

Tunable coaxial cavity resonator for linear and nonlinear microwave characterization of superconducting wires

We discuss experimental results obtained using a tunable cylindrical coaxial cavity constituted by an outer Cu cylinder and an inner Pb-BSCCO wire. We have used this device for investigating the microwave response of the superconducting wire, both in the linear and nonlinear regimes. In particular, by tuning the different modes of the cavity to make them resonant at exactly harmonic frequencies, we have detected the power emitted by the superconducting inner wire at the second- and third-harmonic frequency of the driving field. The results obtained in the nonlinear regime, whether for the microwave surface impedance or the harmonic emission, are qualitatively accounted for considering inter…

Electrical-optical characterization of multijunction solar cells under 2000X concentration

In the framework of the FAE "Fotovoltaico ad Alta Efficienza" ("High Efficiency Photovoltaic") Research Project (PO FESR Sicilia 2007/2013 4.1.1.1), we have performed electrical and optical characterizations of commercial InGaP/InGaAs/Ge triple-junction solar cells (1 cm2) mounted on a prototype HCPV module, installed in Palermo (Italy). This system uses a reflective optics based on rectangular off-axis parabolic mirror with aperture 45×45 cm2 leading to a geometrical concentration ratio of 2025. In this study, we report the I-V curve measured under incident power of about 700 W/m2 resulting in an electrical power at maximum point (PMP) of 41.4 W. We also investigated the optical properties…

Microwave harmonic emission in MgB2 superconductor: Comparison with YBA2CU3O7

We report results of microwave second-harmonic generation in ceramic samples of MgB2, prepared by different methods. The SH signal has been investigated as a function of the temperature and the static magnetic field. The results are discussed in the framework of models reported in the literature. We show that the peculiarities of the SH signal are related to the specific properties of the sample. A comparison with the results obtained in ceramic and crystalline YBa2Cu3O7 shows that the second-harmonic emission in MgB2 is weaker than that observed in ceramic YBa2CuO7. (c) 2006 Wiley Periodicals, Inc.

Computer simulations to approach surface tension by means of a simple mesoscopic mechanical model

A small insect can stand or walk on water surface, drops of mercury do not spread on a solid surface, and a meniscus is formed at the free surface of a liquid contained in a thin vessel. These phenomena can be seen as macroscopic manifestations of molecular interactions and can be explained macroscopically in terms of surface tension. In this study, we deal with an approach to surface tension from a mechanical point of view, presenting a simple mesoscopic mechanical model of surface tension and the results of its implementation in numerical fluid dynamics simulations. Particularly, phenomena like droplet formation without gravity and with gravity when it can drop from a narrow hole like a t…

The double cone: a mechanical paradox or a geometrical constraint?

In the framework of the Italian National Plan ‘Lauree Scientifiche’ (PLS) in collaboration with secondary schools, we have investigated the mechanical paradox of the double cone. We have calculated the geometric condition for obtaining an upward movement. Based on this result, we have built a mechanical model with a double cone made of aluminum and a couple of wooden rails.

Field-induced suppression of the pi-band superconductivity and magnetic hysteresis in the microwave surface resistance of MgB_2 at temperatures near T_c

We report on the magnetic-field-induced variations of the microwave surface resistance, R_s, in a polycrystalline MgB_2 sample, at different values of temperature. We have detected a magnetic hysteresis in R_s, which exhibits an unexpected plateau on decreasing the DC magnetic field below a certain value. In particular, at temperatures near T_c the hysteresis manifests itself only through the presence of the plateau. Although we do not quantitatively justify the anomalous shape of the magnetic hysteresis, we show that the results obtained in the reversible region of the R_s(H) curve can be quite well accounted for by supposing that, in this range of magnetic field, the pi-gap is almost supp…

Near-Tc second-harmonic emission in high-density bulk MgB2 at microwave frequency

We discuss the microwave second-harmonic generation in high-density bulk MgB2, prepared by the reactive liquid Mg infiltration technology. The intensity of the harmonic signal has been investigated as a function of temperature and amplitudes of the DC and microwave magnetic fields. The results are discussed in the framework of a phenomenological theory, based on the two-fluid model, which assumes that both the microwave and static magnetic fields, penetrating in the surface layers of the sample, weakly perturb the partial concentrations of the normal and superconducting fluids. We show that, in order to account for the experimental results, it is essential to suppose that in MgB2 the densit…

A mechanical model of the smartphone’s accelerometer

To increase the attention of students, several physics experiments can be performed at school, as well at home, by using the smartphone as laboratory tools. In the paper we describe a mechanical model of the smartphone's accelerometer, which can be used in classroom to allow students to better understand the principle of the accelerometer even by students at the beginning of the study in physics.

Microwave Response of Ceramic MgB2 Samples

The microwave response of ceramic MgB2 has been investigated as a function of temperature and external magnetic field by two different techniques: microwave surface impedance and second-harmonic emission measurements. The measurements of the surface resistance have shown that microwave losses in MgB2 are strongly affected by the magnetic field in the whole range of temperatures below Tc, even for relatively low field values. The results have been accounted for in the framework of the Coffey and Clem model hypothesizing that in different temperature ranges the microwave current induces fluxons to move in different regimes. In particular, the results at temperatures close to Tc have been quan…

Microwave second-harmonic response of ceramic MgB2 samples

Nonlinear microwave response of different ceramic MgB2 samples has been investigated by the technique of second-harmonic emission. The second-harmonic signal has been investigated as a function of temperature, DC magnetic field and input microwave power. The attention has mainly been devoted to the response at low magnetic fields, where nonlinear processes arising from motion of Abrikosov fluxons are ineffective. The results show that different mechanisms are responsible for the nonlinear response in the different ranges of temperature. At low temperatures, the nonlinear response is due to processes involving weak links. At temperatures close to Tc, a further contribution to the harmonic em…

Microwave surface resistance of pristine and neutron-irradiated MgB2 samples in magnetic field

We report on the microwave surface resistance of two polycrystalline Mg11B2 samples; one consists of pristine material, the other has been irradiated at very high neutron fluence. It has already been reported that in the strongly irradiated sample the two gaps merge into a single value. The mw surface resistance has been measured in the linear regime as a function of the temperature and the DC magnetic field, at increasing and decreasing fields. The results obtained in the strongly irradiated sample are quite well justified in the framework of a generalized Coffey and Clem model, in which we take into account the field distribution inside the sample due to the critical state. The results ob…

Microwave response of bulk MgB2 samples of different granularity

The microwave response of three high-density bulk MgB2 samples has been investigated in the linear and nonlinear regimes. The three samples, characterized by different mean size of grains, have been obtained by reactive infiltration of liquid Mg in powdered B preforms. The linear response has been studied by measuring the microwave surface impedance; the nonlinear response by detecting the power radiated by the sample at the second-harmonic frequency of the driving field. Our results suggest that bulk MgB2 prepared by the liquid Mg infiltration technique is particularly promising for manufacturing resonant cavities operating at microwave frequencies.

Superconducting Microwave Cavity Made of Bulk MgB2

We report the successful manufacture and characterization of a microwave resonant cylindrical cavity made of bulk MgB2 superconductor (Tc = 38.5 K), which has been produced by the Reactive Liquid Mg Infiltration technique. The quality factor of the cavity for the TE011 mode, resonating at 9.79 GHz, has been measured as a function of the temperature. At T = 4.2 K, the unloaded quality factor is 2.2x10^5; it remains of the order of 10^5 up to T ~ 30 K. We discuss the potential performance improvements of microwave cavities built from bulk MgB2 materials produced by reactive liquid Mg infiltration.

A didactic experiment and model of a flat-plate solar collector

We report on an experiment performed with a home-made flat-plate solar collector, carried out together with high-school students. To explain the experimental results, we propose a model that describes the heating process of the solar collector. The model accounts quantitatively for the experimental data. We suggest that solar-energy topics should be included in school programmes to give students the opportunity to gain experience with solar energy and increase their awareness of the benefits that can be obtained from this remarkable and renewable energy source.

'School adopts an experiment': the magnetic levitation of superconductors

The event 'School adopts an experiment' is an event targeted at high schools and secondary schools. It is based on a tight and direct collaboration between researchers and school students and teachers. Several schools were involved in the event by 'adopting' an experiment in physics research laboratories. Groups of selected students were first trained by university researchers, then they demonstrated the experiments to other students and teachers during the event. Students who adopted an experiment acquired knowledge of the subjects connected with the experiment in a most impressive way compared with the usual didactics at school. Further positive points were: (i) to establish a close and d…

Depinning frequency in a heavily neutron-irradiated MgB2 sample

The magnetic-field-induced variations of the microwave surface resistance have been investigated in a heavily neutron-irradiated MgB2 sample, in which the irradiation has caused the merging of the two gaps into a single value. The experimental results have been analyzed in the framework of the Coffey and Clem model. By fitting the experimental data, we have determined the field dependence of the depinning frequency, omega_0, at different values of the temperature. Although the pinning is not particularly effective, the value of omega_0 obtained at low temperatures is considerably higher than that observed in conventional low-temperature superconductors.

High-Efficiency Multi-Junction Photovoltaic Cells in School Physics Laboratory

Energy consumption in the world is increasing more and more due to the huge energy request coming from emerging countries such as China, India, etc. To face the challenge of sustainability, a solution may be the use of solar energy, since it is the most abundant renewable energy source on Earth. The electromagnetic energy coming from the Sun can be converted into usable energy (electricity) by solar cells, whose conversion efficiency is continuously increasing due to scientific and technological progress. The proposed activity is thought to be carried out with secondary as well as high school students to allow teachers to discuss sustainability issues, and to provide students with an introd…

Effect of boron doping in the microwave surface resistance of neutron irradiated melt-textured Y1.6Ba2.3Cu3.3O7−x samples

We report on the microwave surface resistance of melt-textured Y_1.6Ba_2.3Cu_3.3O_7-x samples, doped with different amount of B_2O_3 and, subsequently, irradiated by thermal neutrons at the fluence of 1.476 \times 10^17 cm^-2. The microwave surface resistance has been measured as a function of temperature and DC magnetic field. The experimental results are quantitatively discussed in the framework of the Coffey and Clem theory, properly adapted to take into account the d-wave nature of cuprate superconductors. By fitting the experimental data at zero DC field, we have highlighted the effects of the induced defects in the general properties of the samples, including the intergranular region.…

Surface-barrier effects in the microwave second-harmonic response of superconductors in the mixed state

We report on transient effects in the microwave second-harmonic response of different type of superconductors in the mixed state. The samples have contemporarily been exposed to a dc magnetic field, varying with a constant rate of 60 Oe/s, and a pulsed microwave magnetic field. The time evolution of the signal radiated at the second-harmonic frequency of the driving field has been measured for about 500 s from the instant in which the dc-field sweep has been stopped, with sampling time of ∼0.3 s. We show that the second-harmonic signal exhibits two relaxation regimes; an initial exponential decay, which endures roughly 10 s, and a logarithmic decay in the time scale of minutes. Evidence is …

Time evolution of the microwave second-harmonic response of MgB2 superconductor

We report on transient effects in the microwave second-order response of two ceramic MgB2 samples. The time evolution of the second-harmonic signal is investigated for about 500 s after the sample has been exposed to a variation of the dc magnetic field. We suggest that during the first seconds the response is determined by diffusive motion of fluxons, while in the time scale of minutes it is ruled by magnetic relaxation over the surface barrier.

Fluxon dynamics in Li–Al codoped MgB2 by microwave surface resistance measurements

The magnetic-field-induced variations of the microwave surface resistance, Rs, have been investigated in ceramic Mg_(1-x)(LiAl)_xB_2, with x in the range 0.1 - 0.4. The measurements have been performed on increasing and decreasing the DC magnetic field, H0, at fixed temperatures. At low temperatures, we have observed a magnetic hysteresis in the Rs(H0) curves in all the investigated samples. On increasing the temperature, the range of H0 in which the hysteretic behavior is visible shrinks; however, in the sample with x=0.1 it is present up to temperatures close to Tc. We show that the field dependence of Rs can be quantitatively justified taking into account the critical-state effects on th…

Measurement of the Convective Heat-Transfer Coefficient

We propose an experiment for investigating how objects cool down toward the thermal equilibrium with its surrounding through convection. We describe the time dependence of the temperature difference of the cooling object and the environment with an exponential decay function. By measuring the thermal constant tau, we determine the convective heat-transfer coefficient, which is a characteristic constant of the convection system.

Introduzione al Laboratorio di Fisica: gli errori nelle misure sperimentali

L'attività di laboratorio deve fornire agli studenti la possibilita di effettuare osservazioni quantitative di grandezze fisiche facilmente individuabili e analizzabili. Per questo motivo, bisogna pensare esperimenti operativi, cioe esperimenti che possano essere eseguiti in laboratorio allo scopo di studiare la relazione tra le varie grandezze fisiche coinvolte e quindi determinare la relativa legge fisica. Questi esperimenti hanno valenze didattiche prevalenti per la misura, l'analisi dei dati, la formalizzazione della legge fisica e per gli aspetti formativi in generale. Gli esperimenti illustrativi, cioe esperimenti in cui viene visualizzato un determinato fenomeno fisico, non sono indi…

Critical-state effects on microwave losses in type-II superconductors

We discuss the microwave energy losses in superconductors in the critical state. The field-induced variations of the surface resistance are determined, in the framework of the Coffey and Clem model, by taking into account the distribution of the vortex magnetic field inside the sample. It is shown that the effects of the critical state cannot generally be disregarded to account for the experimental data. Results obtained in bulk niobium at low temperatures are quantitatively justified.

Anomalous magnetic hysteresis in the microwave surface resistance of MgB2 superconductor

We report experimental results of the field-induced variations of the microwave surface resistance in samples of MgB2, produced by different methods. By sweeping the DC magnetic field at increasing and decreasing values, we have detected a magnetic hysteresis that can be ascribed to the different magnetic induction, due to the critical state of the fluxon lattice. The hysteresis observed in the bulk samples has an unusual shape, which cannot be justified in the framework of the critical-state models.

Frequency dependence of the microwave surface resistance of MgB2 by coaxial cavity resonator

Abstract We report on the microwave (mw) properties of a cylindrical MgB2 rod prepared by the reactive liquid Mg infiltration technology. The MgB2 rod, 94.3 mm long, is used as inner conductor of a coaxial cavity having a Cu tube as external conductor. By analyzing the resonance curves of the cavity in the different resonant modes and at different temperatures, we have determined the temperature dependence of the mw surface resistance, R s , of the MgB2 material, at fixed frequencies, and the frequency dependence of R s , at fixed temperatures. Our results show that the R s ( f ) curves follow a f n law, where n decreases on increasing the temperature, starting from n ≈ 2 , at T = 4.2 K , d…

'Naughty cylinder' mechanical paradox

Electromagnetic response of LaO_0.94F_0.06FeAs: AC susceptibility and microwave surface resistance

We discuss on the electromagnetic response of a polycrystalline sample of LaO_0.94F_0.06FeAs exposed to DC magnetic fields up to 10 kOe. The low- and high-frequency responses have been investigated by measuring the AC susceptibility at 100 kHz and the microwave surface resistance at 9.6 GHz. At low as well as high DC magnetic fields, the susceptibility strongly depends on the amplitude of the AC driving field, highlighting enhanced nonlinear effects. The field dependence of the AC susceptibility exhibits a magnetic hysteresis that can be justified considering the intragrain-field-penetration effects on the intergrain critical current density. The microwave surface resistance exhibits a cloc…

Microwave Surface Resistance and Upper-Critical-Field Anisotropy of MgB2 Superconductor

The field-induced variations of the microwave surface resistance are investigated in two different samples of powdered MgB2. The experimental results can be justified in the framework of the Coffey and Clem model with fluxons moving in the flux-flow regime, provided that the anisotropy of the upper critical field is taken into due account. Assuming the angular dependence of the upper critical field expected from the anisotropic Ginzburg-Landau theory, we determine the anisotropy factor by fitting the experimental data of the field dependence of the microwave surface resistance. We show that the anisotropy factor is constant in a range of temperatures of about 3 K below Tc and it takes on di…

'School adopts an experiment': the photoluminescence in extra-virgin olive oil and in tonic water

We report a laboratory activity, carried out along with high- and secondary-school students, that can be done to increase the interest of the young in scientific studies. Groups of selected students ‘adopted’ experiments at physics research laboratories, under the guidance of university researchers. Subsequently, the students demonstrated the experiments to the public at large during the annual science festival organized in Palermo by the association PalermoScienza, in collaboration with the University of Palermo. Experiments on the magnetic levitation of superconductors and on the photoluminescence of several substances were proposed. We discuss the experiment on photoluminescence as a cas…

Harmonic emission at microwave frequencies in YBa2Cu3O7 single crystals near Tc

Abstract Nonlinear microwave emission by YBa 2 Cu 3 O 7 single crystals is investigated at temperatures close to T c . Second- and third-harmonic signals are studied as a function of the temperature and input power, for different values of the external magnetic field. The results are discussed in the framework of a phenomenological theory based on the two-fluid model which assumes that both the microwave and static fields perturb the partial concentrations of the normal and condensate fluids. It is suggested that, at temperatures very close to T c , this mechanism is the only one responsible for the harmonic emission by YBa 2 Cu 3 O 7 single crystals in the Meissner state. It is also effect…

Dynamic measurement of the elastic constant of an helicoidal spring by a smartphone

Abstract We describe an educational activity that can be done by using smartphones to collect data in physics experiments aimed to measure the oscillating period of a spring-mass system and the elastic constant of the helicoidal spring by the dynamic method. Results for the oscillating period and for the elastic constant of the spring agree very well with measurements obtained by different methods. We also discuss the error analysis that can be done in an introductory physics laboratory at undergraduate level.

A study of capillarity phenomena by using a computer-based simulation approach

Liquid properties are relevant for the understanding of fundamental and applied sciences. Among these properties, those that can be traced back and explained through the surface tension are particularly interesting to study and reconstruct in educational terms. Traditional educational treatment of surface tension is often obscure or too complex, sometimes superficial or completely neglected. The aim of the research here described is to discuss in detail a mesoscopic model of liquids and show quantitative results obtained by a computer simulation approach. Looking at the educational aspect, the main advantage of this approach is that it allows the student/teacher to control the simulation pa…

Fluxon dynamics by microwave surface resistance measurements in MgB2

Field-induced variations of the microwave surface resistance, Rs(H), have been investigated in high-density ceramic MgB2. At low temperatures, several peculiarities of the Rs(H) curves cannot be justified in the framework of models reported in the literature. We suggest that they are ascribable to the unconventional vortex structure in MgB2, related to the presence of two gaps. On the contrary, the results near Tc can be accounted for by the Coffey and Clem model, with fluxons moving in the flux-flow regime, provided that the anisotropy of the upper critical field is taken into due account.

Microwave Response of Coaxial Cavities Made of Bulk Magnesium Diboride

We report on the microwave (mw) properties of coaxial cavities built by using bulk MgB2 superconductor prepared by reactive liquid Mg infiltration technology. We have assembled a homogeneous cavity, by using an outer MgB2 cylinder and an inner MgB2 rod, and a hybrid cavity by using an outer copper cylinder and the same MgB2 rod as inner conductor. By the analysis of the resonance curves, in the different resonant modes, we have determined the microwave surface resistance, Rs, of the MgB2 materials as a function of the temperature and the frequency, in the absence of DC magnetic fields. At T = 4.2 K and f = 2.5 GHz, by a mw pulsed technique, we have determined the quality factor of the homog…

Microwave response of a cylindrical cavity made of bulk MgB2 superconductor

We report on the microwave properties of a resonant cylindrical cavity made of bulk MgB2 superconductor, produced by the reactive liquid Mg infiltration process. The frequency response of the cavity has been measured in the range 5-13GHz. Among the various modes, the TE011, resonating at 9.79GHz, exhibits the highest quality factor. For this mode, we have determined the temperature dependence of the quality factor, obtaining values of the order of 10^5 in the temperature range 4.2-30K. The values of the surface resistance deduced from the measurements of the quality factor agree quite well with those independently measured in a small sample of MgB2 extracted from the same specimen from whic…

An approach to the Venturi effect by historical instruments

Student understanding of the laws that describe the flow of a fluid is often hampered by a defective knowledge of basic classical mechanics (kinematics, statics, dynamics, and conservation laws) and by wrong common-sense ideas about quantities related to fluids, such as velocity and pressure. A pedagogical discussion about the Venturi effect, based on experiments inspired by historical instruments, may be an effective way to introduce students to these laws. In this paper, we discuss an approach to the understanding of the Venturi effect based on the study of historical instruments and on simple experiments. In particular, after a presentation of the Venturi effect, also from a historical p…

Time evolution of the microwave second-order response of YBaCuO powder

Transient effects in the microwave second-order response of YBaCuO powder are investigated. The time evolution of the second harmonic signal has been measured for about 300 s after the sample had been exposed to variations of the DC magnetic field. We show that in different time scales the transient response has different origin. In the time scale of milliseconds the transient response of samples in the critical state is ascribable to processes of flux redistribution induced by the switching on/off of the microwave field. At longer times, the time evolution of the second harmonic signal can be ascribed to motion of fluxons induced by the variation of the DC magnetic field. In particular, di…

Fluxon dynamics in Li–Al codoped by microwave surface resistance measurements

Abstract The magnetic-field-induced variations of the microwave surface resistance, R s , have been investigated in ceramic Mg1−x(LiAl)xB2, with x in the range 0.1 – 0.4 . The measurements have been performed on increasing and decreasing the DC magnetic field, H 0 , at fixed temperatures. At low temperatures, we have observed a magnetic hysteresis in the R s ( H 0 ) curves in all the investigated samples. On increasing the temperature, the range of H 0 in which the hysteretic behavior is visible shrinks; however, in the sample with x = 0.1 it is present up to temperatures close to T c . We show that the field dependence of R s can be quantitatively justified taking into account the critical…

Intergrain Effects in the AC Susceptibility of Polycrystalline LaFeAsO_{0.94}F_{0.06}

The AC susceptibility, chi, at zero DC magnetic field of a polycrystalline sample of LaFeAsO_{0.94}F_{0.06} (Tc ≈ 24 K) has been investigated as a function of the temperature, the amplitude of the AC magnetic field (in the range Hac = 0.003 Oe - 4 Oe) and the frequency (in the range f = 10 kHz - 100 kHz). The chi(T) curve exhibits the typical two-step transition arising from the combined response of superconducting grains and intergranular weak-coupled medium. The intergranular part of chi strongly depends on both the amplitude and the frequency of the AC driving field, from few Kelvin below Tc down to T = 4.2 K. Our results show that, in the investigated sample, the intergrain critical cur…

Comparative study of historical woods from XIX century by thermogravimetry coupled with FTIR spectroscopy

Thermal and structural properties of historical woods from apparatuses of the Historical Collection of the Physics Instruments of the University of Palermo have been investigated by FTIR spectroscopy coupled with thermogravimetric analysis. Specifically, the wooden portions of apparatuses from XIX century have been studied. The investigated woods belong to different taxa (Swietenia mahagoni, Picea abies and Juglans regia). The thermal behavior of the wooden materials has been successfully interpreted on the basis of specific indexes determined by the quantitative analysis of the FTIR spectra. The kinetics of the wood pyrolysis have been investigated by using a non-isothermal approach based …