Experimental and theoretical evidence for substitutional molybdenum atoms in theTiO2(110)subsurface

Molybdenum was deposited at room temperature on the ${\mathrm{TiO}}_{2}(110)$ surface in the 0--1.3 equivalent monolayer (eqML) range and was then annealed at $400\phantom{\rule{0.2em}{0ex}}\ifmmode^\circ\else\textdegree\fi{}\mathrm{C}$ in order to reach a kind of equilibrium state. A threshold was found in the behavior of the deposit: below 0.2 eqML, substitutional molybdenum occurs in titanium sites located under the bridging oxygen atoms of the ${\mathrm{TiO}}_{2}(110)$ surface. In this position, molybdenum atoms are in a structural and chemical ${\mathrm{MoO}}_{2}$-like environment. Density-functional theory calculations show that this molybdenum site is actually the most stable one in …

We report on lifetime measurements of the 3d(5)(S-6)4s4p(P-3)y P-6 degrees states of Fe II using time-resolved vacuum ultraviolet (VUV) laser spectroscopy. A laser-produced plasma has been used as the source of free Fe+ ions. The tunable VUV radiation was obtained employing resonantly enhanced sum-difference four-wave-mixing of short laser pulses. We obtained tau((6)P(3/2)degrees) = 3.90(20) ns, tau((6)P(5/2)degrees) = 3.80(20) ns and tau((6)P(7/2)degrees) = 3.65(20) ns.

Watching adsorption and electron beam induced decomposition on the model system Mo(CO)(6)/Cu(111) by X-ray absorption and photoemission spectroscopies

Abstract An in-depth study of the first steps of electron beam assisted growth of Mo from molybdenum hexacarbonyl on Cu(1 1 1) has been carried out exploiting the complementarity of X-ray photoemission and X-ray absorption spectroscopies. Frank van der Merwe (2D) growth mode has been observed for the completion of the two first monolayers of adsorbed molecules through a simple physisorption process. Irradiation of the Mo(CO)6 deposit by 1 keV electron beam induces a modification of molybdenum coordination, the average number of C-neighbors decreasing from 6 to 3. Decomposed molecules remain on the surface after annealing at 520 K and organize themselves, the molybdenum atoms moving in Cu(1 …

Reactivity between molybdenum and TiO2(110) surfaces: evidence of a sub-monolayer mode and a multilayer mode

Small amounts of molybdenum (from 0.03 to 1.3 eqML) were deposited on non-stoichiometric TiO 2 (1 1 0) surface. The deposits were investigated by means of LEED and X-ray/UV photoemission using synchrotron radiation. For the smallest coverage (<0.2 eqML), deposition leads to oxidation of molybdenum into species close to Mo 4+ .In such a case, states appearing in TiO 2 band gap are mainly due to reduced titanium. For higher coverages, metallic behaviour of molybdenum is observed. This phenomenon was explained, thanks to first principle calculations, as a decrease of the Mo-O interactions for the benefit of the Mo-Mo interactions as the surface molybdenum atom density increases.

Photoemission study of the reactivity of barium towards SiOx thermal films

Abstract Barium was deposited at room temperature on a thermal silicon oxide layer and the interfacial reaction was monitored by synchrotron induced photoemission (both core level and valence band). The first step of the growth consists of an interfacial reaction which leads to the formation of an interfacial silicate layer. The next step consists in formation of barium oxide while metallic barium occurs subsequently. The deposit can be also homogenized by annealing above 575 K. This results in the formation of several layers of silicate by consumption of silicon oxide. In the case of fractional coverage, subsequent annealing at 975 K induces the decomposition of barium silicate. However, s…

Landé factor and lifetime measurements in even-parity Rydberg series of PbIusing time-resolved laser spectroscopy

Lande gJ factors and lifetimes for the levels in the even-parity Rydberg series 6pnp (n = 9-16) and 6pnf (n = 6-12) as well as for the levels from perturbing configurations of neutral lead have been measured using laser-induced fluorescence and Zeeman quantum-beat techniques. Two-step excitation was performed in a thermal atomic lead beam. Strong perturbations in the Rydberg series are manifested both in the gJ factor and lifetime data.

Titanium dioxide surface stoichiometry and ordering studied by resonant photoemission spectroscopy

Abstract The electronic structure of titanium dioxide surfaces having undergone different preparations leading to different stoichiometries and crystallinities has been studied using resonant photoemission spectroscopy. Valence band photoemission spectra through the Ti 3p–3d/4s absorption edge between 45 and 55 eV were measured and allowed a characterization of defects present at the surface as well as of the quality of the surface organization. Indeed, from the comparison of the resonance results obtained for each kind of surface with the LEED patterns on the one hand and the corresponding Ti 2p core level lines on the other hand, it was evidenced that the high binding energy part of the v…