0000000000246998
AUTHOR
Jose M. Catala-civera
On-line tools for microscopic and macroscopic monitoring of microwave processing
International audience; Direct monitoring of temperature, chemistry and microstructure is required to understand microwave heating in more detail, in order to fully exploit the unique features this non-equilibrium processing method can offer. In this paper, we show first that microwave radiometry can be used to follow volumetrically the thermal trajectory of microwave-heated aluminium powder. In-situ Raman spectroscopy is then shown to evidence thermal gradients between diamond and silicon grains in a binary powder mixture. Finally, perspectives and preliminary results of microstructural analysis obtained from X-ray microtomography are presented.
Accurate determination of the complex permittivity of materials with transmission reflection measurements in partially filled rectangular waveguides
An enhanced transmission reflection technique for the precise determination of the complex permittivity of dielectric materials partially filling the cross section of a rectangular waveguide is described. Dielectric properties are determined by an iterative procedure from two-port S-parameter measurements and a numerically generated propagation constant obtained from the analysis of a partially filled waveguide. Convergence of the solution is ensured from perturbational approximations. Unlike previous approaches, an uncertainty investigation is performed, taking into account all the parameters involved in the dielectric characterization. Permittivity accuracy values are presented and, hence…
Rapid nanocrystallization of soft-magnetic amorphous alloys using microwave induction heating
The crystallization of Fe73Nb3Cu1Si16B7 alloy during microwave heating was investigated in situ using synchrotron radiation powder diffraction. The phase transformation comprises a primary nanocrystallization stage and a final microcrystallization step. We provide evidence for a strong enhancement of the transformation kinetics. Microwave heating occurs as a result of both ohmic and magnetic losses induced by eddy currents, which defines a volumetric microwave induction heating process. Nanocrystallization is completed within 5 s, while full crystallization is achieved in less than 10 s.
Nanocrystallization of amorphous alloys using microwaves:In situtime-resolved synchrotron radiation studies
Important energy and time savings can be achieved with the thermal treatment of materials by replacing conventional heating methods with microwave heating. The nano- crystallization of Co-Fe-W-B amorphous alloy powders under microwave irradiation was followed for the first time by in situ time-resolved synchrotron radiation powder diffraction. It is shown that even a very short exposure to the electromagnetic field (single pulse microwave application) typically of the order of a few seconds is sufficient to obtain the bulk nano- crystalline state. A metastable high-temperature Co-W-B orthorhombic phase forms during the microwave heating, which gradually transforms to the tetragonal Co2B sta…
A Novel Technique for Deembeding the Unloaded Resonance Frequency from Measurements of Microwave Cavities
[EN] A novel technique to extract the influence of coupling networks on the resonant frequency of cavities in one-port measurements is presented. The determination of the unloaded resonant frequency is performed directly from measurements without either the need to obtain the electromagnetic fields in the resonator or to deembed the delay of transmission lines from the measuring equipment to the resonator. The importance of the Foster's form on the modeling of the frequency detuning of the resonators is also discussed and a criterion for the choice of the appropriate Foster's form is suggested. The procedure is validated with simulations and experimental measurements of manufactured cavities
Feasible glass‐melting process assisted by microwaves
[EN] The advantages of microwave (MW) energy processing have been verified in the sintering of a ceramic frit at a pre-industrial scale. The challenge of achieving high temperature using MW energy at such dimensions was overcome and a mix of natural raw materials was heated until its fluxing point. Changes in dielectric properties of the raw materials mix were also measured in situ with the increase in temperature, being in accordance to thermal processes of a conventional heating process. The properties of the resulting ceramic frit were compared with the same frit obtained by the conventional sintering method. Both frits showed similar thermal behavior regarding DTA-TGA, heating microscop…
Solving the Cut-Off Wave Numbers in Partially filled Rectangular Waveguides with Ferrite by the Cauchy Integral Method
The modal analysis of the off-centered rectangular waveguide loaded with a vertical slab of ferrite material, biased in the y-direction by a DC magnetic field, leads to the resolution of a transcendent equation whose infinite solutions are the TE/sub m0/ cutoff wave numbers in the guide. The method based on the Cauchy integral (Delvest L.M. and Lyness, J.N., 1967) is becoming very popular for solving such equations. This powerful method is described for solving the propagation constant in a partially ferrite filled waveguide. The method is used to calculate the propagation constant of the fundamental TE mode for some configurations used in the literature about ferrites. Results obtained in …