0000000000265991

AUTHOR

Isabelle Baglin

0000-0001-9951-9459

showing 17 related works from this author

Efficient Synthesis of Multifunctional Chelating Agents Based on Tetraazacycloalkanes

2018

An efficient route has been developed for the synthesis of multifunctional tetraazacycloalkanes (in particular 1,4,7,10-tetraazacyclotridecane) incorporating an aminomethyl pendant arm on the carbon skeleton. Starting from the appropriate C-functionalized bisaminal-protected intermediate, the target macrocycles were easily obtained by means of a step-by-step introduction of the desired functional groups onto the free primary amine group, followed by deprotection of the bisaminal intermediates. This straightforward and versatile synthetic approach paves the way for the design of a new family of multifunctional chelators.

Primary (chemistry)010405 organic chemistryLigandChemistryOrganic ChemistryCarbon skeletonRegioselectivity010402 general chemistry01 natural sciencesCombinatorial chemistry0104 chemical sciencesAmine gas treatingChelationPhysical and Theoretical ChemistryEuropean Journal of Organic Chemistry
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Reinforced cyclam derivatives functionalized on the bridging unit

2016

International audience; A new synthetic method has been developed for the preparation of reinforced cyclams (1,4,8,11-tetraazacyclotetradecane) C-functionalized on the bridging unit, by using a "one pot" reaction starting from the appropriate bis-aminal cyclam intermediate. The high reactivity of quaternized aminal moiety toward nucleophilic agent has been used to elaborate a new class of cross-bridged and side-bridged cyclam derivatives containing cyanide group on the ethylene bridge. Several chelators and corresponding copper(II) complexes have been prepared and characterized by X-ray diffraction. These new constrained polyazamacrocycles are valuable precursors of bifunctional chelating a…

CyanideRadiometals010402 general chemistry01 natural sciencesCatalysisCopper(ii) complexesCoordination complexContinuous symmetry measureschemistry.chemical_compoundNucleophileBifunctional chelator[SDV.IDA]Life Sciences [q-bio]/Food engineeringCyclamMaterials ChemistryOrganic chemistryMoietyChelationBifunctionalPolyhedrachemistry.chemical_classification010405 organic chemistry[ SDV.IDA ] Life Sciences [q-bio]/Food engineeringGeneral ChemistryCombinatorial chemistry0104 chemical sciencesCoordination chemistrychemistryAminalTherapyStability
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CCDC 1439080: Experimental Crystal Structure Determination

2016

Related Article: Nicolas Sok, Isabelle Baglin, Yoann Rousselin, Frederic Boschetti, Claire Bernhard, Christine Goze, Franck Denat|2016|New J.Chem.|40|5829|doi:10.1039/C5NJ03488D

Space GroupCrystallographyCrystal SystemCrystal Structure411-dibenzyl-14811-tetraazabicyclo[6.6.2]hexadecane-1516-dicarbonitrileCell ParametersExperimental 3D Coordinates
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CCDC 1583210: Experimental Crystal Structure Determination

2018

Related Article: Nicolas Sok, Claire Bernhard, Pauline Désogère, Christine Goze, Yoann Rousselin, Frédéric Boschetti, Isabelle Baglin, Franck Denat|2018|Eur.J.Org.Chem.|2018|4762|doi:10.1002/ejoc.201800801

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters1-(anthracen-9-yl)-N-[(9b9c-dimethyldecahydro-5H-2a4a7a9a-tetraazacyclopenta[cd]phenalen-1-yl)methyl]methanamineExperimental 3D Coordinates
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CCDC 1439078: Experimental Crystal Structure Determination

2016

Related Article: Nicolas Sok, Isabelle Baglin, Yoann Rousselin, Frederic Boschetti, Claire Bernhard, Christine Goze, Franck Denat|2016|New J.Chem.|40|5829|doi:10.1039/C5NJ03488D

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters411-dimethyl-14811-tetraazabicyclo[6.6.2]hexadec-15-ene-15-carbonitrileExperimental 3D Coordinates
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CCDC 1439081: Experimental Crystal Structure Determination

2016

Related Article: Nicolas Sok, Isabelle Baglin, Yoann Rousselin, Frederic Boschetti, Claire Bernhard, Christine Goze, Franck Denat|2016|New J.Chem.|40|5829|doi:10.1039/C5NJ03488D

Space GroupCrystallographyCrystal SystemCrystal Structure411-dibenzyl-14811-tetraazabicyclo[6.6.2]hexadecane-1516-dicarbonitrileCell ParametersExperimental 3D Coordinates
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CCDC 1439077: Experimental Crystal Structure Determination

2016

Related Article: Nicolas Sok, Isabelle Baglin, Yoann Rousselin, Frederic Boschetti, Claire Bernhard, Christine Goze, Franck Denat|2016|New J.Chem.|40|5829|doi:10.1039/C5NJ03488D

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters411-dibenzyl-14811-tetraazabicyclo[6.6.2]hexadec-15-ene-15-carbonitrileExperimental 3D Coordinates
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CCDC 1583212: Experimental Crystal Structure Determination

2018

Related Article: Nicolas Sok, Claire Bernhard, Pauline Désogère, Christine Goze, Yoann Rousselin, Frédéric Boschetti, Isabelle Baglin, Franck Denat|2018|Eur.J.Org.Chem.|2018|4762|doi:10.1002/ejoc.201800801

Space GroupCrystallographyCrystal SystemCrystal Structure{1-(9b9c-dimethyldecahydro-5H-2a4a7a9a-tetraazacyclopenta[cd]phenalen-1-yl)-N-[(pyren-1-yl)methyl]methanamine}(trihydrido)boronCell ParametersExperimental 3D Coordinates
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CCDC 1583211: Experimental Crystal Structure Determination

2018

Related Article: Nicolas Sok, Claire Bernhard, Pauline Désogère, Christine Goze, Yoann Rousselin, Frédéric Boschetti, Isabelle Baglin, Franck Denat|2018|Eur.J.Org.Chem.|2018|4762|doi:10.1002/ejoc.201800801

Space GroupCrystallography{1-(anthracen-9-yl)-N-[(9b9c-dimethyldecahydro-5H-2a4a7a9a-tetraazacyclopenta[cd]phenalen-1-yl)methyl]methanamine}(trihydrido)boronCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1583209: Experimental Crystal Structure Determination

2018

Related Article: Nicolas Sok, Claire Bernhard, Pauline Désogère, Christine Goze, Yoann Rousselin, Frédéric Boschetti, Isabelle Baglin, Franck Denat|2018|Eur.J.Org.Chem.|2018|4762|doi:10.1002/ejoc.201800801

Space GroupCrystallographyCrystal SystemN-[(9b9c-dimethyldecahydro-5H-2a4a7a9a-tetraazacyclopenta[cd]phenalen-1-yl)methyl]-1-(pyren-1-yl)methanimineCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1439082: Experimental Crystal Structure Determination

2016

Related Article: Nicolas Sok, Isabelle Baglin, Yoann Rousselin, Frederic Boschetti, Claire Bernhard, Christine Goze, Franck Denat|2016|New J.Chem.|40|5829|doi:10.1039/C5NJ03488D

Space GroupCrystallography(411-dibenzyl-14811-tetraazabicyclo[6.6.2]hexadecane-1516-dicarbonitrile)-nitrato-copper(ii) nitrate methanol solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1476682: Experimental Crystal Structure Determination

2017

Related Article: Nicolas Sok, Isabelle Baglin, Christelle Basset, Fatima Fakkor, Evelyne Kohli, Yoann Rousselin, Claire Bernhard, Frédéric Boschetti, Christine Goze, Franck Denat|2017|RSC Advances|7|28291|doi:10.1039/C7RA04218C

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates3-(6-(tetradecahydro-1H-imidazo[15-d][14710]tetraazacyclotridecin-3-yl)pyridin-2-yl)tetradecahydro-1H-imidazo[15-d][14710]tetraazacyclotridecine monohydrate
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CCDC 1583208: Experimental Crystal Structure Determination

2018

Related Article: Nicolas Sok, Claire Bernhard, Pauline Désogère, Christine Goze, Yoann Rousselin, Frédéric Boschetti, Isabelle Baglin, Franck Denat|2018|Eur.J.Org.Chem.|2018|4762|doi:10.1002/ejoc.201800801

Space GroupCrystallography1-(anthracen-9-yl)-N-[(9b9c-dimethyldecahydro-5H-2a4a7a9a-tetraazacyclopenta[cd]phenalen-1-yl)methyl]methanimineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1439079: Experimental Crystal Structure Determination

2016

Related Article: Nicolas Sok, Isabelle Baglin, Yoann Rousselin, Frederic Boschetti, Claire Bernhard, Christine Goze, Franck Denat|2016|New J.Chem.|40|5829|doi:10.1039/C5NJ03488D

Space GroupCrystallographyCrystal SystemCrystal Structurediaqua-(411-dimethyl-14811-tetraazabicyclo[6.6.2]hexadec-15-ene-15-carbonitrile)-copper(ii) dinitrateCell ParametersExperimental 3D Coordinates
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CCDC 1476683: Experimental Crystal Structure Determination

2017

Related Article: Nicolas Sok, Isabelle Baglin, Christelle Basset, Fatima Fakkor, Evelyne Kohli, Yoann Rousselin, Claire Bernhard, Frédéric Boschetti, Christine Goze, Franck Denat|2017|RSC Advances|7|28291|doi:10.1039/C7RA04218C

Space GroupCrystallographyCrystal System110131620-pentaazatetracyclo[10.10.1.0210.038]tricosa-357-trien-9-oneCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1476681: Experimental Crystal Structure Determination

2017

Related Article: Nicolas Sok, Isabelle Baglin, Christelle Basset, Fatima Fakkor, Evelyne Kohli, Yoann Rousselin, Claire Bernhard, Frédéric Boschetti, Christine Goze, Franck Denat|2017|RSC Advances|7|28291|doi:10.1039/C7RA04218C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters3-(3-(tetradecahydro-1H-imidazo[15-d][14710]tetraazacyclotridecin-3-yl)phenyl)tetradecahydro-1H-imidazo[15-d][14710]tetraazacyclotridecine monohydrateExperimental 3D Coordinates
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CCDC 1583213: Experimental Crystal Structure Determination

2018

Related Article: Nicolas Sok, Claire Bernhard, Pauline Désogère, Christine Goze, Yoann Rousselin, Frédéric Boschetti, Isabelle Baglin, Franck Denat|2018|Eur.J.Org.Chem.|2018|4762|doi:10.1002/ejoc.201800801

Space GroupCrystallographyCrystal SystemCrystal StructureN-[(anthracen-9-yl)methyl]-N-[(9b9c-dimethyldecahydro-5H-2a4a7a9a-tetraazacyclopenta[cd]phenalen-1-yl)methyl]prop-2-yn-1-amine cyclohexane solvateCell ParametersExperimental 3D Coordinates
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