FTIR Studies of Silicon Carbide 1D-Nanostructures
Stable 1D silicon carbide nanostructures (nanowires) have been obtained via combustion synthesis route. Infrared absorption and reflection spectra for as-obtained and purified SiC nanowires were compared with the spectra of commercially available SiC nanomaterials. Principal vibrational modes have been identified. Reflectivity spectrum has been reconstructed by modeling of the dielectric function
Optical and Vibrational Spectra of CsCl-Enriched GeS2-Ga2S3 Glasses
Optical and FTIR spectroscopy was employed to study the properties of 80GeS2-20Ga2S3-CsCl chalcohalide glasses with CsCl additives in a temperature range of 77–293 K. It is shown that CsCl content results in the shift of fundamental absorption edge in the visible region. Vibrational bands in FTIR spectra of (80GeS2-20Ga2S3)100 − х (СsCl) x (x = 5, 10, and 15) are identified near 2500 cm−1, 3700 cm−1,, around 1580 cm−1, and a feature at 1100 cm−1. Low energy shifts of vibrational frequencies in glasses with a higher amount of CsCl can be caused by possible thermal expansion of the lattice and nanovoid agglomeration formed by CsCl additives in the inner structure of the Ge-Ga-S glass.